Results 271 to 280 of about 7,641,749 (323)

Beyond Presumptions: Toward Mechanistic Clarity in Metal‐Free Carbon Catalysts for Electrochemical H2O2 Production via Data Science

open access: yesAdvanced Materials, EarlyView.
Metal‐free carbon catalysts enable the sustainable synthesis of hydrogen peroxide via two‐electron oxygen reduction; however, active site complexity continues to hinder reliable interpretation. This review critiques correlation‐based approaches and highlights the importance of orthogonal experimental designs, standardized catalyst passports ...
Dayu Zhu   +3 more
wiley   +1 more source

Spin‐Split Edge States in Metal‐Supported Graphene Nanoislands Obtained by CVD

open access: yesAdvanced Materials, EarlyView.
Combining STM measurements and ab‐initio calculations, we show that zig‐zag edges in graphene nanoislands grown on Ni(111) by CVD retrieve their spin‐polarized edge states after intercalation of a few monolayers of Au. ABSTRACT Spin‐split states localized on zigzag edges have been predicted for different free‐standing graphene nanostructures.
Michele Gastaldo   +6 more
wiley   +1 more source

A Cu‐Based Near‐IR Active MOF with an Ion‐Pair Guest Exhibiting Versatile and Selective Gas‐Solid Reactivity

open access: yesAdvanced Materials, EarlyView.
The new Cu‐containing MOF (Me2NH2)(CuICl2)@[Cu4(INA)4Cl2O]·1.5dmf (3) contains a cation and an anion as guests and shows UV‐near‐mid‐IR absorption and near‐IR emission. MOF 3 shows gas‐solid reactivity in the presence of NH3 and HCOOH to yield two new 3D MOF.
Rajat Saha   +10 more
wiley   +1 more source

Peptide‐Induced Ferroelectricity in Charge‐Transfer Supramolecular Materials

open access: yesAdvanced Materials, EarlyView.
Bio‐inspired supramolecular charge‐transfer amphiphiles self‐assemble into nanoribbons in water, where peptide chirality‐induced symmetry breaking generates robust ferroelectricity across multiple systems. These water‐processable organic ferroelectrics also enhance neuronal outgrowth and electrophysiological maturity, offering a versatile strategy for ...
James V. Passarelli   +15 more
wiley   +1 more source

Operando X‐ray Spectroscopy Study of Pd and Pd–Au Laterally Condensed Catalysts during Selective Acetylene Hydrogenation: The Role of Carbon

open access: yesAdvanced Materials, EarlyView.
The selective hydrogenation of acetylene over laterally condensed Pd and Pd–Au catalysts (LCCs) was investigated using operando X‐ray absorption and photoelectron spectroscopy in combination with density functional theory. Pd‐LCCs were found to incorporate significantly more carbon into the metal lattice than Pd–Au LCCs, where the carbon uptake governs
Eylül Öztuna   +22 more
wiley   +1 more source

Toward Energy Efficient Electrochemical Valorization of Waste Nitrate and Sulfide

open access: yesAdvanced Materials, EarlyView.
This work introduces an integrated electrochemical strategy couples nitrate reduction with sulfide oxidation for energy‐efficient wastewater valorization. A Cu‐Co dual‑site catalyst, engineered for close proximity, promotes *NO2 relay and subsequently NH3 formation, enabling the system to operate at substantially reduced cell voltages and produce high ...
Bihao Hu   +5 more
wiley   +1 more source

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