Results 211 to 220 of about 23,607 (294)

On the road to Cybathlon 2024: lessons learned from the Polimi FES-bike team. [PDF]

open access: yesJ Neuroeng Rehabil
Savona D   +9 more
europepmc   +1 more source

Emerging Trends in Organic Photoreactions Utilizing Disulfides

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Disulfides are versatile, nontoxic alternatives to metal photocatalysts. This review explores their role as photoactivated thiyl‐radical precursors and bifunctional catalysts (HAT/electron shuttling) in diverse transformations. Strategies for electronic tuning and development into recyclable heterogeneous materials are highlighted for sustainable ...
Sunil Kumar   +3 more
wiley   +1 more source

Chan–Lam Cross‐Coupling With Alkylboron Reagents: From Transmetallation to Radical Pathways

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Alkylative Chan–Lam coupling overcomes intrinsic transmetallation limitations of alkylboron reagents by engaging radical pathways. Recent advances reveal how radical and radical–polar crossover mechanisms enable mild C(sp3)—heteroatom bond formation. This minireview highlights key mechanistic insights and emerging strategies that transform alkylboron ...
Nicolas G.‐Simonian   +3 more
wiley   +1 more source

1,2‐Diazetidines − Structure, Synthesis, and Functionalization

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
1,2‐Diazetidines are saturated four‐membered heterocycles featuring two adjacent nitrogen atoms. Despite recent advances in their synthesis and promising potential in medicinal chemistry, the chemistry of these cyclic hydrazines remains underexplored.
Stefan Roesner
wiley   +1 more source

Total Synthesis of Novel Oxylipins: Plasmodiophorols A, C, and Epimers

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
The first total syntheses of plasmodiophorols A and C, recently identified α‐linolenic acid‐derived oxylipins, were achieved from chiral cyclopentafuranone in 12–13 steps. The routes use enzymatic desymmetrization, epimerization, and diastereoselective Grignard addition, providing stereocontrolled access to the natural products and reliable standards ...
Alexandre Guy   +3 more
wiley   +1 more source

Divergent Synthesis of Polycyclic Derivatives via Gold Catalysis

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
Gold(I)‐catalyzed cycloisomerization enables the formation of complex 3D structures from simple enyne precursors. This study presents a divergent strategy to synthesize functionalized bicyclic and tricyclic scaffolds from a common alkynyl ketone.
Emilie Gentilini   +4 more
wiley   +1 more source

More tools to uncover cancer cells. [PDF]

open access: yesMol Ther Oncol
Pignataro MF, Santos J.
europepmc   +1 more source

Bidirectional sleep‐seizure interactions and orexin in a mouse model of tuberous sclerosis complex‐related epilepsy

open access: yesEpilepsia, EarlyView.
Abstract Objective A strong bidirectional relationship exists between epilepsy and sleep, with seizures often occurring more frequently in sleep and, in turn, sleep being disrupted by seizures. However, the mechanistic basis of seizure–sleep interactions is poorly understood.
Nicholas R. Rensing   +4 more
wiley   +1 more source

Multi-omics data integration from patients with carotid stenosis illuminates key molecular signatures of atherosclerotic instability. [PDF]

open access: yesGenome Med
Das V   +14 more
europepmc   +1 more source

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