Results 11 to 20 of about 289,146 (256)

Molecular Basis for Directional Electron Transfer [PDF]

open access: yesJournal of Biological Chemistry, 2010
Biological macromolecules involved in electron transfer reactions display chains of closely packed redox cofactors when long distances must be bridged. This is a consequence of the need to maintain a rate of transfer compatible with metabolic activity in the framework of the exponential decay of electron tunneling with distance.
Catarina M, Paquete   +3 more
openaire   +2 more sources

Directed evolution of P450cin for mediated electron transfer [PDF]

open access: yesProtein Engineering Design and Selection, 2016
Directed evolution is a powerful method to optimize enzyme properties for application demands. Interesting targets are P450 monooxygenases which catalyze the stereo- and regiospecific hydroxylation of chemically inert C-H bonds. Synthesis employing P450s under cell-free reaction conditions is limited by low total turnover numbers, enzyme instability ...
Ketaki D, Belsare   +7 more
openaire   +2 more sources

Direct arylation reaction of heteroarenes mediated by photoinduced electron transfer

open access: yesJournal of Photochemistry and Photobiology, 2023
Electron donor–acceptor (EDA) complexes are interesting chemical species that function as molecular complexes. In this context, chemists have actively studies the use of halogen bonding as a noncovalent interaction in photochemistry.
Eiji Yamaguchi, Oe Karin, Akichika Itoh
doaj   +1 more source

Direct heterogeneous electron transfer of theophylline oxidase [PDF]

open access: yesBiosensors and Bioelectronics, 2004
Direct electron transfer (DET) was shown between the heme containing enzyme theophylline oxidase (ThO) and the surface of both graphite and gold electrodes. As proof on graphite a steady state current for theophylline was recorded using the electrode modified with adsorbed ThO.
Christenson, Andreas   +3 more
openaire   +3 more sources

Mechanisms of electron transfer to insoluble terminal acceptors in chemoorganotrophic bacteria [PDF]

open access: yesThe Ukrainian Biochemical Journal, 2014
The mechanisms of electron transfer of association of chemoorganotrophic bacteria to the anode in microbial fuel cells are summarized in the survey. These mechanisms are not mutually exclusive and are divided into the mechanisms of mediator electron ...
I. A. Samarukha
doaj   +1 more source

Methanobacterium Capable of Direct Interspecies Electron Transfer [PDF]

open access: yesEnvironmental Science & Technology, 2020
Direct interspecies electron transfer (DIET) from bacteria to methanogens is a revolutionary concept for syntrophic metabolism in methanogenic soils/sediments and anaerobic digestion. Previous studies have indicated that the potential for DIET is limited to methanogens in the Methanosarcinales, leading to the assumption that an abundance of other types
Shiling Zheng   +4 more
openaire   +2 more sources

Direct Interspecies Electron Transfer Mediated by Graphene Oxide-Based Materials

open access: yesFrontiers in Microbiology, 2020
Conductive materials are known to promote direct interspecies electron transfer (DIET) by electrically bridging microbial cells. Previous studies have suggested that supplementation of graphene oxide (GO) based materials, including GO, and reduced GO ...
Kensuke Igarashi   +3 more
doaj   +1 more source

Transcriptomic and Genetic Analysis of Direct Interspecies Electron Transfer [PDF]

open access: yesApplied and Environmental Microbiology, 2013
ABSTRACT The possibility that metatranscriptomic analysis could distinguish between direct interspecies electron transfer (DIET) and H 2 interspecies transfer (HIT) in anaerobic communities was investigated by comparing gene transcript abundance in cocultures in which Geobacter sulfurreducens
Shrestha, Pravin Malla   +5 more
openaire   +2 more sources

Iron Corrosion via Direct Metal-Microbe Electron Transfer

open access: yesmBio, 2019
The concept that anaerobic microorganisms can directly accept electrons from Fe(0) has been controversial because direct metal-microbe electron transfer has previously only been indirectly inferred.
Hai-Yan Tang   +4 more
doaj   +1 more source

Theoretical characterisation of electron tunnelling from granular activated carbon to electron accepting organisms in direct interspecies electron transfer

open access: yesScientific Reports, 2022
Direct interspecies electron transfer (DIET) has been identified as an efficient metabolism between symbiotically interacting organisms. One method of DIET uses conductive materials (e.g., granular activated carbon (GAC)) as a medium to shuttle electrons
Rohan Rao, Jing Hu, Po-Heng Lee
doaj   +1 more source

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