Results 151 to 160 of about 110,658 (265)

Bis(2‐Adamantyl)Magnesium: Synthesis, Structure, and Applications of a Versatile and Shelf‐Stable 2‐Adamantyl Anion Equivalent

open access: yesChemistry – A European Journal, EarlyView.
At last, the long‐sought bis(2‐adamantyl)magnesium reagent has been prepared in high yield as a stable tetrahydrofuran/dioxane adduct and fully characterized by x‐ray crystallography. This potent nucleophile outperforms the corresponding Grignard in transmetallation and carbonyl addition reactions, opening new avenues in adamantyl organometallic and ...
Matthew V. DaCosta   +3 more
wiley   +1 more source

Implementation of a Novel Case-Based Session for Medical Students Focused on Artificial Intelligence Ethics. [PDF]

open access: yesMedEdPORTAL
Fernandes DM   +6 more
europepmc   +1 more source

Accurate Molecular Size Determination by Diffusion Ordered NMR Spectroscopy Based on an Improved Diffusion Model

open access: yesChemistry – A European Journal, EarlyView.
A semi‐empirical Stokes‐Einstein‐based model for describing the diffusion of organic, organometallic and coordination compounds is developed for the interpretation of diffusion constants obtained by diffusion‐ordered NMR spectroscopy (DOSY). This model uses the molecular volume as a descriptor and shows a high accuracy, enabling application to ...
Christian Urbank, Lisa Vondung
wiley   +1 more source

Dioxygen Reduction at a Cu(I) Complex Supported by a Macrocyclic N3O Ligand System

open access: yesChemistry – A European Journal, EarlyView.
A non‐reactive [CuI(14‐TMC)]+ complex is transformed to an efficient catalyst [CuI(14‐TMCO)]+ (TMCO = 4,8,12‐trimethyl‐1‐oxa‐4,8,12‐triazacyclotetradecane) for 4e−/4H+ reduction of O2 by N → O substitution. ABSTRACT CuI(14 TMCO) (1), involving a N3O‐macrocycle, reacts with O2 at cryogenic temperatures to yield an end‐on peroxodicopper(II) species.
Maximilian Schütze   +3 more
wiley   +1 more source

Revisiting Perfusion in the Forgotten Right Ventricle: Artificial Intelligence-Enhanced Quantification on PET/CT. [PDF]

open access: yesJ Nucl Med
Shanbhag A   +24 more
europepmc   +1 more source

Optimization of 3D‐Printed Structured Packings—Current State and Future Developments

open access: yesChemie Ingenieur Technik, EarlyView.
This paper gives an overview about structured packing development for distillation, surveying heuristic development cycles, computational fluid dynamics simulations, and additive manufacturing techniques. The emerging application of shape optimization to improve packings is emphasized, and its benefits, impact, and limitations are discussed.
Dennis Stucke   +3 more
wiley   +1 more source

Intra- and inter-observer reliability of spinal inflection point localization: a cross-sectional radiographic study. [PDF]

open access: yesEinstein (Sao Paulo)
Pajanoti GP   +6 more
europepmc   +1 more source

On the defence of responsible human judgement in peer review

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract Peer review is essential for scientific progress. When it works well, it combines expertise, fairness, proportionality, skepticism, generosity, and discretion. When it fails, it becomes a theatre for egotistical display, laziness, coercion, and, lately, reliance on artificial intelligence tools. Editors, reviewers, and authors must join forces
João B. P. Soares, Thomas A. Adams II
wiley   +1 more source

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