Results 31 to 40 of about 3,066,437 (179)
A cooperative Pd-Cu system for direct C-H bond arylation [PDF]
The authors are grateful to the Royal Society (University Research Fellowship to CSJC) for financial support.A novel and efficient method for C-H arylation using well-defined Pd- and Cu-NHC systems has been developed.
Cazin, Catherine +3 more
core +1 more source
The Synthesis and Photophysical Properties of Weakly Coupled Diketopyrrolopyrroles
Three centrosymmetric diketopyrrolopyrroles possessing either two 2-(2′-methoxyphenyl)benzothiazole or two 2-(2′-methoxyphenyl)benzoxazolo-thiophene scaffolds were synthesized in a straightforward manner, and their photophysical properties were ...
Michał Pieczykolan +8 more
doaj +1 more source
Palladium-catalyzed α-arylation of arylketones at low catalyst loadings [PDF]
The authors thank the ERC (Advanced Researcher award-FUNCAT), 7th Framework Program NMP2-LA-2010–246461 (SYNFLOW) and King Saud University for funding.A general catalytic protocol for the a-arylation of aryl ketones has been developed.
Nolan, Steven Patrick +10 more
core +1 more source
Palladium-Catalyzed C–H Arylation of 1,2,3-Triazoles
Palladium(II) acetate, in combination with triphenylphosphine, catalyzes direct arylation of 1,4-disubstituted 1,2,3-triazoles effectively. This C–H arylation reaction provides facile access to fully substituted triazoles with well-defined regiochemistry.
Chengwei Zhang, Lin You, Chuo Chen
doaj +1 more source
Direct C–H Alpha Arylation of Enones with ArI(O2CR)2 Reagents [PDF]
Herein, we report the metal-free direct C–H arylation of enones mediated by hypervalent iodine reagents. The reaction proceeds via a reductive iodonium Claisen rearrangement of in situ b-pyridinium silyl enol ethers.
Felipe Cesar Sousa e Silva (7520025) +5 more
core +2 more sources
Copper-Catalyzed Selective Arylation of Oxadiazolones by Diaryliodonium Salts [PDF]
The direct N-arylation of cyclic amides can be considered a pivotal issue for modern organic chemistry. Here, we report the method for copper-catalyzed N-arylation of diverse oxadiazolones by diaryliodonium salts in mild conditions in high yields (up to ...
Pavel, Postnikov +8 more
core +2 more sources
Synthesis and properties of tetrathiafulvalenes bearing 6-aryl-1,4-dithiafulvenes
Novel multistage redox tetrathiafulvalenes (TTFs) bearing 6-aryl-1,4-dithiafulvene moieties were synthesized by palladium-catalyzed direct C–H arylation.
Aya Yoshimura +8 more
doaj +1 more source
Harnessing Direct(Hetero)Arylation in Pursuit of a Saddle-Shaped Perylene Diimide Tetramer [PDF]
This contribution explores the direct(hetero) arylation (DHA) cross-coupling of a saddle-like, π-conjugated cyclooctatetrathiophene (Th4) core with the N-annulated perylene diimide (PDI) chromophore.
Joshua, Koenig +2 more
core +1 more source
The arylation of 2-pyrones and related heterocycles [PDF]
2-Pyrones, and related heterocycles such as 2-pyridones, 2-coumarins and 2- quinolones, are useful model substrates to test a novel methodology due to their varied chemical properties.
Prendergast, Aisling M.
core +1 more source
The use of a bromo-substituent as blocking group at the C2-position of 3-substituted thiophenes allows the regioselective introduction of aryl substituents at C5-position via Pd-catalysed direct arylation.
Mariem Brahim +3 more
doaj +1 more source

