Results 31 to 40 of about 3,926 (183)

An Instrument for Isomer‐Specific Action Spectroscopy of Charged Clusters: Electronic Spectra of C 14 + and Ca@C 60 +

Chemistry–Methods, Volume 6, Issue 8, August 2026.
Disentangling spectral congestion of a mixture of isomers in gas‐phase spectroscopy is critical. We present an instrument combining ion mobility, mass spectrometry, and spectroscopy in a cryogenic 3D Paul trap to investigate the isomer‐specific charged clusters and illustrate its performance with the electronic spectra of C14+ and Ca@C60+. Interpreting
Corentin Rossi, Anne P. Rasmussen, Zekai Li, Uma Namangalam, Bérenger Gans, Juraj Jašík, Jan Žabka, Hugo Bauduin, Christophe Charrière, Vira Davouloury, Jean‐Philippe Dugal, Jérome Guigand, Catherine Le Bris, Ugo Jacovella   +13 more
wiley   +1 more source

Process Parameter Optimisation for Endohedral Metallofullerene Synthesis via the Arc-Discharge Method

Inorganics
Fullerenes have a unique structure, capable of both encapsulating other molecules and reacting with those on the exterior surface. Fullerene derivatives have also been found to have enormous potential to address the challenges of the renewable energy ...
Sapna Sinha, Karifa Sanfo, Panagiotis Dallas, Sujay Kumar, Kyriakos Porfyrakis   +4 more
doaj   +1 more source

Endohedral Metallofullerene Derivatives [PDF]

, 2008
Trimetallic nitride endohedral metallofullerene derivatives and their preparation are described. The trimetallic nitride endohedral metallofullerene derivatives have the general formula A(sub 3-n)X(sub n)@C(sub m)(R) where n ranges from 0 to 3, A and X ...
Iezzi, Erick B., Dorn, Harry C., Duchamp, James   +2 more
core  

Gadolinium based endohedral metallofullerene Gd₂@C₇₉N as a relaxation boosting agent for dissolution DNP at high fields

, 2018
The endohedral metallofullerene Gd2@C79N showing unprecedented boosting effects in combination with 4-oxo-TEMPO for dissolution DNP at 5 T.
Bimala Lama, Zhehong Gan, Stephen Hill, Joanna R. Long, Xiaoling Wang, Kyle Kirkpatrick, Johan van Tol, Tinghui Li, Harry C. Dorn, Johannes E. McKay   +9 more
core   +1 more source

Molecular Engineering of Octathio[8]Circulenes with Superhalogens for Enhanced Optoelectronic Properties

Nano Select, Volume 7, Issue 3, March 2026.
ABSTRACT Sunflower‐like octathio[8]circulene (C16S8) has gained attention for its exceptional thermal and electronic properties. In this study, a superhalogen‐based doping strategy was employed to enhance its nonlinear optical (NLO) response, investigated through density functional theory (DFT) simulations.
Naveen Kosar, Tayyba Ashraf, Mona A. Aziz Aljar, Tariq Mahmood, Sumayya M. Ansari, Muhammad Imran, Saleh T. Mahmoud, Adnan Younis   +7 more
wiley   +1 more source

An implanted paramagnetic metallofullerene probe within a metal–organic framework

, 2018
Paramagnetic endohedral metallofullerene can be used as a molecular probe because of its sensitive electron spin characters, one of which is to sense its surroundings.
Chunru Wang, Haibing Meng, Taishan Wang, Mingzhe Nie, Yongjian Li, Chong Zhao   +5 more
core   +1 more source

Metal‐Induced Tuning of Fullerene Reactivity: Application to Nucleophile Addition

ChemPhysChem, Volume 26, Issue 23, November 28, 2025.
A textbook case of how encapsulating an atom in a carbon cage can tune assembly reactivity based on partial charge distribution–exemplified by the classic nucleophilic attack. Endohedral metallofullerenes (EMFs) are a unique class of hybrid molecules formed by encapsulating metal atoms within carbon cages (fullerenes), giving rise to distinctive ...
Corentin Rossi, Anne P. Rasmussen, Bérenger Gans, Ugo Jacovella   +3 more
wiley   +1 more source

Nucleation of endohedral metallofullerene on films

, 1998
We have studied the initial stage growth of endohedral metallofullerene (Formula presented) on crystalline (Formula presented) films using in situ ultrahigh vacuum scanning tunneling microscopy.
Huang, Houjin, Lin, Nian, Yang, Shihe
core   +1 more source

Endohedral metallofullerene molecular nanomagnets

Chemical Society Reviews
This review summarizes the significant advances in endohedral metallofullerene-based molecular nanomagnets, with a particular emphasis on their unique structures and intriguing magnetic properties arising from such structural peculiarity.
Ziqi Hu, Shangfeng Yang
openaire   +2 more sources

Azide Addition to an Endohedral Metallofullerene: Formation of Azafulleroids of Sc₃N@I_h-C₈₀

, 2016
The reaction of an organic azide with an endohedral metallofullerene has been investigated for the first time. Isomeric [5,6]- and [6,6]-azafulleroids can be obtained from the thermal reaction of Sc3N@Ih-C80 with 4-isopropoxyphenyl azide, while ...
Tao Wei (18855), Mingzhi Jiao (1975789), Guan-Wu Wang (1456660), Faye L. Bowles (1744093), San-E Zhu (1894786), Tong-Xin Liu (1456666), Shangfeng Yang (1438420), Alan L. Balch (1444450), Marilyn M. Olmstead (1306137)   +8 more
core   +2 more sources