Results 231 to 240 of about 28,718 (310)

Defect‐Rich CoNi Prussian Blue Analogues Enable Highly Selective Electrochemical Hydrogen Peroxide Production

Angewandte Chemie, EarlyView.
Introducing [Co(CN)6]3− defects into CoNi Prussian Blue analogues exposes square‐planar Ni–N4 active sites, leading to remarkable H2O2 selectivity during the electrochemical oxygen reduction reaction in alkaline media. ABSTRACT Decentralized electrosynthesis of hydrogen peroxide (H2O2) via the two‐electron oxygen reduction reaction (2e− ORR) offers a ...
Kai Sun, Yu Mao, Yongfang Zhou, Ziyun Wang, Geoffrey I. N. Waterhouse   +4 more
wiley   +1 more source

Tailoring Reconstruction of Co/Cu Mixed Oxide-Derived Tandem Electrocatalysts via <i>In Situ</i> Electrochemical Dissolution-Redeposition for Enhanced Nitrate-to-Ammonia Conversion. [PDF]

JACS Au
G Winkler ME, G Yoshimura R, S Rodrigues P, P Sales M, L Gomes K, T Neckel I, Figueroa SJA, B Souza J, Ticianelli EA, Singh N, B Lima FH, Cherevko S, Nagao R.   +12 more
europepmc   +1 more source

Coupled Fe3O4‐Cluster Precipitates and Single Fe‐Atom Catalysts Can Boost Oxygen Reduction via Concomitantly Accelerated Water Dissociation

Angewandte Chemie, EarlyView.
Fe3O4 clusters can be precipitated onto Fe–N–C SACs through a residual‐oxygen‐assisted precipitation approach. Compelling evidence, including operando spectroscopy and ab initio calculations, suggests that Fe3O4‐cluster precipitates not only induce asymmetric electronic structures of Fe‐N4 active center to optimize the OH* adsorption, but also ...
Cheng‐Kai Du, Xiongyi Liang, Fei‐Xiang Ma, Yutong Li, Zheng‐Qi Liu, Long Ma, Zeng Li, Liang Zhen, Yan Huang, Xiao Cheng Zeng, Cheng‐Yan Xu   +10 more
wiley   +1 more source

Electrocatalytic Activity of Delafossite CuCoO₂ for Alkaline Oxygen Evolution Reaction and Acidic Hydrogen Evolution Reaction. [PDF]

Materials (Basel)
Kim SY, Kim D, Choi YH.
europepmc   +1 more source

Acetylene Semi‐Hydrogenation by Photocatalysis

Angewandte Chemie, EarlyView.
Photocatalytic acetylene semi‐hydrogenation is an emerging light‐driven route to polymer‐grade ethylene, offering a mild alternative to energy‐intensive thermocatalysis. By replacing H2 co‐feed with water or other proton sources, these systems can achieve high selectivity under ambient conditions.
Anna Fortunato, Brando Adranno, Sharon Silloni, Marianna Barbieri, Claudia Masia, Francesca Arcudi, Luka Đorđević   +6 more
wiley   +1 more source

Correction to "Iridium-Based Mixed Transition Metal Oxide (Ir₃MO_x, M = Ni, Co, Fe) Incorporated in the Conducting Layer as an Electrocatalyst for Boosting the Oxygen Evolution Reaction". [PDF]

Small
europepmc   +1 more source

Rational Design of Ni³⁺-Rich Nickel Nitride Enables Paired Electrooxidation of Sterol and Hydrogen Evolution in a Flow Electrolyzer. [PDF]

Adv Sci (Weinh)
Li S, Wang J, Feng G, He J, Li K, Liu L, Wang Y, Jia Z, Xu Y, Zhong W, Zhong X, Wang J.   +11 more
europepmc   +1 more source

Functionalization‐Mediated Synthesis of Bridge‐Coordinated Fe Atoms on MoS2 Nanosheets for PEM Water Electrolyzers

Angewandte Chemie, EarlyView.
We report a functionalization‐mediated strategy to synthesize robust iron (Fe) atoms selectively coordinated at bridge sites on molybdenum disulfide (MoS2) nanosheets. The resulting b‐Fe‐MoS2 catalyst exhibits enhanced activity and durability for the hydrogen evolution reaction in proton exchange membrane water electrolyzers compared to atop ...
Zakaria Anfar, Haitham Maslouh, Yuwei Yang, Mathilde Moderne, Jiefeng Liu, Loïc Assaud, Mikhael Bechelany, Chrystelle Salameh, Kun Qi, Yuying Meng, Huali Wu, Ji Li, Nicholas M. Bedford, Damien Voiry   +13 more
wiley   +1 more source

High-performance CeO₂/rGO hybrid nanostructures as bifunctional electrocatalysts for water-splitting. [PDF]

RSC Adv
Staline C JA, Magdalane CM, Ramalingam G, Wabaidur SM, Dwivedi J.   +4 more
europepmc   +1 more source

CO2‐to‐CO Electrochemical Conversion With an Fe(I) Porphyrin Complex in Water

Angewandte Chemie, EarlyView.
Using in situ UV–vis/IR spectroelectrochemistry, we track CO2 reduction by a water‐soluble iron porphyrin. Rather than the usual [Fe0] intermediate in organic solvents, CO2 binds the electrogenerated [FeI] species and undergoes reductive C─O cleavage to stable [FeII‐CO]. This previously unexplored reaction pathway is facilitated by an aqueous H‐bonding
Andrew Howe, Aude Salamé, Ulysse Garnier, Marc Robert, Elodie Anxolabéhère‐Mallart, Mun Hon Cheah   +5 more
wiley   +1 more source