Results 81 to 90 of about 101,052 (211)

Metal-Free Oxidative Dimerization of Dithiocarbamates: Direct Access to 3,5-Bis-mercapto-1,2,4-thiadiazoles

SynOpen, 2017
A facile and efficient protocol for the synthesis of 3,5-bis-mercapto-1,2,4-thiadiazoles by the oxidative dimerization of S-alkyl dithiocarbamates using periodic acid as an inexpensive and commercially available oxidant is reported.
Azim Ziyaei Halimehjani, Yazdanbakhsh Lotfi Nosood, Shaghayegh Didaran, Fezzeh Aryanasab   +3 more
doaj   +1 more source

Bis(diethyldithiocarbamato)(iodo)(4-methoxyphenyl)tellurium(IV), \u3cem\u3ep\u3c/em\u3e-MeOC\u3csub\u3e6\u3c/sub\u3eH\u3csub\u3e4\u3c/sub\u3eTe(Et\u3csub\u3e2\u3c/sub\u3eNCS\u3csub\u3e2\u3c/sub\u3e)\u3csub\u3e2\u3c/sub\u3eI, and its Isomorphous Partially Bromine-Replaced Analogue, \u3cem\u3ep\u3c/em\u3e-MeOC\u3csub\u3e6\u3c/sub\u3eH\u3csub\u3e4\u3c/sub\u3eTe(Et\u3csub\u3e2\u3c/sub\u3eNCS\u3csub\u3e2\u3c/sub\u3e)\u3csub\u3e2\u3c/sub\u3eBr\u3csub\u3e0.41\u3c/sub\u3eI\u3csub\u3e0.59\u3c/sub\u3e [PDF]

, 1996
The structure of the title TeIV complex, C13H19BrN2OS4Te.045(CH2Cl2), is pentagonal bipyramidal with four S atoms [Te-S 2.623 (1)-2.717 (1) Å] and the Br atom [Te-Br 2.890 (1) Å] in equatorial positions. The p-methoxyphenyl group is axial [Te-C 2.145 (3)
Husebye, Steinar, Kudis, Steffen, Lindeman, Sergey V.   +2 more
core   +2 more sources

Elucidation of Sulforaphane‐Mediated Effects on the Cellular Human Metabolome Using Metabolic Profiling

Molecular Nutrition &Food Research, Volume 70, Issue 1, January 2026.
Sulforaphane (SFN) is an isothiocyanate derived from broccoli and is related to various health‐promoting effects. By using metabolic profiling on the hepatoblastoma cell line HepG2 several effects on pathways such as TCA cycle, urea cycle and redox metabolism through SFN were identified.
Nadine Bieß, Hans‐Ulrich Humpf, Matthias Behrens, Andrea Gerdemann   +3 more
wiley   +1 more source

[N,N-Bis(2-hydroxyethyl)dithiocarbamato-κ2S,S′]bis(triphenylphosphane-κP)copper(I) chloroform monosolvate: crystal structure, Hirshfeld surface analysis and solution NMR measurements

Acta Crystallographica Section E: Crystallographic Communications, 2016
The title compound, [Cu(C5H5NO2S2)(C18H15P)2]·CHCl3, features a tetrahedrally coordinated CuI atom within a P2S2 donor set defined by two phosphane P atoms and by two S atoms derived from a symmetrically coordinating dithiocarbamate ligand.
Sang Loon Tan, Chien Ing Yeo, Peter J. Heard, Geoffrey R. Akien, Nathan R. Halcovitch, Edward R. T. Tiekink   +5 more
doaj   +1 more source

Aseries of M-M_heterometallic coordination polymers: syntheses structures properties (M=Ni+2/M-=Ag+1 ,Cd+2 ,Zn+2) [PDF]

Kirkuk Journal of Science, 2016
In this paper a series of new mono and heterometallic Ni(II) complexes of the general formula[Ni(3-Hophdtc)2],[Ni(Ag(3-Hophdtc)2}2],NiLn(Ag(3-Hophdtc)2}2],NiM(3-Hophdtc)4] ,[Ni(L)nM(3-Hophdtc)4].3-Hophdtc=3-hydroxy phenyl dithiocarbamate.when n =
Hiba F. AL. Katib
doaj   +1 more source

MAPK phosphatase-1 represents a novel antiinflammatory target of glucocorticoids in the human endothelium [PDF]

, 2007
Glucocorticoids are well-established anti- inflammatory drugs thought to mainly act by inhibition of proinflammatory transcription factors like NF-κB.
Bubik, Martin F., Eilken, Hanna M., Fürst, Robert, Kiemer, Alexandra K., Schroeder, Timm, Vollmar, Angelika M., Zahler, Stefan   +6 more
core   +1 more source

Causal Association Between Plasma Proteins and Pericarditis: A Mendelian Randomization Study With Therapeutic Target Identification

Mediators of Inflammation, Volume 2026, Issue 1, 2026.
Background Observational studies demonstrate that pro‐inflammatory cytokines play a critical role in pericarditis. However, the causal association between circulating plasma proteins and pericarditis remains unestablished. Objective This research aimed to assess the causal association between plasma proteins and pericarditis and to investigate ...
Zhexuan Chen, Zongqiang Chen, Lingfeng Peng, Huankai Zhang, Ali Dawood   +4 more
wiley   +1 more source

Dithiocarbamates effectively inhibit the α-carbonic anhydrase from Neisseria gonorrhoeae

Journal of Enzyme Inhibition and Medicinal Chemistry, 2022
Recently, inorganic anions and sulphonamides, two of the main classes of zinc-binding carbonic anhydrase inhibitors (CAIs), were investigated for inhibition of the α-class carbonic anhydrase (CA, EC 4.2.1.1) from Neisseria gonorrhoeae, NgCA.
Simone Giovannuzzi, Nader S. Abutaleb, Chad S. Hewitt, Fabrizio Carta, Alessio Nocentini, Mohamed N. Seleem, Daniel P. Flaherty, Claudiu T. Supuran   +7 more
doaj   +1 more source

Crystal structure of bis(μ2-di-n-butyldithiocarbamato-κ3S,S′:S;κ3S:S:S′)-hexacarbonyl-di-rhenium(I), C24H36N2O6Re2 [PDF]

, 2018
C24H36N2O6Re2, triclinic, P¯1 (no. 2), a=10.3013(2) Å, b=11.3471(2) Å, c=14.5967(3) Å, α=72.540(2)°, β=73.074(2)°, γ=85.369(2)°, V =1557.05(6) Å3, Z =2, Rgt(F)=0.0214, wRref(F2)=0.0466, T =100(2 ...
Halcovitch, Nathan R., Heard, Peter *, Lee, See Mun *, Tiekink, Edward R. T. *   +3 more
core   +1 more source

Applications of N─F─Based Reagents in the Synthesis of Organochalcogen Compounds

Asian Journal of Organic Chemistry, Volume 14, Issue 12, December 2025.
Herein, we provide a comprehensive review of recent advances in synthetic strategies to access organochalcogen‐decorated compounds using N─F reagents as efficient oxidants for converting chalcogen–chalcogen bonds into electrophilic chalcogen‐based species.
Thiago Anjos, Mateus W. Rambo, Damiano Tanini, Alan Diego C. Santos, Ricardo F. Schumacher, Filipe Penteado   +5 more
wiley   +1 more source