Carba‐closo‐dodecaborates as Superchaotropic Anions
The singly charged boron cluster anion CB11H12– forms strong inclusion complexes with cyclodextrins, interacts strongly with nonionic polymers, and serves as an effective transmembrane carrier, positioning itself as the smallest superchaotropic anion known to date. .
Andrea Barba‐Bon +8 more
wiley +1 more source
Modulation of Epigenetic Control by Advanced Molecular Tweezers
Tailored dimeric molecular tweezers recognize the DNA‐binding part of Histone H4 and interrupt the essential histone‐DNA interaction. ABSTRACT This work addresses the question if supramolecular systems can be tailored to interfere with posttranslational modifications (PTM) and epigenetics.
My‐Hue‐Le +9 more
wiley +1 more source
Determinants of Abl kinase stability and drug binding thermodynamics: Role of regulatory domains and phosphorylation. [PDF]
Juárez-Barragán A +5 more
europepmc +1 more source
T‐shaped bolapolyphiles with highly branched carbosilane‐based side‐groups self‐assemble into liquid crystalline honeycombs composed of type‐2 pentagonal prismatic cells and p2gg plane group symmetry. ABSTRACT Periodic pentagon tessellations are rarely observed in self‐assembled molecular systems.
Christian Anders +3 more
wiley +1 more source
Crystallization of Glasses: A Theoretical Analysis of the Role of Fragility and Polymorphism in Crystals. [PDF]
Bagchi B.
europepmc +1 more source
Persilylated and Related Silyl Anion‐Induced Synthesis of Group 3–10 Metal–Silyl Complexes
Persilylated and related silyl anions serve as powerful tools for constructing metal–silyl complexes across group 3–10 elements. Their strong σ‐donating ability and steric bulk stabilize low‐coordinate, reactive species and enable unique bonding motifs.
Yusuke Sunada
wiley +1 more source
Compressing Experiences of Optical Resolution Trials, Based on Diastereomeric Salt or Co-Crystal Formation, into Ternary Equilibrium Melting Phase Diagrams of Two Chiral Enantiomers and a Resolving Agent Molecule with the Help of DSC and Powder XRD. [PDF]
Madarász J.
europepmc +1 more source
Thermal defrosting limits desublimator efficiency in freeze‐drying. This review and case study compares thermal versus mechanical regeneration, links frost properties and external heat transfer to energy demand, and summarizes pilot‐scale scraping results enabling single‐unit, continuous lyophilization.
Moritz Krummenacher +3 more
wiley +1 more source
Microstructure & physicochemical properties dataset of NaCl-based salt mixtures for concentrating solar power. [PDF]
Feng Y, Wu Y, Wang W.
europepmc +1 more source
This study evaluates how small water impurities—typical in ammonia cracking feedstock—affect catalyst performance at elevated pressures and temperatures. By decoupling permanent degradation from reversible inhibition, the findings highlight trace water as a significant factor for reliable catalyst screening and industrial ammonia cracking scale‐up ...
Bruno V. P. Lago +6 more
wiley +1 more source

