Results 131 to 140 of about 9,491 (247)
Synthesis, Updated Characterization, and Reactivity of Low‐Valent Titanocene Complexes
Syntheses and characterizations are provided for a series of low‐valent titanocene complexes including halotitanocene(III) dimers, [Cp2Ti(κ2‐DME)][BAr4] cations, and heterobimetallic [Cp2Ti(μ‐Cl)2AlR2]. Additionally, a monomeric titanacyclopropene complex featuring a pendent phosphine was prepared, and C─F bond activation upon reduction of [Cp{η5:κ2F2 ...
Griffin J. LaChapelle +2 more
wiley +1 more source
A Janus electrocatalyst, Fe/FexOy is facilely synthesized via in situ reconstruction of β‐FeOOH. In particular, the electronically coupled Fe crystal phase with FexOy exhibits high NO3RR performance through synergistic promotion of nitrate adsorption/activation and water activation, offering an alternative platform to conventional bi‐metallic catalyst ...
Sourav Chaule +5 more
wiley +1 more source
ABSTRACT Alkaline oxygen reduction reaction (ORR)/OER bifunctionality is central to rechargeable Zn–air batteries, reversible fuel cells and regenerative electrolysis. These technologies are promising for mitigating carbon emissions resulting from fossil fuel energy dependency, driving the energy sector towards a carbon‐neutral energy cycle.
Tebogo Abigail Mashola +4 more
wiley +1 more source
EMERGING TRENDS OF ORGANIC ELECTROSYNTHESIS IN BRAZIL
This review provides an overview of the recent progress in organic electrosynthesis in Brazil, ranging from 2013 to 2023. By highlighting the principles, applications, and limitations of various electrosynthetic methodologies, this article aims to ...
Kleber T. de Oliveira +1 more
core +1 more source
Metal–Organic Frameworks for Electrocatalytic Nitrate‐to‐Ammonia Conversion: A Review
Electrocatalytic MOF‐based nitrate reduction transforms nitrate‐contaminated water into valuable ammonia. The process involves treating nitrate‐contaminated water. Engineering MOF catalysts with tunable structures. Activating dynamic metal sites within MOFs. Regulating charge transfer and proton availability.
Abdullah Shah +5 more
wiley +1 more source
Carbon‐Confined Fe3C/Fe3N Janus Interfaces for Selective Nitric Oxide‐to‐Ammonia Electroreduction
A defect‐rich, graphitic‐carbon‐confined Fe3C/Fe3N Janus catalyst integrates NO transport, adsorption/activation, and interfacial H supply for efficient nitric oxide electroreduction to ammonia. Built from earth‐abundant elements, this architecture enables high‐yield and high‐efficiency NH3 synthesis while valorizing industrial NO emissions.
Jialing Song +10 more
wiley +2 more sources
Electroactive Microbiomes: Electron Transfer Mechanisms and Environmental Biotechnology Applications
Electroactive microbiomes couple direct, mediated, conductive, and interspecies electron transfer with biofilm organisation to drive wastewater treatment, bioremediation, resource recovery, carbon conversion, and biosensing. Their performance depends on balancing electron transfer, mass transport, community structure, and electrode–biofilm interactions
Timoth Mkilima
wiley +1 more source
A heterogeneous photocatalytic system has been developed that enables the dehydrogenative decarbonylation of primary alcohols under visible light using highly dispersed oxidic iron sites supported on aryl‐modified graphitic carbon nitride (Fe@f–gC3N4).
Jun Hu +11 more
wiley +2 more sources
Bromide-mediated paired electrosynthesis of hydrogen and epoxide. [PDF]
Ruan G, Rothschild A.
europepmc +1 more source
Using defect‐rich Co‐N2O2 single‐atom catalysts as a model system, this work reveals that atomic site density governs the competition between H2O2 electrosynthesis and microenvironmental decomposition during 2e−‐ORR. Optimised site isolation suppresses HPRR and HDR, thereby establishing a site‐density principle to balance H2O2 formation and ...
Junwen Chen +8 more
wiley +1 more source

