Results 51 to 60 of about 3,926 (183)
ChemPhysChem, Volume 26, Issue 4, February 16, 2025.The 3‐centre metal–metal bonding in the tri‐actinide clusters [An₃Cl₆]z (z=1–6) and [An₃Cl₆Cp₃]z (z=−2–+3; An=Ac–Pu) is explored using computational chemistry methods. The studied clusters have 2, 1 or 0 electrons in the 3‐centre MOs and their electronic structures and geometries are discussed.
Josef Tomeček +2 more
wiley +1 more source
Host−Guest Complexation of Endohedral Metallofullerene with Azacrown Ether and Its Application
, 2016 Complexation of endohedral metallofullerene La@C82-A (1) with macrocyclic compounds, such as 1,4,7,10,13,16-hexaazacyclooctadecane (2), 1,4,7,10,13,16-hexamethyl-1,4,7,10,13,16-hexaazacyclooctadecane (3), mono-aza-18-crown-6 ether (4), 18-crown-6 ether ...
Takeshi Akasaka (1402213) +12 more
core +1 more source
Advanced Functional Materials, Volume 34, Issue 49, December 2, 2024.Fullerene‐based immunomodulatory nanomaterials have a dual immunomodulatory mechanism. They activate the immune system after immunosuppression, giving them powerful roles in tumor immunotherapy and tumor‐enhancing immunotherapy. In addition, fullerene nanomaterials inhibit over‐activated immunity, developing different strategies to suppress related ...
Mingming Zhen +3 more
wiley +1 more source
, 2009 : The interaction of thermal and hyperthermal Ni ions with gas-phase C60 fullerene was investigated at two temperatures with classical molecular dynamics simulations using a recently developed interatomic many-body potential.
Bogaerts, Annemie, Neyts, Erik C.
core +1 more source
Precision Chemistry of Metallofullerenes and Graphene: Recent Advances
ChemPlusChem, Volume 89, Issue 11, November 2024.Precision chemistry of synthetic carbon allotropes including fullerene and graphene is at the forefront of nanocarbons chemistry. This minireview provides a concise overview of the latest advancements in the precision chemistry of metallofullerene and graphene, underlining the challenges and prospects for ongoing research.
Xueyi Chang, Muqing Chen, Tao Wei
wiley +1 more source
Encapsulated Atomic Hydrogen in Octamethyl‐POSS Cages: A Pulsed EPR Study
ChemPlusChem, Volume 89, Issue 11, November 2024.The electron spin relaxation properties and hyperfine interactions of atomic hydrogen trapped in octamethyl‐POSS cages are studied by advanced EPR methods. Despite the typical shortening of the electron spin coherence time T2 at low temperatures due to methyl rotation, this species exhibits key spectroscopic properties that could be harnessed to ...
G. Mitrikas
wiley +1 more source
, 2016 The reaction mechanism of the Diels–Alder reaction of paramagnetic endohedral metallofullerene, La@C82, and 1,2,3,4,5-pentamethylcyclopentadiene was studied theoretically and experimentally.
Takeshi Akasaka (1402213) +6 more
core +1 more source
Exohedral Diels‐Alder Reactivity of Endohedral Metallofullerene C36
Chemistry – A European Journal, Volume 30, Issue 58, October 17, 2024.The preferential position of 3d metal atoms inside the C36 cage and their effect on exohedral Diels‐Alder reactivity is reported in comparison with the empty C360 and C362− cages. Among all [5‐5], [6‐5] and [6 6] C−C bonds the [5‐5] bond is the most reactive bond in both the empty C36 and metallofullerene M@C36.
Athul Santha Bhaskaran +4 more
wiley +1 more source
Zero‐Dimensional Carbon Nanomaterials for Electrochemical Energy Storage
ChemElectroChem, Volume 11, Issue 10, May 17, 2024.The review is focus on the 0‐dimensional carbon nanomaterials (fullerenes, carbon quantum dots, graphene quantum dots, and “small” carbon nano‐onions) in the electrochemical energy storage. Their unique properties beneficial for batteries and supercapacitors application are the result of their small and controllable size, ranging from 1 to 10 nm, and ...
Joanna Breczko +3 more
wiley +1 more source
Donor−Acceptor Conjugates of Lanthanum Endohedral Metallofullerene and π-Extended Tetrathiafulvalene
, 2016 Stable donor−acceptor conjugates (2, 3) involving an endohedral metallofullerene, La2@Ih-C80, and π-extended tetrathiafulvalene (exTTF) have been synthesized by highly regioselective 1,3-dipolar cycloadditions of exTTF-containing azomethine ylides to the
Takeshi Akasaka (1402213) +7 more
core +1 more source