Results 141 to 150 of about 3,716,472 (288)

Research Progress of Room‐Temperature Phosphorescence Materials Based on Reversible Bonding Interactions

open access: yesAggregate
Recently, organic room‐temperature phosphorescence (RTP) has been greatly developed. The design strategies for common RTP materials are highly dependent on enhancing the intersystem crossing (ISC) efficiency or constructing a rigid ordered ...
Dan Li, Jie Yang, Zhen Li
doaj   +1 more source

Graded Metallopolymer Structures with Shape‐Memory Abilities via DLP‐Based 3D‐Printing

open access: yesAdvanced Functional Materials, EarlyView.
This study presents the digital light processing (DLP) based 3D printing of graded metallopolymers featuring shape‐memory abilities. The permanent shape can be recovered in two distinct steps with excellent rates. The obtained graded prints range from simple rod‐like structures to complex hollow materials.
Michael Klein   +6 more
wiley   +1 more source

Mussel‐Inspired and Recyclable Cardanol‐Based Supramolecular Networks for Multifunctional and Sustainable Resins

open access: yesEcoMat
Dynamic covalent epoxy resins integrate the merits of thermoplastics and thermosets, enabling reprocessability while maintaining covalent crosslinking. However, achieving simultaneous shape memory, intrinsic flame retardancy, and antibacterial properties
Yun Hu   +6 more
doaj   +1 more source

Covalent Functionalization of 2D Semiconductors: A Roadmap to Advanced Electronic Devices

open access: yesAdvanced Functional Materials, EarlyView.
This Review presents recent advances in the covalent functionalization strategies for two‐dimensional semiconductors and their implementation in modern technologies. Layered materials are modified through diverse molecular chemistries (e.g., thiols, diazonium salts, alkyl halides, and electron‐deficient species) to tailor their surface properties ...
Ramiro Quirós‐Ovies   +2 more
wiley   +1 more source

Dynamic Covalent Synthesis Applied to Optoelectronic and Energy Materials: Design, Applications and Limitations

open access: yes
International audienceDynamic Covalent Chemistry, consisting in the use of dynamic covalent bonds (DCBs) to create complex objects by working at the thermodynamic equilibrium, has undeniable advantages for the preparation of conjugated systems with ...
David, Arthur, H G   +3 more
core   +1 more source

A persistent germylyne radical enabling reversible σ-dimerization and diverse bond activation

open access: yesNature Communications
The reversible σ-dimerization of radicals is a fundamental process in bond formation and cleavage, yet achieving this with an isolable heavy carbyne analogue has remained a paramount challenge.
Xingyu Yang   +9 more
doaj   +1 more source

Deciphering the Photopolymerization‐Induced Nanostructures and Interface Formation for Submicrometer Additive Manufacturing

open access: yesAdvanced Functional Materials, EarlyView.
This work reveals the UV‐curing‐induced monomer‐rich domain, oligomer‐rich domain, and entangled oligomer domain. The cured submicron films in stressed state induce interlayer nano‐wrinkle structures during the deposition of the second layer. Stress‐free cured films in relaxed state form non‐diffusive, diffusive and semi‐diffusive interlayer ...
Shouzheng Chen   +13 more
wiley   +1 more source

Accurate quantum-centric simulations of intermolecular interactions

open access: yesCommunications Physics
Modelling and simulating non-covalent interactions is challenging, as they are inherently weak, dynamic, and system-specific. Common predictive methods often require trading the accuracy for reducing the otherwise cumbersome computational cost.
Danil Kaliakin   +12 more
doaj   +1 more source

Genetically Programmed Shape‐Morphing of Engineered Living Materials

open access: yesAdvanced Functional Materials, EarlyView.
Here, bacterial and mammalian engineered living materials (ELMs) are presented, in which living cells direct genetically programmed and enzymatically mediated shape‐morphing. The resulting deformation and shape‐recovery can be actuated in a genetically controlled manner by an ELM incorporating out‐of‐equilibrium counteracting biochemical reactions with
Jan Becker   +7 more
wiley   +1 more source

Protein‐Nanoarchitectures for Low‐Field Intracellular Electro‐Immunomodulation

open access: yesAdvanced Functional Materials, EarlyView.
DHQ‐SDH‐mediated binding of AuNPs drives the formation of interconnected, chain‐like nanoarchitectures with enhanced electrical conductivity. These conductive assemblies undergo macrophage uptake and enable low‐field electrical stimulation, promoting M1‐to‐M2 phenotypic switching with decreased iNOS and increased CD206 expression. Such protein‐mediated
Viktoriya Pakharenko   +7 more
wiley   +1 more source

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