Results 221 to 230 of about 28,718 (310)

Direct Solar Power‐Driven Durable Ammonia Electrosynthesis From Nitrate Under Fluctuating Voltage Conditions

open access: yesAngewandte Chemie, EarlyView.
Isolated Sn sites on Cu(111) induce a highly asymmetric charge distribution, which promotes water dissociation, accelerates key intermediate hydrogenation, and suppresses competing hydrogen evolution. As a result, SnCu111 delivers NH3 Faradaic efficiencies above 90% over an 800 mV potential window and enables stable direct solar power‐driven NH3 ...
Xiaokang Wang   +8 more
wiley   +1 more source

Microenvironment Engineering as a Design Principle for Suppressing Catalyst Metal Loss

open access: yesAngewandte Chemie, EarlyView.
Under ionomer‐containing microenvironments, nonporous carbon supports enhance the retention of dissolved platinum ions, whereas porous carbon supports promote pore‐confined redeposition and mitigate net platinum loss. ABSTRACT Stability losses in platinum electrocatalysts arise from dissolution, redeposition, and restructuring processes that are ...
Sumin Lim   +4 more
wiley   +1 more source

Pt‐Mediated Co‐Adsorption of Hydroxyl and Nitrogen‐Heterocyclic Species Over Cu/CuO Heterostructure Enhances Coupled Azotriazole Electrosynthesis and Dual‐Electrode Hydrogen Production

open access: yesAngewandte Chemie, EarlyView.
Pt@Cu/CuO heterostructures were designed for electrochemical N─N coupling of 3,5‐diamino‐1H‐1,2,4‐triazole. Mechanism investigation revealed that the Pt sites mediated co‐adsorption of substrates and hydroxyl on Cu/CuO sites. The elaborate Pt@Cu/CuO achieved an ultralow working potential of 0.832 VRHE with a high FE of 95%. A long‐term stability of 600
Jiachen Li   +11 more
wiley   +1 more source

Linking Synthetic Materials Chemistry to Electrocatalytic Performance. [PDF]

open access: yesAngew Chem Int Ed Engl
Bagchi D   +3 more
europepmc   +1 more source

Proton‐Switching Regulates Interfacial Iodine Chemistry for Long‐Life Zinc–Iodine Batteries

open access: yesAngewandte Chemie, EarlyView.
A proton‐switchable imine‐linked framework is developed to dynamically regulate interfacial iodine chemistry in aqueous Zn–I2 batteries, where reversible protonation/deprotonation switches the host affinity between iodide and polyiodide species. This state‐dependent regulation suppresses shuttle‐induced side reactions while preserving fast iodine redox
Feifei Wang   +14 more
wiley   +1 more source

Large-scale identical-location electron microscopy enables quantifying nanoparticulate electrocatalyst degradation

open access: yes
Kamšek AR   +8 more
europepmc   +1 more source

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