Results 171 to 180 of about 66,037 (288)

The Intricate Sabatier Optimality of Anion Electroreduction and Its Consequences for Nitrate Reduction

open access: yesAngewandte Chemie, EarlyView.
The Sabatier principle and volcano plots declare that optimal electrocatalysis is found in the middle between strong and weak binding of key intermediates. However, it is shown here that during anion electroreduction, strong and weak binding are potential‐dependent concepts and volcanoes are mobile.
Mattia Salomone   +2 more
wiley   +2 more sources

Photocatalytic Transfer Hydrogenation Using Plastic Hydrolysates as Hydrogen Donor

open access: yesAngewandte Chemie, EarlyView.
Plastic waste is transformed into functional amines via solar‐driven transfer hydrogenation. Soluble monomers from acid hydrolysis of waste polymers serve as a hydrogen (electron/proton)donors in the selective reduction of nitroarenes using a visible light active photocatalyst consisting of cobalt promoted molybdenum disulfide integrated in cyanamide ...
Papa K. Kwarteng   +2 more
wiley   +2 more sources

Atomic‐Scale Understanding of Selectivity Control in Nitrate Reduction on Cu(100) Under Acidic and Alkaline Conditions

open access: yesAngewandte Chemie, EarlyView.
A combination of ab initio molecular dynamics simulations and density functional theory calculations clarifies the pH‐dependent origin of the selectivity of nitrate reduction on Cu(100). ABSTRACT We investigate the nitrate reduction reaction (NO3 RR) on the Cu(100) surface using grand‐canonical density functional theory (GC‐DFT) under constant ...
Ebrahim Tayyebi, Kai S. Exner
wiley   +2 more sources

Electrolyte‐Replacement‐Free Continuous Electrocatalytic Desalination Coupled With CO2 Reduction at Record Throughput and Low Cost

open access: yesAngewandte Chemie, EarlyView.
A continuous electrocatalytic desalination system powered by CO2 electroreduction that eliminates electrolyte replacement through a self‐balancing circulating design. Using a five‐chamber architecture and an efficient cobalt‐based catalyst, it achieves ultrafast salt removal, high CO production efficiency, and stable long‐term operation, offering a ...
Man Liang   +8 more
wiley   +2 more sources

Spin‐State Modulation of Atomic Iron Sites Enables Efficient CO2 Electroreduction in Acid Medium

open access: yesAngewandte Chemie, EarlyView.
An axial oxygen ligand was added to shift the spin state of the single‐atom Fe site from low to medium spin. This change reduces the interfacial interaction with H3O+ and decreases the *CO desorption energy, thus enhancing CO2RR in acidic media.
Shanhe Gong   +13 more
wiley   +2 more sources

Engineering PtFe/LiO<sub>2</sub> Frontier Orbital Interaction in Li-O<sub>2</sub> Batteries. [PDF]

open access: yesNanomicro Lett
Zhou Y   +16 more
europepmc   +1 more source

Solar‐Driven Ammonia Synthesis From Nitrate Reduction Paired With CO2 Capture for Sustainable Agriculture via a Robust CuPd Heterojunction

open access: yesAngewandte Chemie, EarlyView.
Laser‐assisted synthesis of CuPd amorphous/crystalline heterojunction demonstrates >80% Faradaic efficiency for nitrate‐to‐ammonia electroreduction across wide potential windows. The integrated solar‐powered electrolyzer achieves 6% solar‐to‐ammonia energy efficiency at 0.4 sun, 6–20 mg h−1 CO2 capture rate, and stability exceeding 100 h.
Weihua Guo   +18 more
wiley   +2 more sources

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