Results 181 to 190 of about 2,600,114 (303)

Steric Coordination Modulated Iodine Chemistry With Four‐Electron Conversion for Zinc‐Iodine Batteries

Advanced Materials, EarlyView.
A dual‐additive electrolyte strategy is developed to address the hydrolysis of I+ in the aqueous electrolytes. The steric‐hindrance effect of TES− effectively shields I+ from nucleophilic attacks by hydroxyl groups, facilitating the reversible I−/I0/I+ conversion with four‐electron transfer.
Shuai Wang, Haoran Wang, Yujue Yang, Yuanyuan Gao, Yaopeng Wu, Junze Zhang, Jingxin Zhao, Yuejiao Chen, Bingang Xu   +8 more
wiley   +1 more source

Toward a Unified Mechanistic Understanding of Polymer Electrolytes for Advanced Solid‐State Batteries

Advanced Materials, EarlyView.
Polymer electrolytes (PEs) are often indiscriminately grouped as “solid polymer electrolytes (SPEs)”, despite fundamental differences in their ion‐transport mechanisms. This Perspective establishes a mechanism‐based framework that distinguishes gel, quasi‐solid, and all‐solid polymer electrolytes based on their dominant ion‐transport pathways.
Jing Chen, Han Chen, Michel Armand, Gunther Brunklaus, Jang Wook Choi, Yan‐Bing He, Bumjoon J. Kim, Seung Woo Lee, Stefano Passerini, Meera Mohankumar, Patrick Theato, Marnix Wagemaker, Martin Winter, Qiang Zhang, Shujiang Ding, Zhiqun Lin   +15 more
wiley   +1 more source

Caffeine during exercise in the heat: thermoregulation and fluid-electrolyte balance.

Medicine & Science in Sports & Exercise, 2009
J. Del Coso, E. Estevez, R. Mora‐Rodriguez   +2 more
semanticscholar   +1 more source

Transient Laser‐Shocked Synthesis of Amorphous Layer‐Supported Metal Nanocrystals for Efficient Nitrate Reduction

Advanced Materials, EarlyView.
A general, versatile laser‐shock synthesis process is reported to produce various bimetallic CuNi, CuFe, CuCo, and medium‐entropy CuFeCoNi heterostructures, in which crystalline metal nanoparticles are anchored to amorphous hydroxide supports. During nitrate reduction reaction, the heterostructures undergo dynamic amorphous/crystalline reconstruction ...
Weihua Guo, Jixun Zhang, Siwei Zhang, Yangbo Ma, Yun Song, Jianjun Su, Zihao Li, Yinger Xin, Qiang Zhang, Mingming He, Ruixuan Wang, Rui Xue, Shibo Xi, Ying Wang, Shenlong Zhao, Tao Yang, Zhengxiao Guo, Ben Zhong Tang, Ruquan Ye   +18 more
wiley   +1 more source

Engineering CO2 Reduction Pathways via Alloy‐Support Interactions in Li‐CO2 Batteries

Advanced Materials, EarlyView.
Alloy‐support interactions in RuCu/NC induce interfacial charge redistribution and shift d‐band centers, steering CO2 reduction from Li2CO3 to metastable Li2C2O4. This pathway engineering lowers the rate‐determining barrier and suppresses carbonate formation, enabling high discharge voltage (3.23 V) in Li‐CO2 batteries with reduced overpotential (0.50 ...
Liang Sun, Xindan Zhang, Guang Feng, Guoqiang Zhao, Bernt Johannessen, Guanjie Li, Shilin Zhang, Hongge Pan, Zaiping Guo   +8 more
wiley   +1 more source

Bias‐Triggered Conductivity Relaxation (BCR): A Unique Tool to Simultaneously Investigate Thermodynamics, Kinetics, and Electrostatic Effects of Oxygen Reactions in MIEC Thin Films

Advanced Materials, EarlyView.
This work develops bias‐triggered conductivity relaxation as a novel technique to study oxygen reactions in mixed ionic‐electronic conducting thin films by integrating electrochemical titration and electrical conductivity relaxation to achieve synchronous multi‐parameter characterization, providing simultaneous electronic, ionic, and extraordinarily ...
Alexander Stangl, Alexander Schmid, Adeel Riaz, Jürgen Fleig, Arnaud Badel   +4 more
wiley   +1 more source

Surface‐Functionalized LLZO‐Incorporated Multilayer Composite Solid Electrolytes for Dendrite Suppression and Efficient Ionic Conduction in Lithium–Metal Batteries

Advanced Materials, EarlyView.
A soft–hard tri‐layer composite electrolyte that couples fast Li+ transport with reinforced interfacial stability to enable high‐conductivity, mechanically robust, dendrite‐free lithium‐metal batteries. ABSTRACT The development of solid polymer electrolytes is central to safe, high‐energy lithium‐metal batteries (LMBs); however, persistent challenges ...
Fazal Ur Rehman, Minhong Woo, Hyesoo Choi, Jihwan Kim, Yujin Kim, Sanghee Park, Serim Ahn, Jinsub Lim, Minyoung Kim, Mincheol Chang   +9 more
wiley   +1 more source

Low Resistance Interphase Formation at the PEO‐LiTFSI|LGPS Interface in Lithium Solid‐State Batteries

Advanced Materials Interfaces, EarlyView.
Interfacial charge transfer and low‐resistance interphase formation between PEO‐based polymer and Li10GeP2S12 solid electrolytes are investigated using multi‐electrode impedance spectroscopy and advanced analytical techniques such as XPS and ToF‐SIMS.
Ujjawal Sigar, Timo Weintraut, Sebastian L. Benz, Semih Engün, Sascha Kremer, Anja Henss, Felix H. Richter   +6 more
wiley   +1 more source

Design of High‐Energy Anode for All‐Solid‐State Lithium Batteries–A Model with Borohydride‐Based Electrolytes

Advanced Materials Interfaces, EarlyView.
This study proposes a function‐sharing anode design to enable nonmetallic lithium insertion while maintaining intimate interfacial contact with the solid‐state electrolyte. A combination of lithium‐compatible and conformable borohydrides, highly conformable indium metal, less‐graphitized acetylene black, and a layer of highly graphitized massive ...
Keita Kurigami, Akihiro Ishii, Itaru Oikawa, Hitoshi Takamura   +3 more
wiley   +1 more source

Phase Diagrams Enable Solid‐State Battery Design

Advanced Materials Interfaces, EarlyView.
Batteries are non‐equilibrium devices with inherent thermodynamic driving forces to react at interfaces, regardless of kinetics or operating conditions. Chemical potential mismatches across interfaces are dissipated via interfacial reactions. In this work, it is illustrated how phase diagrams and chemical potential maps predict degradation pathways but
Nathaniel L. Skeele, Matthias T. Agne
wiley   +1 more source