Results 221 to 230 of about 1,124,954 (291)

Monitoring the Microwave Synthesis of d0‐Free Disordered Rocksalt Cathodes Using In Situ Infrared Pyrometry

open access: yesAngewandte Chemie, EarlyView.
Despite its promise for producing metastable materials, the mechanisms underlying solid‐state microwave synthesis remain poorly understood. By combining in situ thermography with x‐ray diffraction and solid‐state NMR, this study uncovers a surprising order–disorder–order reaction pathway during the microwave synthesis of the Li1.1Mn0.9O1.9F0.1${\rm Li ...
Erick A. Lawrence   +8 more
wiley   +1 more source

Pyridinium Cations Act as Charge Reservoirs in Expanded Halide Perovskite Analogs at High Pressure

open access: yesAngewandte Chemie, EarlyView.
Redox‐innocent pyridinium derivatives can act as charge reservoirs in expanded tin‐iodide perovskite analogs. Material compression reduces the energy gap between the pyridinium π* acceptor orbital and the valence‐band maximum, facilitating electron transfer from the framework to the molecules and thereby significantly increasing electronic conductivity
Christina R. Deschene   +7 more
wiley   +1 more source

A Stellar magnesium to silicon ratio in the atmosphere of an exoplanet. [PDF]

open access: yesNat Commun
Sanchez JA   +19 more
europepmc   +1 more source

Accelerating Phosphate Transport Across Membranes via Synergistic Chemical‐Electrochemical Carriers

open access: yesAngewandte Chemie, EarlyView.
A new membrane design principle based on synergistic chemical and electrochemical carriers is proposed to construct an electro‐driven carrier‐conducting membrane for high‐throughput phosphate transport. Monodispersed ferrihydrite nanoparticles embedded within the membrane act as built‐in phosphate carriers, enabling accelerated phosphate migration via ...
Lei Xia   +9 more
wiley   +1 more source

Defect‐Rich CoNi Prussian Blue Analogues Enable Highly Selective Electrochemical Hydrogen Peroxide Production

open access: yesAngewandte Chemie, EarlyView.
Introducing [Co(CN)6]3− defects into CoNi Prussian Blue analogues exposes square‐planar Ni–N4 active sites, leading to remarkable H2O2 selectivity during the electrochemical oxygen reduction reaction in alkaline media. ABSTRACT Decentralized electrosynthesis of hydrogen peroxide (H2O2) via the two‐electron oxygen reduction reaction (2e− ORR) offers a ...
Kai Sun   +4 more
wiley   +1 more source

The chemistry of habitable oceans in the Solar system. [PDF]

open access: yesNat Commun
Hao J   +17 more
europepmc   +1 more source

Tailoring Photochromism Beyond Human Eye Visibility: On/Off Switchable NIR Absorption in an Aluminosilicate

open access: yesAngewandte Chemie, EarlyView.
A new photochromic material was developed. Its on/off‐switchable absorption band is situated completely outside the human eye's visibility, in the near‐infrared (NIR) region, a feature never reported before. The photochromism mechanism in this aluminosilicate is elucidated by combining experimental as well as computational results, and the material's ...
Bettiina Muurinen   +15 more
wiley   +1 more source

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