Results 191 to 200 of about 28,205 (307)

Electrocatalytic oxidation of cysteine on a nafion-ruthenium oxide pyrochlore chemically modified electrode

open access: yes, 2014
The electrocatalytic oxidation of cysteine (CySH) to cystine (CyS-SCy) was noticed on the Nafion-ruthenium oxide pyrochlore chemically modified electrode.
Kumar, A.S.   +3 more
core  

Understanding the Catalytic Determinant role of Diaphorase‐Like Subunit in Formate Dehydrogenases via Redox Couples

open access: yesAdvanced Science, EarlyView.
A unique mechanism of catalytic bias regulated by diaphorase‐like subunit in formate dehydrogenase from Rhodobacter aestuarii is revealed. The diaphorase‐like subunit functions act as a biological “voltage rheostat” that controls the slow release of NADH to regulate redox balance, biasing the enzyme's catalytic preference toward CO2 reduction over ...
Kuncheng Zhang   +7 more
wiley   +1 more source

Lewis‐Acid Engineering with Neodymium Promoters as Synergistic Nd‐Ni Dual Sites for Enhanced Urea Oxidation

open access: yesAdvanced Science, EarlyView.
The integration of rare‐metal neodymium centers to engineer Lewis acid sites with nickel centers is proposed as highly efficient UOR catalysts. ABSTRACT The sluggish kinetics of the urea oxidation reaction (UOR) are strongly associated with the high energy barriers required for the C‐N cleavage and N‐N coupling steps.
Mingfan Li   +8 more
wiley   +1 more source

Tailored D‐π Conjugation Boosts Piezocatalytic CO2 Reduction in a Platinum(II)‐Acetylide Framework

open access: yesAdvanced Science, EarlyView.
The highly conjugated metalII‐acetylide framework demonstrates efficient ultrasound‐driven conversion of CO2 to CO. The piezoelectric field generated by ultrasound facilitates electron transfer from the tetraphenylene π‐column to the MII‐bis(acetylide) moiety, enabling CO2 activation. Compared to PdII‐ and NiII‐based analogues, the stronger d–π orbital
Mude Zhu   +6 more
wiley   +1 more source

Magnetically Boosted Water‐Splitting Performance in Metallic Glasses

open access: yesAdvanced Science, EarlyView.
A strategy for boosting water electrolysis efficiency using ultralow magnetic fields on soft‐magnetic MG wires is reported. Ni40Fe40P20 metallic glass exhibits superior overall water‐splitting performance (1.51 V @ 1000 mA cm−2) at 100 Oe, enabled by spin polarization in periodic surface magnetic domains to enhance orbital hybridization and net spin ...
Chaoqun Pei   +9 more
wiley   +1 more source

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