Results 21 to 30 of about 3,926 (183)

Non-Chromatographic Purification of Endohedral Metallofullerenes [PDF]

Molecules, 2017
The purification of endohedral metallofullerenes by high performance liquid chromatography is very time-consuming and expensive. A number of rapid and inexpensive non-chromatographic methods have thus been developed for large-scale purification of metallofullerenes.
Zhiyong Wang, Haruka Omachi, Hisanori Shinohara   +2 more
openaire   +2 more sources

A prospective study on ionization of endohedral metallofullerene as cryo-electron microscopy biomarker using relativistic electron scattering

, 2022
Since the discovery of endohedral metallofullerene, it has always been attractive among researchers in various fields of utilities. An encapsulated Au atom with fullerene can be an ideal active agent for enhancing the response of the ligand docking site ...
Ghanshyam Purohit, Munendra Jain
core   +1 more source

Functionalization of Endohedral Metallofullerenes with Reactive Silicon and Germanium Compounds

Molecules, 2017
Exohedral derivatization of endohedral metallofullerenes (EMFs) has been exploited as a useful method for characterizing the structural and chemical properties of EMFs, and for functionalizing them for potential applications.
Masahiro Kako, Shigeru Nagase, Takeshi Akasaka   +2 more
doaj   +1 more source

Structure and Reactivity of Endohedral Metallofullerenes [PDF]

ECS Meeting Abstracts, 2009
Abstract not Available.
Josep M. Poblet, Ramón Valencia, Antonio Rodríguez-Fortea, Anna Clotet, Xavier Aparicio   +4 more
openaire   +1 more source

A Dual PET/MR Imaging Nanoprobe: 124I Labeled Gd3N@C80

Applied Sciences, 2012
The current report describes the development of a dual modality tomographic agent for both positron emission tomography and magnetic resonance imaging (PET/MRI).
Jianqiao Luo, John D. Wilson, Jianyuan Zhang, Jerry I. Hirsch, Harry C. Dorn, Panos P. Fatouros, Michael D. Shultz   +6 more
doaj   +1 more source

Four‐Centre, Multielectron Bonding in Rare‐Earth Germole Sandwich Complexes

Angewandte Chemie, Volume 137, Issue 21, May 19, 2025.
Stepwise one‐ and two‐electron reduction of the dimeric germole‐ligated sandwich complexes [(η5‐CpGe)M(η5‐Cpttt)]2 (M = Y, Gd, Dy) produces the isostructural complex anions [{(η5‐CpGe)M(η5‐Cpttt)}2]− and [{(η5‐CpGe)M(η5‐Cpttt)}2]2−, respectively. The additional electrons populate bonding molecular orbitals extending across the {M2Ge2} rings, resulting ...
Siddhartha De, Arpan Mondal, Jem Pitcairn, Lucy Clark, Jinkui Tang, Akseli Mansikkamäki, Richard A. Layfield   +6 more
wiley   +2 more sources

Structures of Endohedral Metallofullerenes

Nihon Kessho Gakkaishi, 2006
The structures of many typical endohedral metallofullerenes have been reported by the powder X-ray analysis. For example, the report of the trimetallofullerene Sc3C82has shown that the endohedral structure is Sc3@C82, this being widely accepted. However, the recent13C NMR spectroscopy and X-ray single crystal analysis have revealed that the structure ...
AKASAKA, Takeshi, NAGASE, Shigeru
openaire   +2 more sources

On the Structural and Vibrational Properties of Solid Endohedral Metallofullerene Li@C₆₀

Inorganics
The endohedral lithium fulleride, Li+@C60•−, is a potential precursor for new families of molecular superconducting and electronic materials beyond those accessible to date from C60 itself.
Martina Vrankić, Takeshi Nakagawa, Melita Menelaou, Yasuhiro Takabayashi, Naoya Yoshikane, Keisuke Matsui, Ken Kokubo, Kenichi Kato, Saori Kawaguchi-Imada, Hirokazu Kadobayashi, John Arvanitidis, Yoshiki Kubota, Kosmas Prassides   +12 more
doaj   +1 more source

Endohedral metallofullerenes in self-assembled monolayers

Phys. Chem. Chem. Phys., 2010
A method has been developed for the attachment of a dithiolane group to endohedral metallofullerenes via a 1,3-dipolar cycloaddition reaction. This sulfur-containing functional group serves as an anchor, enabling efficient immobilisation of endohedral fullerenes on Au(111) surfaces at room temperature, directly from the solution phase.
Gimenez-Lopez, M, Gardener, J, Gardener, J, Shaw, A, Shaw, A, Iwasiewicz-Wabnig, A, Iwasiewicz-Wabnig, A, Porfyrakis, K, Porfyrakis, K, Balmer, C, Balmer, C, Dantelle, G, Dantelle, G, Hadjipanayi, M, Hadjipanayi, M, Crossley, A, Crossley, A, Champness, N, Champness, N, Castell, M, Castell, M, Briggs, G, Briggs, G, Khlobystov, A, Khlobystov, A   +24 more
openaire   +4 more sources

Unveiling metal-cage hybrid states in a single endohedral metallofullerene

, 2003
The local structural and electronic properties of individual metallofullerenes are studied using scanning tunneling microscopy, scanning tunneling spectroscopy, and theoretical simulations.
Li, Qunxiang, Zhu, Qingshi, Yang, Shangfeng, Hou, J. G., Zhao, Jin, Wang, Kedong, Yang, Jinlong, Wang, Bing, Yang, Shihe, Chen, Lan   +9 more
core   +1 more source