Cyclo‐P5− Revisited: The Surprisingly Stable Uncoordinated Pentaphospholide Anion
The addition of [2.2.2]cryptand to alkali metal heptaphosphides M3P7 (M = Na, K) leads to the formation of the salts [M([2.2.2]cryptand)][cyclo‐P5]. Although the cyclo‐P5− anion is spectroscopically known since the 1980s it was so far prepared and handled only in solution.
Moritz Ernst+4 more
wiley +1 more source
Identifying High Ionic Conductivity Compositions of Ionic Liquid Electrolytes Using Features of the Solvation Environment. [PDF]
Thorat A+5 more
europepmc +1 more source
An Update: Enzymatic Synthesis for Industrial Applications
Supported by rapid technological advancements, biocatalytic applications have matured into a sustainable, scalable, and cost‐competitive alternatives to established chemical catalysis. This review presents the most recent examples of enzyme‐based solutions for the manufacturing of molecules with extended carbon‐carbon frameworks and multiple ...
Thomas Bayer+4 more
wiley +1 more source
Are changes in physical activity associated with depression? A follow-up study of 1,950 individuals. [PDF]
Queiroga LL+5 more
europepmc +1 more source
Reactivity of Pnictaalumenes towards 1,3‐Dipole Molecules
Alkynes undergo 1,3‐dipolar cyclisation reactions with organic azides giving 1,2,3‐triazoles. Pnictaalumenes RPn=AlRˈ are the isoelectronic congeners of alkynes, hence a similar reactivity towards 1,3‐dipole molecules is expected. Herein, we report the reactions of DippTerPn=AlCp* (DippTer = 2,6‑(2,6‐iPr2C6H3)‐C6H3, Cp* = [Me5C5]−, Pn = P, As) towards ...
Tim Wellnitz+7 more
wiley +1 more source
Admissions to MD-PhD programs: how well do application metrics predict short- or long-term physician-scientist outcomes? [PDF]
Brass LF+3 more
europepmc +1 more source
Solution blow spinning PTFE‐SiO2 membrane for membrane assisted solvent extraction. ABSTRACT An ultrafine‐fibrous polytetrafluoroethylene (PTFE)–SiO2 membrane was successfully fabricated using the solution blow spinning (SBS) method. This membrane demonstrated superhydrophobicity (water contact angle > 150°) and oleophilicity (ethyl acetate contact ...
Yaozhong Zhang+2 more
wiley +1 more source
Azacitidine-induced bullous pemphigoid-like localized toxic reaction. [PDF]
Nogueira RBE+7 more
europepmc +1 more source
Ultrafast Demagnetization Through Femtosecond Generation of Non‐Thermal Magnons
A fully ab initio parametrized model is developed to describe out‐of‐equilibrium magnon dynamics in ferromagnetic metals. Applying this model to ultrafast laser‐induced demagnetization, it is revealed that the generation of non‐thermal magnons provides a sizable demagnetization within 200 fs in excellent comparison with experiments, which establishes ...
Markus Weißenhofer, Peter M. Oppeneer
wiley +1 more source
Clinical, imaging, and biofluid correlates of Lyme polyradiculitis in a case report of neuroborreliosis. [PDF]
Duong MT+10 more
europepmc +1 more source