Organocatalytic iminium-assisted asymmetric B(sp²)-to-B(sp³) transformation. [PDF]
Nong Y +9 more
europepmc +1 more source
Enzyme–MOF Composites: Quantitative Benchmarking and Evaluation of Biocatalyst Performance
Rigorous evaluation of enzyme@MOF composites requires quantitative benchmarking. This study illustrates this approach by applying and comparing enzyme‐loading and activity‐assessment strategies for two structurally and functionally distinct enzymes, phenolic acid decarboxylase, and cytochrome c.
Annika J. Weber +9 more
wiley +1 more source
A metal-organic framework with chiral nanochannels for enantioselective fluorescence switching of amino alcohols. [PDF]
Ladhi R, Dhillon AK, Singh M.
europepmc +1 more source
Males of the tropical frog Gephyromantis granulatus carry unique ethyl‐branched sesquiterpenoid macrolactones in their scent glands. Their structure elucidation was performed by GC/MS, leading to the proposed structures of the granolides. A flexible enantioselective synthesis confirmed the structures and allowed determination of their absolute ...
Johanna Kuhn +2 more
wiley +1 more source
This work presents the first enzymatic polymerization of defined metal‐chelator‐modified nucleotides that leverage polymerase fidelity for uniform (radio)metal loading with successful incorporation of five different metals: Ga, In, Tb, Lu, and Y.
Antonio A. W. L. Wong +2 more
wiley +2 more sources
Chiral Oxazoline-Triazole-Benzothiazole Molecular Triads: Photoactive Sensors for Enantioselective Carbohydrate Recognition in Solution. [PDF]
Debia NP +5 more
europepmc +1 more source
Second‐Harmonic Hyper‐Mie Optical Activity Enables Closed‐Loop Chiral Photochemistry
Nonlinear chiral photochemistry is demonstrated in CdTe/CdO nanohelices, where circularly polarized infrared light both drives and tracks photo‐oxidation via second‐harmonic scattering. This closed‐loop process reveals real‐time structural evolution, including shell fracturing and core exposure, accompanied by a transition from hyper‐Mie to hyper ...
Hoyeon Choi +6 more
wiley +1 more source
f-Block Element-Based MOF Thin Films: A Platform for Luminescence, Sensing, and Energy Applications. [PDF]
Chen DH, Wöll C.
europepmc +1 more source
Enhanced Volume Optical Chirality in Electromagnetically Balanced Plasmonic Helices
Electromagnetically balanced plasmonic helices enable enhanced optical chirality within their interior volume in the mid‐infrared. Tuning the helix geometry controls the balance between electric and magnetic dipole responses, producing strong chiral near fields and enabling chirality sign reversal without changing structural handedness.
Ihar Faniayeu, Ivan Fanyaev
wiley +1 more source
How Polyphenol Metabolites Spatiotemporally Reprogram Transcription Factors and Human Proteostasis: A Metabolite-Centric Framework. [PDF]
Lastra JMP +4 more
europepmc +1 more source

