Symmetry Breaking in Chiral Gold Nanoclusters by Ansa‐Metallamacrocycles Strain
Aggregate, EarlyView.In this work, we prepare a chiral Au11 nanocluster ligated by diphosphine ligand, Au11(dppp)5Cl3, which is induced by the unique ansa‐metallamacrocycle stain (the “Au─P─CH2CH2CH2─P─Au” staple). ABSTRACT Chiral nanomaterials have recently stimulated significant interest in both fundamental research and practical applications (e.g., nanoprobes for ...
Zhiwen Li +6 more
wiley +1 more source
High-Throughput Drug Derivatization and Bioassay by Desorption Electrospray Ionization Mass Spectrometry. [PDF]
ChempluschemGhosh J, Morato NM, Feng Y, Cooks RG.
europepmc +1 more source
Overview and Latest Developments in Desorption Electrospray Ionization (DESI) Mass Spectrometry Imaging [PDF]
, 2013 Christina R. Ferreira, R. Graham Cooks
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Emerging Opportunities of Metal Nanoclusters for Photocatalytic Organic Synthesis
Aggregate, EarlyView.Atomically precise metal nanoclusters have emerged as versatile photocatalysts for photo‐induced organic reactions. This review comprehensively summarizes recent advances in this cutting‐edge research field. We begin the discussion with a brief introduction of metal nanoclusters and the fundamental principles of photocatalysis.
Chun‐Lian Lin +4 more
wiley +1 more source
Bright Circularly Polarized Electrochemiluminescence from Heterobinuclear IrIII–AuI Enantiomers
Angewandte Chemie, EarlyView.Efficient and bright circularly polarized electrochemiluminescence (CP‐ECL) is achieved in a class of enantiopure hetobinuclear iridium(III)–gold(I) complexes owing to the combination of high ECL efficiency with stability, good emission dissymmetry factor and high brightness, thus paving the way to the next‐generation of bright CP‐ECL probes.
Lavinia Ballerini +13 more
wiley +2 more sources
Antibody-Drug Conjugate Stability Probed by Variable-Temperature Electrospray Ionization Mass Spectrometry. [PDF]
J Am Soc Mass SpectromFiala J, Schuster D, Heck AJR.
europepmc +1 more source
Stacking‐Angle‐Manipulated Emission (SAME) in Anthracene‐Based Figure‐Eight Metallo‐Supramolecules
Aggregate, EarlyView.Most strategies of tuning packing modes of chromophores are covalent synthesis without reversible features. Herein, we developed a customizable strategy to construct a series of figure‐eight supramolecules S1–S3 with different stacking angles of chromophores. The fluorescent properties were enhanced with stacking angles increased.
Junjuan Shi +6 more
wiley +1 more source
Programmable Microwaveable Chemistry in the Chemputer
Angewandte Chemie, EarlyView.The Chemputer integrates complementary microwave modules under χDL control, enabling fully automated syntheses of O‐alkylation products, Suzuki–Miyaura cross‐couplings, ring‐closing metathesis, and peptide sequences via solid‐phase methods. This modular, programmable platform delivers flexible and scalable microwave‐assisted workflows, broadening ...
Jacopo Zero +5 more
wiley +2 more sources
Critical Role of Voltage Application Points in "Analog" and "Digital" Electrospray Ionization Mass Spectrometry. [PDF]
J Am Soc Mass SpectromHung MM, Elpa DP, Ochirov O, Urban PL.
europepmc +1 more source