Direct Arylation in the Presence of Palladium Pincer Complexes [PDF]
Molecules, 2021 Direct arylation is an atom-economical alternative to more established procedures such as Stille, Suzuki or Negishi arylation reactions. In comparison with other palladium sources and ligands, the use of palladium pincer complexes as catalysts or pre ...
Garazi Urgoitia +4 more
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Rhodium-catalyzed selective direct arylation of phosphines with aryl bromides [PDF]
Nature Communications, 2022 The widespread use of biaryl monophosphines is frequently hampered by the challenges associated with their modular preparation. Here, the authors report a protocol that appends arenes to arylphosphines to access a series of these compounds via rhodium ...
Dingyi Wang +6 more
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Direct Arylation Synthesis of Small Molecular Acceptors for Organic Solar Cells [PDF]
Molecules, 2023 In recent years, small molecular acceptors (SMAs) have extensively promoted the progress of organic solar cells (OSCs). The facile tuning of chemical structures affords SMAs excellent tunability of their absorption and energy levels, and it gives SMA ...
Xiaochen Wang +5 more
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CHIMIA, 2022 Bonds between hydrogen and carbon atoms are the most frequent type of bonds in organic molecules. The ability to replace hydrogen atoms by making other types of bonds to carbon atoms can enable simpler access to complex organic molecules by substituting
Jyoti Dhankhar, Ilija Čorić
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Room-temperature Pd/Ag direct arylation enabled by a radical pathway [PDF]
Beilstein Journal of Organic Chemistry, 2020 Direct arylation is an appealing method for preparing π-conjugated materials, avoiding the prefunctionalization required for traditional cross-coupling methods. A major effort in organic electronic materials development is improving the environmental and
Amy L. Mayhugh, Christine K. Luscombe
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“On Water” Palladium Catalyzed Direct Arylation of 1H-Indazole and 1H-7-Azaindazole [PDF]
Molecules, 2020 The C3 direct arylation of 1H-indazole and 1H-7-azaindazole has been a significant challenge due to the lack of the reactivity at this position. In this paper, we describe a mild and an efficient synthesis of new series of C3-aryled 1H-indazoles and C3 ...
Khadija Gambouz +7 more
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Novel Diketopyrrolopyrrole-Based π-Conjugated Molecules Synthesized Via One-Pot Direct Arylation Reaction [PDF]
Molecules, 2019 Diketopyrrolopyrrole (DPP) is an important type of π-conjugated building block for high-performance organic electronic materials. DPP-based conjugated materials are usually synthesized via Suzuki, Stille, or Negishi cross-coupling reactions, which ...
Hui Liu +5 more
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Ruthenium(η6,η1-arene-CH2-NHC) Catalysts for Direct Arylation of 2-Phenylpyridine with (Hetero)Aryl Chlorides in Water [PDF]
Molecules, 2018 A series of new benzimidazolium halides were synthesized in good yields as unsymmetrical N-heterocyclic carbene (NHC) precursors containing the N–CH2–arene group.
Nazan Kaloğlu +4 more
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Palladium-Catalyzed C2-Selective Direct Arylation of Benzo[b]thiophene 1,1-Dioxides with Arylboronic Acids [PDF]
ACS Omega, 2023 Xinwei Zhang +5 more
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Direct Arylation of 1,10-Phenanthroline Using an Organomagnesium Reagent [PDF]
ACS OmegaNathanael A. Hirscher +4 more
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