The photocatalyst ImC60‐ZnTPP has a unique ultrashort inter‐fullerene spacing in a continuous fullerene stacking array for enhancing electron transport, demonstrating a hydrogen evolution rate of 80.95 mmol·g−1·h−1. This work not only provides a strategy to develop a high‐performance photocatalyst but also provides an avenue for advancing organic ...
Yupeng Song+9 more
wiley +1 more source
Improved ion detection sensitivity in mass spectrometry imaging using tapping-mode scanning probe electrospray ionization to visualize localized lipids in mouse testes. [PDF]
Otsuka Y+8 more
europepmc +1 more source
A novel family of water‐soluble, nontoxic, and phosphorescent N‐glycosylated Ru(II) phenanthroline‐based complexes are reported. They exhibit photoselectivity indexes ranging from 10 to 44 in PC‐3 cells, while impacting cell migration and resistance to detachment after irradiation with blue light.
Elena de la Torre‐Rubio+5 more
wiley +1 more source
Detergent design parameters determine experimental successes in membrane protein research. Recent progresses in detergent chemistry are reviewed to promote the top‐down design of non‐ionic detergents for the purification and analysis of intact membrane proteins, including lipid interactions.
Katharina Alker+2 more
wiley +1 more source
Fluorenyl Cations: Synthesis and Reactivity
This review covers the history of fluorenyl cations from Deno's first report in 1954 on the parent fluorenyl cation to the present. The parent cation and most derivatives have only been observed as a fleeting species by mass spectrometry, UV/Vis spectroscopy, IR spectroscopy, or NMR spectroscopy while recent developments led to isolable species ...
Kanika Vashisth+5 more
wiley +1 more source
Tumor-Promoted Changes in Pediatric Brain Histology Can Be Distinguished from Normal Parenchyma by Desorption Electrospray Ionization Mass Spectrometry Imaging. [PDF]
Seidinger AL+16 more
europepmc +1 more source
Mono‐ IrIII versus heterobimetallic IrIII‐AuI complexes for circularly polarized luminescence
Fundamental rationalization of the structural–circularly polarized luminescence (CPL) activity relationship is a challenging task. Herein, a pair of enantiopure, heterobimetallic IrIII–AuI complexes IrAu‐4 featuring chirality‐at‐metal is thoroughly investigated by means of spectroscopical and computational techniques, also including spin‐orbital ...
Lavinia Ballerini+9 more
wiley +1 more source
Hardware and software solutions for implementing nanospray desorption electrospray ionization (nano-DESI) sources on commercial mass spectrometers. [PDF]
Jiang LX, Hilger RT, Laskin J.
europepmc +1 more source
Tailored Watson–Crick Pairing Partners for Xanthosine in RNA
RNAs with kappa‐xanthosine (K–X) or 2‐iminocytidine‐xanthosine (2imC–X) base pairs form stable double helices that have higher melting temperatures than those of the A–U or G–U references. Access to these novel 2imC‐modified RNAs is possible through the mild, selective chemical conversion of 2‐thiocytidine RNA precursors.
Stefan Mair+5 more
wiley +1 more source
Desorption Electrospray Ionization Cyclic Ion Mobility-Mass Spectrometry Imaging for Traumatic Brain Injury Spatial Metabolomics. [PDF]
Leontyev D+5 more
europepmc +1 more source