Results 61 to 70 of about 28,205 (307)

Toward Fast Proton Shuttling in Acidic Oxygen Evolution Reaction

open access: yesAdvanced Functional Materials, EarlyView.
This review establishes proton transfer dynamics as a descriptor governing acidic OER activity, moving beyond the kinetic constraints derived from the proton coupled electron transfer. We discuss how deprotonation governs classical mechanisms, including adsorbate evolution mechanism (AEM), lattice oxygen mechanism (LOM) and oxide path mechanism (OPM ...
Ashish Gaur   +3 more
wiley   +1 more source

Bacterial‐Electrochemical Platform Utilizing a MXene‐Peptide Hydrogel

open access: yesAdvanced Functional Materials, EarlyView.
A peptide‐based fibrillar hydrogel incorporating MXene facilitates efficient electron delivery to intracellular recombinant [FeFe]‐hydrogenase enzyme in E. coli, enabling sustained bioelectrochemical H2 production without engineered exoelectrogenicity pathways.
Oren Ben‐Zvi   +6 more
wiley   +1 more source

Coupling Anodic Activity and Stability at Ni‐Based Non‐Oxide Catalysts via Coordinating Alcohol Oxidation and Oxygen Evolution

open access: yesAdvanced Functional Materials, EarlyView.
A cooperative and competitive interrelationship between alcohol oxidation (AOR) and water oxidation (OER) was observed on a typical anode catalyst of Ni2P. In situ Raman spectroscopy and electrochemical analyses revealed a specific complementary mechanism between them, in which OER and AOR critically contribute to the activity and stability of anodic ...
Yong Yan   +10 more
wiley   +1 more source

Premonolayer oxidation of nanostructured gold : an important factor influencing electrocatalytic activity

open access: yes, 2009
The study of the electrodeposition of polycrystalline gold in aqueous solution is important from the viewpoint that in electrocatalysis applications ill-defined micro- and nanostructured surfaces are often employed.
Ippolito, Samuel J.   +4 more
core   +1 more source

Electrochemical alcohol oxidation reaction on Precious‐Metal‐Free catalysts: Mechanism, activity, and selectivity

open access: yesCarbon Neutralization
The electrochemical alcohol oxidation reaction (AOR) is pivotal for the development of sustainable energy. The complete oxidation of alcohols has attracted extensive attention as a vital process in fuel cells.
Jiawei Shi   +6 more
doaj   +1 more source

Preparation of MnO2/Ti electrocatalytic membrane and its performance in the treatment of emulsified oil wastewater

open access: yesGongye shui chuli
A high-performance MnO2-coated Ti-based electrocatalytic membrane(MnO2/Ti) was prepared by a simple and controllable electrodeposition method. The morphology, elemental content, valence distribution and electrochemical impedance of the prepared MnO2/Ti ...
LIU Baolin   +5 more
doaj   +1 more source

Electrocatalytic oxidation and reduction of S(IV) Species by 5,10,15,20-Tetrakis-Tetraferrocenylporphyrin-Modified Electrodes.

open access: yesInternational Journal of Electrochemical Science, 2013
5,10,15,20-tetrakis-tetraferrocenylporphyrin (TFcPH2) free ligand was synthesized and characterized by spectroscopic (UV-Vis, ⁎ 1HNMR, FT-IR) and electrochemical (cyclic voltammetry) techniques.
J.P. Muena, M. Villagrán, M.J. Aguirre
doaj   +1 more source

Support‐Controlled Reaction Pathways via Dynamic Sulfur‐Mediated Interfaces for Selective Urea Electrolysis

open access: yesAdvanced Functional Materials, EarlyView.
Sulfur‐doped graphitized carbon nanofibers act as adaptive catalyst–support platforms, enabling dynamic sulfur‐mediated reconstruction and strong metal–support interactions. This unique behavior enhances catalyst stability and controls reaction pathways, achieving highly selective urea oxidation (∼92% N2) coupled with efficient hydrogen evolution ...
Melanie Guillén‐Soler   +4 more
wiley   +1 more source

Electrocatalytic oxidation of ascorbic acid using a single layer of gold nanoparticles immobilized on 1,6-hexanedithiol modified gold electrode

open access: yes, 2007
This paper describes the electrocatalytic oxidation of ascorbic acid (AA) in phosphate buffer solution by the immobilized citrate capped gold nanoparticles (AuNPs) on 1,6-hexanedithiol (HDT) modified Au electrode.
Abraham John, S.   +2 more
core   +1 more source

Resonance-Promoted Formic Acid Oxidation via Dynamic Electrocatalytic Modulation

open access: yes, 2020
It is a truth universally acknowledged that faster catalysts enable the more efficient transformation of molecules to useful products and enhance the sustainable utilization of natural resources. However, the limit of static catalyst performance defined
Omar, Abdelrahman   +5 more
core   +1 more source

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