Electrochemistry of potential bioreductive alkylating quinones : Part 2. Electrochemical properties of 2,5-bis(1-aziridinyl)-3,6-bis(ethoxycarbonylamino)-1,4-benzoquinone and some model compounds [PDF]
The reduction mechanism of 2,5-bis(1-aziridinyl)-3,6-bis(ethoxycarbonylamino)-1,4-benzoquinone (Diaziquone, AZQ) and several model compounds of the mono- and bis(1-aziridinyl)quinone type at the dropping mercury electrode in aqueous solutions was studied.
Blauw, J.S.+6 more
core +2 more sources
This article examines the effect of postprocessing heat treatment on 316L stainless steel (SS316L) produced via laser powder bed fusion (LPBF). Heat treatment slightly affects property anisotropy, reduces strength, and enhances elongation. However, it increases corrosion susceptibility due to nanoscale precipitations, though overall corrosion ...
Baibhav Karan+5 more
wiley +1 more source
Working at the interfaces of data science and synthetic electrochemistry
Electrochemistry is quickly entering the mainstream of synthetic organic chemistry. The diversity of new transformations enabled by electrochemistry is to a large extent a consequence of the unique features and reaction parameters in electrochemical ...
Jesus I. Martinez Alvarado+2 more
doaj
Normality of I-V Measurements Using ML [PDF]
Electrochemistry ecosystems are promising for accelerating the design and discovery of electrochemical systems for energy storage and conversion, by automating significant parts of workflows that combine synthesis and characterization experiments with computations.
arxiv
Zero-bias anomalies in electrochemically fabricated nanojunctions [PDF]
A streamlined technique for the electrochemical fabrication of metal nanojunctions (MNJs) between lithographically defined electrodes is presented. The first low-temperature transport measurements in such structures reveal suppression of the conductance near zero-bias.
arxiv +1 more source
A multiswitchable poly(terthiophene) bearing a spiropyran functionality: understanding photo and electrochemical control [PDF]
An electroactive nitrospiropyran-substituted polyterthiophene, 2-(3,3′′-dimethylindoline-6′-nitrobenzospiropyranyl)ethyl 4,4′′-didecyloxy-2,2′:5′,2′′-terthiophene-3′-acetate, has been synthesized for the first time.
Breukers, Robert+10 more
core +1 more source
Incorporating nanosized silver into titanium for antimicrobial materials exploits the metastable miscibility gap between silver and titanium. Silver nanoparticles are synthesized via pulsed laser ablation in liquid. Silver addition refines the microstructure, increases hardness by 30%, and reduces Staphylococcus capitis microbial adhesion by 70%, with ...
Hamed Shokri+4 more
wiley +1 more source
Converging Divergent Paths: Constant Charge vs. Constant Potential Energetics in Computational Electrochemistry [PDF]
Using the example of a proton adsorption process, we analyze and compare two prominent modelling approaches in computational electrochemistry at metallic electrodes - electronically canonical, constant-charge and electronically grand-canonical, constant-potential calculations.
arxiv
The Li intercalation potential of LiMPO4 and LiMSiO4 olivines with M = Fe, Mn, Co, Ni [PDF]
The Li intercalation potential of LiMPO4 and LiMSiO4 compounds with M = Fe, Mn, Co, and Ni is computed with the GGA+U method. It is found that this approach is considerably more accurate than standard LDA or GGA methods. The calculated potentials for LiFePO4, LiMnPO4 and LiCoOPO4 agree to within 0.1 V with experimental results. The LiNiPO4 potential is
arxiv +1 more source
Current Trends and Future Perspective for Cold Spray Metal‐Ceramic Composites
The use of cold spray (CS) technology for creating cermet deposits, combining ceramic and metallic components, is advancing rapidly. Cermets offer excellent temperature handling and erosion resistance for diverse applications. This review outlines the current state of the art, focusing on the deposition dynamics and strategies to optimize the ...
Romario A. Wicaksono+2 more
wiley +1 more source