Results 101 to 110 of about 16,891 (211)

Electric Double Layer Engineering Induces O‐Down Interfacial Water Reorientation for Efficient and Long‐Term Seawater Electrolysis

Advanced Energy Materials, EarlyView.
The additive EDTMPS inhibits hydroxides deposition by chelating with Ca2+/Mg2+. It also disrupts the hydrogen bond network of interfacial water and expands the thickness of electric double layer, promoting more free water to flip into adsorbable O‐down configuration.
Tongzhou Li, Yutong Zhao, Hongjie Zhang, Yangkai Han, Zhiwei Ren, Feng Xie, Zongping Shao, Zhigang Shao   +7 more
wiley   +1 more source

Crystallography‐Dependent Plating/Stripping Kinetics and Interfacial Morphologies in Zn Metal Anodes

Angewandte Chemie, EarlyView.
SECCM coupled with fast‐scan cyclic voltammetry enables facet‐resolved measurements of Zn plating/stripping kinetics on single‐crystal (002), (100), and (101) surfaces. The close‐packed (002) facet exhibits the lowest exchange current density, whereas the more open (100) facet is kinetically fastest.
Ziqing Wang, Debasree Mandal, Iván Elías Mondaca‐Medina, Kenta Kawashima, Rinish Reddy Vaidyula, Charles Buddie Mullins, Hang Ren, Kent J. X. Zheng   +7 more
wiley   +2 more sources

Surface‐Strained NiMo Cathodes Enable Kinetics‐Decoupled Hydrogen Bubble Management for Stable Near‐Neutral Water Electrolysis

Advanced Energy Materials, EarlyView.
Surface strain tunes the NiMo/electrolyte interface without altering intrinsic hydrogen evolution reaction (HER) kinetics. The strained surface exhibits a lower effective bubble‐detachment tendency and faster release of smaller H2 bubbles, sustaining a more accessible catalytic interface in near‐neutral electrolyte. Reduced bubble‐induced transport and
Si Eun Je, Sumin Lee, Seongjong Kim, Seyeong Jeong, Han Seo Im, Kyu‐Myung Lee, Seunggu Lee, Yongsup Park, Seongsoo Han, Seung‐Jae Shin, Wenjing Zhang, Donghoon Han, Sung Yul Lim   +12 more
wiley   +1 more source

Enhanced Hydrogen Evolution Activity of MoS2 Through Solid Solution Modification of Its Edge Sites With Ruthenium

Angewandte Chemie, EarlyView.
Modulating the edge sites of molybdenum disulfide significantly boosts hydrogen production. By depositing Ru to form an edge‐coordinated solid solution, we accelerate water dissociation and shift the hydrogen evolution reaction pathway to Volmer–Tafel.
Jinsong Zhou, Tsz Kei Leung, Denis A. Kuznetsov, Christoph R. Müller, Lei Ran, Yingguang Zhang, Xin Li, Gang Li, Yifan Xu, Keda Chen, Qinglan Tang, Yaoyang Yu, Michael K.H. Leung   +12 more
wiley   +2 more sources

Interfacial Electronic Modulation of Vacancy‐Stabilized Pt Sites in Mo‐NiSeO4/NiSe2 Heterostructures for Industrial Alkaline Water Electrolysis

Advanced Energy Materials, EarlyView.
A vacancy‐stabilized Pt,Mo‐NiSeO4/NiSe2@Co2P heterostructure with atomically dispersed Pt sites and Mo‐regulated electronic structure enables efficient bifunctional water splitting. Strong interfacial coupling and defect‐assisted Pt stabilization promote rapid charge transfer and optimized intermediate adsorption, delivering outstanding HER/OER ...
Thokchom Anjali Devi, Abhisek Majumdar, Sidra Saleem, Do Hwan Kim, Bollu Manoj, Duy Thanh Tran, Nam Hoon Kim, Joong Hee Lee   +7 more
wiley   +1 more source

Polypyridyl Coordination Motifs as Precursors for Ordered Carbonaceous Frameworks Toward High‐Density Ru Single‐Atom Catalysts

Angewandte Chemie, EarlyView.
Here, we introduce a molecular design principle that fundamentally expands the bottom‐up synthesis of single‐atom catalysts (SACs). Coordinatively flexible polypyridyl units enable bottom‐up formation of ordered carbonaceous frameworks containing atomically dispersed Ru (∼11 wt%) by simple carbonization.
Koki Chida, Tan‐Hao Shi, Takeharu Yoshii, Yuichiro Hayasaka, Yu Gao, Hao Zhang, Nikolay Kosinov, Shigehisa Akine, Kazuhide Kamiya, Kaining Li, Yoshifumi Kondo, Yasutaka Kuwahara, Tomoki Ogoshi, Hirotomo Nishihara   +13 more
wiley   +2 more sources

Reversible Ag-based electrodeposition electrochromic technology and its application in smart windows. [PDF]

RSC Adv
Lu D, Jiang H, Liu J, Nie L, Zhang N, Zhou Y, Wan X, Zhang Y, Yang G, Sun Y, Zhang S, Yu Y.   +11 more
europepmc   +1 more source

Mechanochemically Disordered Li2Ta2OCl10 Oxyhalide Unlocks Superionic Conductivity (>10 mS.cm−1)

Advanced Energy Materials, EarlyView.
This work presents a new crystalline oxyhalide, Li2Ta2OCl10, built from [Ta2OCl10]2− dimers. The disorder induced by ball‐milling drives the dramatic 5000‐fold increase in ionic conductivity to reach 11 mS.cm−1. The material shows promise as a solid electrolyte for batteries and opens new prospects for the discovery of new dimer‐based compounds ...
Clément Morel, Anshuman Chaupatnaik, Jie Liu, Mingxue Tang, Horyung Ji, Mouna Ben Yahia, Marie‐Liesse Doublet, Tatiana N. Kobernik, Dmitry A. Aksyonov, Artem M. Abakumov, Gwenaëlle Rousse, Jean‐Marie Tarascon   +11 more
wiley   +1 more source

Diagnosing the Role of Mn Additives in Aqueous Zn/MnO2 Batteries

Advanced Energy Materials, EarlyView.
Aqueous zinc‐ion batteries frequently employ manganese dioxide cathodes and prevent capacity fade with manganese electrolyte additives. Using operando X‐ray fluorescence spectroscopy to directly track Mn concentration during cycling, we show that the beneficial role of the Mn additive appears to be as an additional source of redox‐active material ...
Zixuan Li, Katarzyna Sowa, Tomasz Kołodziej, Yi Yuan, Hewen Chen, Lijiang Song, Pawel Wróbel, Didier Wermeille, Paul Thompson, Paweł Korecki, Peter G. Bruce, Alex W. Robertson   +11 more
wiley   +1 more source

Immersion-Controlled Nanoparticle Electrodeposition on a Patterned Pyrolyzed Photoresist Film Electrode for Single-Entity Electrochemistry Studies Using Scanning Electrochemical Cell Microscopy. [PDF]

Langmuir
Ito T, Bailey KO, De Leon J, Harvey NF, Zhang L, Baker LA.   +5 more
europepmc   +1 more source