Results 31 to 40 of about 1,440 (127)

Chemical Ionization Mass Spectrometry: Fundamental Principles, Diverse Applications, and the Latest Technological Frontiers

Mass Spectrometry Reviews, EarlyView.
ABSTRACT The review examines the evolution of chemical ionization mass spectrometry (CI‐MS), a technique developed in 1966 by Field and Munson. CI is a soft‐ionization method that produces more intense molecular ions with less fragmentation than electron ionization (EI).
Malvika Dutt, Adriana Arigò, Giorgio Famiglini, Pierangela Palma, Achille Cappiello   +4 more
wiley   +1 more source

Data‐Independent Acquisition Mass Spectrometry in Tumor Classification and Cancer Biomarker Research

Mass Spectrometry Reviews, EarlyView.
Abstract Cancer treatment is far from optimal also because current classification systems do not reflect the complex molecular status of the tumor and its phenotype in sufficient detail. To construct molecular tumor classifiers, omics tools provide complex molecular data reflecting many aspects from genotype to phenotype.
Jan Simonik, Petr Lapcik, Pavla Bouchalova, Pavel Bouchal   +3 more
wiley   +1 more source

First 20 Years of Orbitrap Mass Spectrometry as the Mainstream Analytical Technique

Mass Spectrometry Reviews, EarlyView.
ABSTRACT This review traces the first 20 years of Orbitrap mass spectrometry as a mainstream high‑resolution and accurate‑mass (HR/AM) technology. It outlines the historical development of the Orbitrap analyzer, the evolution of major instrument families, and the key technological innovations that enabled its widespread adoption. Particular emphasis is
Alexander Makarov
wiley   +1 more source

17O Quadrupole Coupling Constants in Water

Magnetic Resonance in Chemistry, EarlyView.
In water clusters, first‐nearest‐neighbor interactions (1A and 1D) provide the largest contribution and are well captured by an additive donor–acceptor scheme, with improved accuracy upon inclusion of hydrogen bond distance dependence. Second nearest neighbor (D and A*) effects introduce smaller but systematic negative corrections, restoring near ...
Nabeeha Haque, Alexander G. de Dios, Angel C. de Dios   +2 more
wiley   +1 more source

Covalent Functionalization of NiFe Layered Double Hydroxides using Tris(Hydroxymethyl)Aminomethane

Small, EarlyView.
Covalent functionalization of NiFe layered double hydroxides with tris(hydroxymethyl)aminomethane enables controlled growth, enhanced structural order, and improved processability. Temporary TRIS anchoring promotes stable water‐based inks and binder‐free electrode fabrication, leading to enhanced oxygen evolution activity and long‐term stability under ...
Alvaro Seijas Da Silva, Federico Juarez‐Dominguez, Víctor Oestreicher, Martín Mizrahi, Diego Hunt, Bruno J. C. Vieira, Joao C. Waerenborgh, Valeria Ferrari, Gonzalo Abellán   +8 more
wiley   +1 more source

Reactivity of Oxidized Porous Silicon with Calcium Ion in Aqueous Media: Stability, pH Behavior, and Host‐Guest Strategies

Small, EarlyView.
Oxidized porous silicon, composed of an elemental silicon porous skeleton coated with a silica shell, reacts with aqueous Ca2+ to generate a mixed silica–calcium silicate matrix that is remarkably efficient at trapping small molecules. With an emphasis on the engineering of controlled‐release drug delivery systems, this study identifies the factors ...
Ruhan Fan, Qinglin Yang, Michael J. Sailor   +2 more
wiley   +1 more source

Advance in One‐Pot Synthesis of Polymer‐Coated Nanogold: Au(III)–Monomer Redox Reaction Initiates Radical Polymerization and Produces a Potential Nanotag Platform

Small, EarlyView.
Gold nanoparticles are prepared simultaneously with the formation of a polymer, whose growth is initiated by direct interaction of Au(III) with a vinyl‐type monomer. Nanoparticles produce stable, bioorthogonal SERS signal originating from an isonitrile/carbene‐type functionality covalently anchored to the gold surface.
Hana Charvátová, Ivana Šeděnková, Jiřina Hromádková, Ognen Pop‐Georgievski, Michal Babič   +4 more
wiley   +1 more source

Universal Confinement Length Governs Radical Depolymerization Kinetics in Nanoconfined Polymers

Small, EarlyView.
Analysis of PMMA depolymerization kinetics identifies a critical threshold under extreme nanoconfinement where segmental mobility saturation prevents further increases in depolymerization temperature. ABSTRACT Thermal depolymerization is typically studied in bulk, yet many systems involve polymers confined within nanoscale geometries. Understanding how
Uiseok Hwang, Ching‐Yu Wang, Zhanyuan Liu, John M. Vohs, Baekmin Q. Kim, Daeyeon Lee   +5 more
wiley   +1 more source

One million scans later: the evolution of the I16 material and magnetism beamline at Diamond Light Source

Journal of Synchrotron Radiation, EarlyView.
Beamline I16 at Diamond Light Source is a versatile X‐ray scattering instrument that combines tunable X‐ray energy and polarization, flexible diffraction geometries, and advanced sample environments for studies of electronic, magnetic, and structural phenomena.Here, we review the capabilities of beamline I16 at Diamond Light Source after nearly 20 ...
Aly H. Abdeldaim, Rebecca Scatena, James Hawkins, Gareth Nisbet, Daniel G. Porter, Graeme Barlow, Andy Marshall, Brian Nutter, Guillaume Beutier, Stephen P. Collins, Alessandro Bombardi   +10 more
wiley   +1 more source

Effects of Pistacia lentiscus Leaf‐Twig and Resin (Mastic) Oils on Salivary Flow in Healthy Individuals

Oral Diseases, EarlyView.
ABSTRACT Objective Pistacia lentiscus L. tree is known for its aromatic mastic gum containing terpenes α‐pinene and β‐myrcene, and has been applied as a traditional remedy in oral care for centuries. Previously, intranasal exposure to mastic resin volatiles increased salivary flow in healthy and dry‐mouth individuals. This study assessed the biological
Wiktoria Potocka, Luca van Eijndthoven, Marja L. Laine, Floris J. Bikker, Zainab Assy   +4 more
wiley   +1 more source