Silylium‐Ion‐Initiated Disulfidation of Internal Alkynes With Disulfides
Silylium‐ion initiation enables the disulfidation of internal alkynes with diaryl disulfides. The catalytic turnover is maintained by the sulfonium ion ArS(ArSSAr)+ as a sulfenium‐ion carrier that reacts with an alkyne to form a thiirenium ion. Its ring opening by disulfide addition yields the 1,2‐bis(arylthio)‐substituted alkene product with E:Z > 95 ...
Dáiríne M. Morgan +2 more
wiley +1 more source
Correction to: Systematic review of prophylactic antibacterial agents for radiation‑induced oral mucositis in head and neck cancer. [PDF]
Alicea DS +8 more
europepmc +1 more source
We report the synthesis and characterization of a sulfated prism[5]arene host (Prism[5]MaxQ). Prism[5]MaxQ displays ultrahigh binding affinity (Ka up to 1012 M−1) toward hydrophobic (di)cations in phosphate‐buffered saline (PBS). The work positions Prism[5]MaxQ as a new member of the family of ultrahigh‐affinity hosts poised for use as a sequestrant in
Emmanuel A. Bazan‐Bergamino +1 more
wiley +1 more source
Phacoemulsification in a highly myopic, single-seeing, post-vitrectomized eye with an anterior chamber phakic intraocular lens: a surgical challenge. [PDF]
Kim RB +3 more
europepmc +1 more source
Multi‐state Photoswitching in Thienoquinoid‐Based Fluorescent Trithiophenes
A methine‐bridged trithiophene with a thienoquinoid core undergoes photoisomerization of both C═C bonds, affording three geometrical isomers in a ratio controlled by the irradiation wavelength. Despite full π‐conjugation, the system retains fluorescence, enabling wavelength‐addressable multi‐state switching with luminescent readout.
Rio Nishimura +3 more
wiley +1 more source
Pre-clinical impact of higher irrigation flow rates during pulsed field ablation with a variable loop circular catheter. [PDF]
Zou F +20 more
europepmc +1 more source
Reporter chemistry controls the operational window of liquid‐phase SERS. Para‐substituted benzenethiols induce distinct AuNPs colloidal regimes, ranging from delayed but stable hotspot formation to rapid flocculation‐dominated signal decay. The balance between SERS‐active‐state formation and colloidal loss defines whether a reporter provides reliable ...
Irene Calderon Gonzalez +2 more
wiley +1 more source
AASLD practice guidance on drug, herbal, and dietary supplement–induced liver injury
Hepatology, EarlyView.
Robert J. Fontana +6 more
wiley +1 more source
Reply to "comment on: Socioeconomic inequities in prostate cancer care: private versus public treatment settings pose a significant impact on overall survival". [PDF]
Costa ACS +6 more
europepmc +1 more source

