Results 51 to 60 of about 3,066,437 (179)

Sustainable Access to π-Conjugated Molecular Materials via Direct (Hetero)Arylation Reactions in Water and under Air

open access: yesMolecules, 2020
Direct (hetero)arylation (DHA) is playing a key role in improving the efficiency and atom economy of C–C cross coupling reactions, so has impacts in pharmaceutical and materials chemistry.
Adiel Mauro Calascibetta   +5 more
doaj   +1 more source

Palladium-Catalyzed intramolecular direct arylation of aromatic tertiary amide compounds revisited

open access: yesResults in Chemistry, 2022
We have investigated the palladium-catalyzed intramolecular direct arylation of three aromatic tertiary amide compounds. For the C–H activation of the benzene ring, heating over 120 °C in the presence of PCy3·HBF4 and PivOH was indispensable, and the ...
Koji Takagi   +2 more
doaj   +1 more source

Palladium-Catalyzed Direct Arylation of Selenophene [PDF]

open access: yesProceedings of the 15th Brazilian Meeting on Organic Synthesis Proceedings, 2013
An efficient and convenient method was developed for the regioselective formation of 2-aryl- or 2,5-diarylselenophenes via a palladium-catalyzed direct arylation. This protocol is suitable for a wide range of aryl halides containing different functional groups.
Daniel S, Rampon   +2 more
openaire   +3 more sources

Aryl Bromides and Aryl Chlorides for the Direct Arylation of Benzylic Amines Mediated by Ruthenium(II) [PDF]

open access: yesEuropean Journal of Organic Chemistry, 2013
AbstractThe ruthenium(II)‐catalyzed sp3 C–H bond arylation of benzylic amines with aryl halides is reported. In the present method, aryl iodides and, more importantly, also the cheaper aryl bromides and aryl chlorides can be applied as aryl sources. Additionally, the method does not require elaborate manipulations in a glove box and can be carried out ...
Dastbaravardeh, Navid   +2 more
openaire   +2 more sources

Efficient Rh(I)-Catalyzed Direct Arylation and Alkenylation of Arene C-H Bonds via Decarbonylation of Benzoic and Cinnamic Anhydrides

open access: yes, 2009
Efficient rhodium(I)-catalyzed regioselective direct arylation and alkenylation of aromatic C-H bonds has been realized with aromatic carboxylic and cinnamic anhydrides as the coupling partners via decarbonylation and C-H activation under phosphine-free ...
Ye, Wenjing   +5 more
core   +1 more source

Copper-catalyzed CuAAC/intramolecular C–H arylation sequence: Synthesis of annulated 1,2,3-triazoles

open access: yesBeilstein Journal of Organic Chemistry, 2012
Step-economical syntheses of annulated 1,2,3-triazoles were accomplished through copper-catalyzed intramolecular direct arylations in sustainable one-pot reactions.
Rajkumar Jeyachandran   +2 more
doaj   +1 more source

Arylation Reactions in the Synthesis of Biologically Important 2,5-Diaryl-1,3,4-Oxadiazoles

open access: yesApplied Sciences, 2022
Apart from carbon atoms, some cyclic molecules contain other elements and play an extraordinary role in human life. Among these systems, 1,3,4-oxadiazole derivatives deserve special attention due to their biological properties such as antibacterial ...
Monika Olesiejuk, Agnieszka Kudelko
doaj   +1 more source

Ruthenium-catalyzed direct arylations with aryl chlorides

open access: yesRSC Advances, 2016
Aryl chlorides are readily available at lower cost than the corresponding bromides and iodides, but are much more challenging as substrates in metal-catalyzed cross-couplings.
Gao-Feng Zha   +2 more
openaire   +1 more source

Synthesis of 2,2,5-Trisubstituted 2H‑Pyrroles and 2,3,5-Trisubstituted 1H‑Pyrroles by Ligand-Controlled Site-Selective Dearomative C2-Arylation and Direct C3-Arylation

open access: yes, 2019
Palladium-catalyzed site-selective dearomative C2-arylation of 2,5-diaryl-1H-pyrroles with aryl chlorides was accomplished, and a series of 2,2,5-triaryl-2H-pyrroles were synthesized.
Sakiko Fujiwara   +5 more
core   +1 more source

Nucleophilic Arylation of Halopurines Facilitated by Brønsted Acid in Fluoroalcohol

open access: yesMolecules, 2019
Various aryl-substituted purine derivatives were synthesized through the direct arylation of halopurines with aromatic compounds, facilitated by the combination of triflic acid and fluoroalcohol.
Naoko Takenaga   +7 more
doaj   +1 more source

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