Results 61 to 70 of about 601 (144)

The Catalytic Asymmetric Allylic Alkylation of Acyclic Enolates for the Construction of Quaternary and Tetrasubstituted Stereogenic Centres

open access: yesChemistry – A European Journal, Volume 30, Issue 20, April 5, 2024.
This review describes the catalytic asymmetric allylic alkylation (AAA) of acyclic prochiral nucleophiles, namely enolates, as a means of accessing congested quaternary and tetrasubstituted stereogenic centres. In particular, strategies for the stereocontrolled access to acyclic enolate nucleophiles, as well as the impact of enolate geometry on the ...
Connor M. Griffiths   +1 more
wiley   +1 more source

Electrochemical Behavior of Quinones Classically Used for Bioenergetical Applications: Considerations and Insights about the Anodic Side

open access: yesChemElectroChem, Volume 11, Issue 5, March 1, 2024.
In this article, the electrochemical behaviour of some substituted quinones (dichloro‐; dimethyl‐; phenyl) is revisited in aqueous media using chronoamperometry, cyclic and steady‐state voltammetry. In particular, the calculation of the number of electrons involved in the hydroquinone/quinone couple may be distorted due to kinetic limitations. A simple
Guillaume Longatte   +4 more
wiley   +1 more source

Time-Resolved Resonance Raman Spectroscopic Studies on the Radical Anions of Methyl-1,4-benzoquinone and 2,6-Dimethyl-1,4-benzoquinone

open access: yes, 2002
Time-resolved resonance Raman spectroscopy (TR3) and density functional calculations have been used to study the effect of asymmetric substitution of methyl group on the structure and vibrational spectra of the radical anion of benzoquinone.
Mohapatra, Himansu, Umapathy, Siva
core   +1 more source

Electrode Treatments for Redox Flow Batteries: Translating Our Understanding from Vanadium to Aqueous‐Organic

open access: yesAdvanced Science, Volume 11, Issue 1, January 5, 2024.
Electrodes are often treated chemically to mitigate the voltage losses in redox flow batteries (RFBs) and improve RFBs performance. Here, electrode treatments are compared for vanadium‐based RFBs under similar operating conditions to identify promising treatments for industrial implementation.
Harsh Agarwal   +5 more
wiley   +1 more source

The TvPirin gene is necessary for haustorium development in the parasitic plant Triphysaria versicolor [PDF]

open access: yes, 2011
The rhizosphere is teemed with organisms that coordinate their symbioses with plant roots through chemical signals. Chemicals also mediate associations between roots of different plants; the most obvious being those between parasitic Orobanchaceae and ...
Tomilov, A   +13 more
core   +1 more source

Dearomatization of Indoles via Palladium-Catalyzed Allylic C–H Activation

open access: yes, 2016
The first Pd-catalyzed allylic dearomatization of substituted indoles triggered by C–H bond activation is reported. The presence of a catalytic amount of 2,5-DMBQ is proven to be a key factor for the high yield. This one-pot tandem allylic C–H activation/
Shi-Xia Li (1447516)   +4 more
core   +1 more source

Modelling Quinones using Density Functional Theory

open access: yes, 2022
We modelled benzoquinone (BQ), dichlorobenzoquinone (DCBQ), and dimethylbenzoquinone (DMBQ) using the ORCA quantum chemistry computation suite. We obtained singlepoint energies, electron and spin densities, and the hyperfine coupling values for each ...
Gruszecki, Elijah   +4 more
core   +1 more source

Studies on the antiproliferative and antimetabolic effect of the dietary supplement Avemar on human gastrointestinal tumor cells

open access: yes, 2017
Unter dem Namen Avemar sind fermentierte Weizenkeimlinge als onkologisches Supportivprodukt erhältlich. Der hohe Anteil an 2,6-Dimethoxy-1,4-benzochinonen (DMBQ) in Avemar soll für das \(in\) \(vitro\) und \(in\) \(vivo\) belegte antikanzerogene ...
Hahlbrock, Theresa
core  

DataSheet_1_Phenolic signals for prehaustorium formation in Striga hermonthica.pdf

open access: yes, 2022
Striga hermonthica is a root parasitic plant that causes considerable crop yield losses. To parasitize host plants, parasitic plants develop a specialized organ called the haustorium that functions in host invasion and nutrient absorption. The initiation
Natsumi Aoki (2821997)   +6 more
core   +1 more source

Striga hermonthica Del (Benth.): Biology of the host/parasite relationship [PDF]

open access: yes, 1993
Striga hermonthica is a parasitic angiosperm that attaches to the roots of cereal hosts and causes severe reductions in crop yields m the semi-arid tropics of Africa. Striga seeds germinate in response to chemicals exuded by the host root.
Murphy, Alexandra Marie
core  

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