A short‐range Rh‐O‐Co‐O‐Ce interfacial moiety drives low‐temperature N2O decomposition via a cooperative redox cycle. Operando modulated‐excitation XAS with phase‐sensitive detection (ME‐XAS+PSD) tracks rapid, reversible Rh oxidation coupled to Co reduction. Combined kinetics and DFT rationalize the activity trends and identify the Rh‐O‐Co interface as
Daniel C. Cano‐Blanco +7 more
wiley +1 more source
Toward an Event-Based and Quality-Assured Air Sampling: A Portable System for Sensing and Sampling Volatile Organic Compounds. [PDF]
Mayer T +3 more
europepmc +1 more source
Cooperative Redox Catalysis of N2O Decomposition by Short‐Range RhOx and CeOx Anchored to Co3O4
A short‐range Rh–O–Co–O–Ce interfacial moiety drives low‐temperature N2O decomposition via a cooperative redox cycle. Operando modulated‐excitation XAS with phase‐sensitive detection (ME‐XAS + PSD) tracks rapid, reversible Rh oxidation coupled to Co reduction.
Daniel C. Cano‐Blanco +7 more
wiley +1 more source
Improving Perovskite/CIGS Tandem Solar Cells for Higher Power Conversion Efficiency through Light Management and Bandgap Engineering. [PDF]
Farias-Basulto G +11 more
europepmc +1 more source
O2 verbessert den Ladungstransfer in organischen n‐Typ‐Donor‐Akzeptor‐Ladungstransferkomplexen (CTCs) durch physisorptive Passivierung von Ladungsträgerfallen. Durch die Unterdrückung der Rekombination und die Förderung langlebiger delokalisierter Ladungsträger verbessert O2 den Elektronentransport und die Leitfähigkeit ohne Dotierung.
Kirill K. Gubanov +16 more
wiley +1 more source
Chemical exfoliation of layered Al<sub>5</sub>C<sub>3</sub>N for the synthesis of AlN nanosheets. [PDF]
Amousa N +12 more
europepmc +1 more source
Photochemistry of Aromatic N‐Oxides in Water Probed by Time‐Resolved X‐ray Absorption Spectroscopy
Time‐resolved XAS at the nitrogen and oxygen K‐edges is applied to the photorearrangement of two N‐oxides in water. Pyridine N‐oxide rapidly forms the oxaziridine isomer. Pyridazine N‐oxide undergoes ring opening to the diazo compound, without any evidence of intermediates.
Maximilian Paradiz Domínguez +3 more
wiley +1 more source
Photodegradation of 2D Ruddlesden-Popper Perovskites: Consequences and Design Principles for Photoelectrochemical Applications. [PDF]
Vasquez-Montoya MF +13 more
europepmc +1 more source
Performance Analysis of Abradable Coating Systems for Aircraft Gas Turbines
Three CoNiCrAlY/YSZ/MgAl2O4 abradable liner configurations on a nickel‐superalloy are evaluated by thermal‐gradient cycling and incursion tests. Laser ablation of the bondcoat and/or Y2O3‐stabilized ZrO2 (YSZ) intermediate layer increases mechanical interlocking and bonding for thick topcoats.
Hanna Heyl +4 more
wiley +1 more source

