Results 281 to 290 of about 230,711 (334)

Identifying an Active Intermediate and Monitoring O─O Bond Formation in Water Oxidation by a Cobalt(III)‐TAML Complex

open access: yesAngewandte Chemie International Edition, EarlyView.
Two redox tautomers of a cobalt–TAML complex show strikingly different reactivity in water oxidation. The ligand‐centered Co(III)–OH species evolves O2 via H2O2, while the metal‐centered Co(IV) = O is inactive. Electron‐transfer kinetics and the Marcus analysis reveal how redox localization influences reactivity and O─O bond formation in high‐valent ...
Deesha D. Malik   +4 more
wiley   +1 more source

Enhancing electrospray ionization efficiency for particle transmission through an aerodynamic lens stack. [PDF]

open access: yesJ Synchrotron Radiat
Rafie-Zinedine S   +6 more
europepmc   +1 more source

Visualization of Gaseous Ammonia Using an Ionic Liquid‐Based pH‐Responsive Dye

open access: yesAnalysis &Sensing, EarlyView.
An ionic liquid composed of bromocresol purple ([P66614]2[BCP]) is synthesized via an ion‐exchange reaction. The color of [P66,614]2[BCP] changes from yellow to blue after exposure to gaseous NH3. The color change in the [P66614]2[BCP] thin film serves as a visual indicator of pork and salmon decomposition.
Naoya Adachi   +3 more
wiley   +1 more source

Electromembrane Extraction for Multiclass Pesticide Assessment in Soil Matrices: Sustainable Analytical Insights

open access: yesAnalysis &Sensing, EarlyView.
The U‐shaped electromembrane extraction with liquid chromatography‐mass spectrometry enables rapid multiclass pesticide screening in soil. The 15 min, low‐solvent workflow achieves high recoveries and robust linearity, while AGREEprep and GAPI assessments highlight a greener profile compared to literature reports, which represents a smart strategy for ...
Rafael O. Martins   +9 more
wiley   +1 more source

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