Results 201 to 210 of about 295,838 (293)

Precise, specific gene editing via a compact GoCas12m-FokI chimeric nuclease. [PDF]

open access: yesNucleic Acids Res
Marsic T   +7 more
europepmc   +1 more source

Photoresponsive Polymers for Debonding-on-Demand Pressure-Sensitive Adhesives. [PDF]

open access: yesACS Appl Mater Interfaces
Raji IO   +6 more
europepmc   +1 more source

Radical‐Based On‐Surface Transformation of Nonplanar Aromatics Into Nonbenzenoid Nanographenes

open access: yesAngewandte Chemie, EarlyView.
Formation of radicals in nonplanar hydrocarbons through thermally induced dehydrogenation leads to molecular transformation via intramolecular radical‐based cyclization and dimerization, leading to formation of nonbenzenoid nanographenes. ABSTRACT On‐surface synthesis has emerged as a powerful tool for atomically precise C─C bond formation, enabling ...
Daniel Rothhardt   +8 more
wiley   +1 more source

Identification and Characterization of ERK2 Dimerization Inhibitors by Integrated In Silico and In Vitro Screening. [PDF]

open access: yesInt J Mol Sci
Ortiz-González C   +5 more
europepmc   +1 more source

Regioselective Synthesis of Benzylsilanols from Kobayashi‐Type Reagents via C(sp3)─H Bond Activating 1,4‐Palladium Migration

open access: yesAngewandte Chemie, EarlyView.
A Pd‐catalyzed regioselective synthesis of benzylsilanols from Kobayashi‐type reagents has been developed through a mechanistically distinct approach involving 1,4‐Pd migration followed by intramolecular transmetalation. The reaction can be combined with various prior transition‐metal‐catalyzed processes and the resulting benzylsilanols have been ...
Ryo Shintani, Keisuke Tachibana
wiley   +1 more source

Structurally Constrained Stibenium: Metallomimetic C−Si Bond Activation

open access: yesAngewandte Chemie, EarlyView.
A structurally constrained stibenium cation supported by a 2,6‐bis(o‐carborano)pyridine pincer‐type ligand was prepared, and its preliminary reactivity toward silanes was investigated. Remarkably, Si−C bonds in silanes undergo activation via an oxidative‐addition‐type process at the cationic Sb center.
Donia Toami, Roman Dobrovetsky
wiley   +1 more source

Diazo Transfer From Nitrous Oxide Employing Phosphorus Ylides

open access: yesAngewandte Chemie, EarlyView.
A phosphorus ylide‐mediated strategy achieves the direct fixation of nitrous oxide (N2O) to access diazo compounds, which after intra‐ or intermolecular trapping, afford N2‐containing organic building blocks. This approach provides an alternative to hazardous diazo‐transfer reagents and establishes N2O fixation as a sustainable methodology.
Jhen‐Kuei Yu   +4 more
wiley   +1 more source

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