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Electronic Transport Properties of Spin-Crossover Magnet Fe(II)-N4S2 Complexes
Chinese Journal of Chemical Physics, 2018Spin-crossover (SCO) magnets can act as one of the most possible building blocks in molecular spintronics due to their magnetic bistability between the high-spin (HS) and low-spin (LS) states. Here, the electronic structures and transport properties through SCO magnet Fe(II)-N4S2 complexes sandwiched between gold electrodes are explored by performing ...
Qunxiang Li +3 more
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Journal of Molecular and Cellular Cardiology, 2008 Chemistry Letters, 2015
Abstract Fabrication of bis(terpyridine)iron(II) complex wires by introduction of a bithiophene-linked bridging ligand (LBT) on the Au(111) surface is discussed. A comparative study revealed a very small energy gap between the HOMOs of Fe(tpy)2 and LBT indicating relatively strong electronic coupling and better electron-transport ability.
Shunsuke Katagiri +4 more
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Abstract Fabrication of bis(terpyridine)iron(II) complex wires by introduction of a bithiophene-linked bridging ligand (LBT) on the Au(111) surface is discussed. A comparative study revealed a very small energy gap between the HOMOs of Fe(tpy)2 and LBT indicating relatively strong electronic coupling and better electron-transport ability.
Shunsuke Katagiri +4 more
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ChemInform, 1989
AbstractIn order to perform the selective transport of electrons from an electron source phase to an electron receiving phase, a redox system is used as an electron carrier whose redox potential can be controlled.
G. De Santis +4 more
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AbstractIn order to perform the selective transport of electrons from an electron source phase to an electron receiving phase, a redox system is used as an electron carrier whose redox potential can be controlled.
G. De Santis +4 more
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Russian Journal of General Chemistry, 2016
Two compounds 1-[(2-carboxymethyl)benzene]-3-[2-pyridine]triazene (HL) and 1-[(2-carboxymethyl) benzene]-3-[o-aminobenzoic acid]triazene (H2L') and two corresponding Pt(II) complexes, Pt(PPh3)2(L)Cl (1) and Pt(PPh3)2(L') (2), are theoretically studied by the density functional theory and time-dependent density functional theory. The geometric structure
Xiang-Xiang Wang +3 more
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Two compounds 1-[(2-carboxymethyl)benzene]-3-[2-pyridine]triazene (HL) and 1-[(2-carboxymethyl) benzene]-3-[o-aminobenzoic acid]triazene (H2L') and two corresponding Pt(II) complexes, Pt(PPh3)2(L)Cl (1) and Pt(PPh3)2(L') (2), are theoretically studied by the density functional theory and time-dependent density functional theory. The geometric structure
Xiang-Xiang Wang +3 more
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Chemistry Letters, 2013
Abstract Bis(terpyridine)–iron(II) complex wires (the number of the complex units: 1–3) possessing triarylamine at the termini were fabricated on gold electrode. The electron-transfer rate constant between the triarylamine moiety and gold electrode was quantified by means of potential-step chronoamperometry, revealing that (1 ...
Hiroshi Nishihara +3 more
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Abstract Bis(terpyridine)–iron(II) complex wires (the number of the complex units: 1–3) possessing triarylamine at the termini were fabricated on gold electrode. The electron-transfer rate constant between the triarylamine moiety and gold electrode was quantified by means of potential-step chronoamperometry, revealing that (1 ...
Hiroshi Nishihara +3 more
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Electroanalysis, 2015
AbstractThe electrochemical redox properties of a surface‐confined thin solid film of nanostructured cobalt(II) tetracarboxyphthalocyanine integrated with multiwalled carbon nanotube (nanoCoTCPc/MWCNT) have been investigated. This novel nanoCoTCPc/MWCNT material was characterized using SEM, TEM, zeta analysis and electrochemical methods. The nanoCoTCPc/
Jeseelan Pillay +5 more
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AbstractThe electrochemical redox properties of a surface‐confined thin solid film of nanostructured cobalt(II) tetracarboxyphthalocyanine integrated with multiwalled carbon nanotube (nanoCoTCPc/MWCNT) have been investigated. This novel nanoCoTCPc/MWCNT material was characterized using SEM, TEM, zeta analysis and electrochemical methods. The nanoCoTCPc/
Jeseelan Pillay +5 more
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Korean Journal of Chemical Engineering, 1993
Molecular oxygen diffusion in the cellulose acetate membranes containing the 5,10,15, 20-tetrakis(pentafluorophenyl)-21H,23H-porphine iron(II) was studied. Both the permeability coefficient and the separation factor for oxygen in the membrane containing the iron(II) porphyrin complex were increased with decreasing the upstream gas pressure which ...
Byung-Soo Yu +3 more
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Molecular oxygen diffusion in the cellulose acetate membranes containing the 5,10,15, 20-tetrakis(pentafluorophenyl)-21H,23H-porphine iron(II) was studied. Both the permeability coefficient and the separation factor for oxygen in the membrane containing the iron(II) porphyrin complex were increased with decreasing the upstream gas pressure which ...
Byung-Soo Yu +3 more
openaire +2 more sources