Results 271 to 280 of about 3,949,733 (388)

Surface Deposition of Dome‐Shaped Metal‐Organic Complexes: A New Approach to the Generation of Single‐Site Catalysts

open access: yesChemPlusChem, EarlyView.
This study describes the synthesis of a new dithia‐[2.1.1]‐(2,6)‐pyridinophane ligand and its molybdenum(0) tricarbonyl complex. Monolayers of the dome‐shaped complex on Au(111) are investigated by employing surface spectroscopic methods (infrared reflection absorption spectroscopy, X‐ray photoelectron spectroscopy, near‐edge X‐ray absorption fine ...
Küpra Yildiz   +4 more
wiley   +1 more source

KnowVolution of an Efficient Polyamidase through Molecular Dynamics Simulations of Incrementally Docked Oligomeric Substrates

open access: yesChemSusChem, EarlyView.
Managing synthetic polymer waste is a major challenge. While enzymatic polyamide (PA) hydrolysis holds great recycling potential, it is limited by ineffective polyamidases. The polyamidase NylCp2‐TS is evolved through random mutagenesis and incremental docking, yielding NylC‐HP with enhanced activity and stability.
Hendrik Puetz   +6 more
wiley   +1 more source

Dynamic Morphological Transformation and Self‐Assembly of DNA‐Functionalized Cellulose Nanocrystal Building Blocks

open access: yesChemSusChem, EarlyView.
We present a simple strategy for dynamic rod‐to‐sphere‐to‐rod morphological transformation and DNA‐mediated self‐assembly of cellulose nanocrystal building blocks into slab‐like architectures in colloidal states. Our approach opens a sustainable, scalable pathway toward biocompatible self‐assembly architectures that may address critical challenges in ...
Jinsu Park   +2 more
wiley   +1 more source

Upcycling of Waste Poly(ethylene Terephthalate): Ammonolysis Kinetics of Model Bis(2‐Hydroxyethyl Terephthalate) and Particle Size Effects in Polymeric Substrates

open access: yesChemSusChem, EarlyView.
Chemical upcycling of poly(ethylene terephthalate) (PET) through ammonolysis is pursued. Model studies convert bis(2‐hydroxyethyl) terephthalate to terephthalamide. Diffusional limitations are explored using varying PET particle sizes and are profoundly important; for particles only 1 millimeter thick, the conversion rate decreases by a factor of ten ...
Richard‐Joseph L. Peterson   +5 more
wiley   +1 more source

Approach to Tuning the Dispersion Stability of TEMPO‐substituted Polymer Nanoparticles for Aqueous Organic Redox Flow Batteries

open access: yesChemSusChem, Accepted Article.
Hydrophilic redox polymer nanoparticles with zwitterionic moieties were synthesized to improve material utilization for semi‐solid redox flow batteries. TEMPO was chosen as the charge storage moiety, taking advantage of its high redox‐activity in pH‐neutral aqueous electrolytes.
Kohei Ishigami   +2 more
wiley   +1 more source

Dynamic Recrystallization Behavior and Corrosion Resistance of a Dual-Phase Mg-Li Alloy. [PDF]

open access: yesMaterials (Basel), 2018
Liu G   +7 more
europepmc   +1 more source

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