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Bioresponsive nanomedicines based on dynamic covalent bonds

Nanoscale, 2021
Efficient drug delivery to target tissues is essential for improved outcomes. Bioresponsive nanomedicine with dynamic covalent bonds (DCBs) is promising.
Xiaoqian Xin   +6 more
openaire   +2 more sources

Mechanical bonds and dynamic covalent bonds

Materials Chemistry Frontiers, 2020
Jishan Wu and Fraser Stoddart introduce the Materials Chemistry Frontiers themed collection on mechanical bonds and dynamic covalent bonds.
Jishan Wu, J. Fraser Stoddart
openaire   +1 more source

Interplay between chalcogen bonds and dynamic covalent bonds

Organic Chemistry Frontiers, 2022
A combination of chalcogen bonds, one type of emerging non-covalent bonding force, and imine bonds, allow the control of the dynamic covalent chemistry with orbital interactions and the reversal of kinetic and thermodynamic selectivity.
Shuaipeng Jia, Hebo Ye, Lei You
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Tuning the Fluorescence in Dynamic Covalent Bonded Liquid Crystals

ACS Applied Materials & Interfaces, 2022
A series of emissive liquid crystalline materials based on salicylidene derivatives is reported and investigated with respect to their thermoresponsive and mechanochromic properties. Single-crystal analysis and temperature-dependent powder X-ray diffraction measurements allowed us to correlate the intermolecular organization of the mesogens with ...
Meik Blanke   +6 more
openaire   +3 more sources

Dynamic Covalent Bonds in Polymeric Materials

Angewandte Chemie International Edition, 2019
AbstractDynamic covalent bonds (DCBs) have received significant attention over the past decade. These are covalent bonds that are capable of exchanging or switching between several molecules. Particular focus has recently been on utilizing these DCBs in polymeric materials.
Progyateg Chakma, Dominik Konkolewicz
openaire   +2 more sources

A transient non-covalent hydrogel by a supramolecular gelator with dynamic covalent bonds

New Journal of Chemistry, 2021
In aqueous solution, equilibrium self-assembly and gelation occur at higher concentration but on addition of EDC non-equilibrium self-assembly and transient hydrogels are formed at low concentration, which dissolve upon anhydride hydrolysis.
Sahabaj Mondal, Debasish Haldar
openaire   +1 more source

Templated Chromophore Assembly by Dynamic Covalent Bonds

Angewandte Chemie, 2015
AbstractThrough the simultaneous use of three orthogonal dynamic covalent reactions, namely disulfide, boronate, and acyl hydrazone formation, we conceived a facile and versatile protocol to spatially organize tailored chromophores, which absorb in the blue, red, and yellow regions, on a preprogrammed α‐helix peptide. This approach allowed the assembly
Rocard, Lou   +3 more
openaire   +3 more sources

Covalent capture of dynamic hydrogen-bonded assemblies

Chemical Communications, 2000
Covalent linkage of the three calix[4]arene units in hydrogen-bonded assemblies 13(DEB)6via a threefold ring closing metathesis (RCM) reaction quantitatively converts the dynamic assemblies into covalent systems (123-membered macrocycles) that can be easily characterized using MALDI-TOF MS and HPLC.
Cardullo, F.   +8 more
openaire   +3 more sources

3D printable adhesive elastomers with dynamic covalent bond rearrangement

Soft Matter, 2023
Soft 3D-printable adhesive elastomers with self-healing capabilities were formulated. These materials were 3D printed into complex structures and used to modify soft robots for shape-selective lifting.
Shiwanka V. Wanasinghe   +9 more
openaire   +2 more sources

H-Shaped Supra-Amphiphiles Based on a Dynamic Covalent Bond

Langmuir, 2012
The imine bond, a kind of dynamic covalent bond, is used to bind two bolaform amphiphiles together with spacers, yielding H-shaped supra-amphiphiles. Micellar aggregates formed by the self-assembly of the H-shaped supra-amphiphiles are observed. When pH is tuned down from basic to slightly acidic, the benzoic imine bond can be hydrolyzed, leading to ...
Guangtong, Wang   +3 more
openaire   +2 more sources

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