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Electrospray ionization for determination of non-polar polyaromatic hydrocarbons and polyaromatic heterocycles in heavy crude oil asphaltenes.

Journal of Mass Spectrometry, 2015
Electrospray ionization (ESI) is the most common ionization method in atmospheric pressure ionization mass spectrometry because of its easy use and handling and because a diverse range of components can be effectively ionized from high to medium polarity.
Lilla Molnárné Guricza, W. Schrader
semanticscholar   +1 more source

Mechanistic aspects of electrospray ionization

Journal of Chromatography A, 1998
Abstract Electrospray ionization (ESI) mass spectrometry can be divided into three steps: Nebulization of a sample solution into electrically charged droplets, liberation of ions from droplets, and transportation of ions from the atmospheric pressure ionization source region into the vacuum and mass analyzer of the mass spectrometer.
openaire   +2 more sources

Electrospray Ionization Using Wooden Tips

Analytical Chemistry, 2011
Electrospray ionization (ESI) is a mass spectrometric technique widely used in various fields including chemistry, biology, medicine, pharmaceutical industry, clinical assessment, and forensic science. In this study, we report a simple and economical ESI-mass spectrometry (MS) technique, which makes use of disposable wooden tips (wooden toothpicks) for
Bin Hu   +3 more
openaire   +3 more sources

Lipidomics: analysis of the lipid composition of cells and subcellular organelles by electrospray ionization mass spectrometry.

Annual Review of Biochemistry, 2014
Lipidomics aims to quantitatively define lipid classes, including their molecular species, in biological systems. Lipidomics has experienced rapid progress, mainly because of continuous technical advances in instrumentation that are now enabling ...
B. Brügger
semanticscholar   +1 more source

Desorption electrospray ionization of aerosol particles

Rapid Communications in Mass Spectrometry, 2007
AbstractWe have applied desorption electrospray ionization to aerosol particles. Ions were formed from aerosols by merging suspended dry particles with an electrospray of solvent in a modified ion trap mass spectrometer. Dry aerosol particles were generated using a fluidized bed powder disperser and directed toward the inlet of the mass spectrometer. A
Yohannes H. Rezenom   +2 more
openaire   +3 more sources

An Electrospray Ionization Source for Integration with Microfluidics

Analytical Chemistry, 2002
We have demonstrated a new electrospray ionization (ESI) device incorporating a tip made from a shaped thin film, bonded to a microfluidic channel, and interfaced to a time-of-flight mass spectrometer (TOFMS). A triangular-shaped thin polymer tip was formed by lithography and etching.
David A. Czaplewski   +5 more
openaire   +3 more sources

Negative electrospray ionization via deprotonation: predicting the ionization efficiency.

Analytical Chemistry, 2014
Electrospray ionization (ESI) in the negative ion mode has received less attention in fundamental studies than the positive ion electrospray ionization. In this paper, we study the efficiency of negative ion formation in the ESI source via deprotonation ...
A. Kruve   +3 more
semanticscholar   +1 more source

Integration of electropreconcentration and electrospray ionization in a microchip

Journal of Chromatography A, 2018
A microfluidic glass chip for performing sensitive mass spectrometry (MS) is developed by integrating nanochannel-based electropreconcentration with electrospray ionization (ESI). Cation analytes in acidic buffer conditions (∼pH 3) were preconcentrated at a micro-nano-microchannel junction where a positively charged polymer, polyE-323, is coated to ...
openaire   +3 more sources

Electrospray Ionization Mass Spectrometry of Oligonucleotides

Current Protocols in Nucleic Acid Chemistry, 2008
AbstractBecause of the high molecular weights and thermal lability of biomolecules such as nucleic acids and protein, they can be difficult to analyze by mass spectrometry. Such analyses require a “soft” ionization method that is capable of generating intact molecular ions.
Colette M. Castleberry   +2 more
openaire   +3 more sources

Shotgun approach for quantitative imaging of phospholipids using nanospray desorption electrospray ionization mass spectrometry.

Analytical Chemistry, 2014
Mass spectrometry imaging (MSI) has been extensively used for determining spatial distributions of molecules in biological samples, and there is increasing interest in using MSI for quantification. Nanospray desorption electrospray ionization (nano-DESI)
Ingela Lanekoff   +2 more
semanticscholar   +1 more source

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