At last, the long‐sought bis(2‐adamantyl)magnesium reagent has been prepared in high yield as a stable tetrahydrofuran/dioxane adduct and fully characterized by x‐ray crystallography. This potent nucleophile outperforms the corresponding Grignard in transmetallation and carbonyl addition reactions, opening new avenues in adamantyl organometallic and ...
Matthew V. DaCosta +3 more
wiley +1 more source
Implementation of a Novel Case-Based Session for Medical Students Focused on Artificial Intelligence Ethics. [PDF]
Fernandes DM +6 more
europepmc +1 more source
A semi‐empirical Stokes‐Einstein‐based model for describing the diffusion of organic, organometallic and coordination compounds is developed for the interpretation of diffusion constants obtained by diffusion‐ordered NMR spectroscopy (DOSY). This model uses the molecular volume as a descriptor and shows a high accuracy, enabling application to ...
Christian Urbank, Lisa Vondung
wiley +1 more source
Can avatar affective valence determine whether virtual reality embodiment reduces implicit workplace ageism? [PDF]
Elyoseph R, Bodner E, Friedman D.
europepmc +1 more source
Dioxygen Reduction at a Cu(I) Complex Supported by a Macrocyclic N3O Ligand System
A non‐reactive [CuI(14‐TMC)]+ complex is transformed to an efficient catalyst [CuI(14‐TMCO)]+ (TMCO = 4,8,12‐trimethyl‐1‐oxa‐4,8,12‐triazacyclotetradecane) for 4e−/4H+ reduction of O2 by N → O substitution. ABSTRACT CuI(14 TMCO) (1), involving a N3O‐macrocycle, reacts with O2 at cryogenic temperatures to yield an end‐on peroxodicopper(II) species.
Maximilian Schütze +3 more
wiley +1 more source
Revisiting Perfusion in the Forgotten Right Ventricle: Artificial Intelligence-Enhanced Quantification on PET/CT. [PDF]
Shanbhag A +24 more
europepmc +1 more source
Optimization of 3D‐Printed Structured Packings—Current State and Future Developments
This paper gives an overview about structured packing development for distillation, surveying heuristic development cycles, computational fluid dynamics simulations, and additive manufacturing techniques. The emerging application of shape optimization to improve packings is emphasized, and its benefits, impact, and limitations are discussed.
Dennis Stucke +3 more
wiley +1 more source
Sobre o desenvolvimento das nossas concepções sobre a natureza e a constituição da radiação
A. Einstein
doaj +1 more source
Intra- and inter-observer reliability of spinal inflection point localization: a cross-sectional radiographic study. [PDF]
Pajanoti GP +6 more
europepmc +1 more source
On the defence of responsible human judgement in peer review
Abstract Peer review is essential for scientific progress. When it works well, it combines expertise, fairness, proportionality, skepticism, generosity, and discretion. When it fails, it becomes a theatre for egotistical display, laziness, coercion, and, lately, reliance on artificial intelligence tools. Editors, reviewers, and authors must join forces
João B. P. Soares, Thomas A. Adams II
wiley +1 more source

