Results 191 to 200 of about 22,587 (278)

Conformational Landscapes in the Ground and Excited States Dictate Circularly Polarized Excimer Emission: A Thermodynamic–Kinetic Interplay in Carbazole Dimer Systems

Angewandte Chemie, EarlyView.
Covalently linked carbazole dimers exhibit intense excimer‐based circularly polarized luminescence (CPL). A simple propylene‐tethered dimer achieves glum ≈ 0.01 in the violet region—among the highest for small organic emitters without heavy atoms. Conformational mapping reveals CPL is governed by thermodynamic/kinetic control of emissive conformers ...
Tomohiro Kujime, Zhe Wang, Tadashi Mori
wiley   +2 more sources

Water-Mediated Isomerization in the Stepwise Hydration of the Nitrobenzene Radical Cation with 1-6 Water Molecules. [PDF]

J Phys Chem A
Christensen ZA, Saunier JP, Mason KA, Lao KU, El-Shall MS.   +4 more
europepmc   +1 more source

Room‐Temperature Gas‐Phase CO2‐to‐C3 Coupling by a 4f‐Aromatic Cluster

Angewandte Chemie, EarlyView.
We engineered a 4f metalla aromatic cluster, PrB2C2−, that enables efficient sequential C−C coupling with CO2 at room temperature, yielding a linear C3 backbone. This system provides a complete theoretical catalytic cycle and establishes a new design principle for lanthanide mediated CO2 activation.
Feng‐Xiang Zhang, Xiao‐Wang Li, Ning‐Zheng Li, Sheng‐Gui He, Yu‐Chen Zhang, Li‐Li Xing, Donald G. Truhlar, Jia‐Bi Ma   +7 more
wiley   +2 more sources

Thermodynamics of Protonation and Prototropic Equilibria in Simple <i>para</i>- and Di-<i>meta</i>-Substituted Phenols. [PDF]

ACS Omega
Kováčová A, Michalík M, Hartmann H, Lukeš V.   +3 more
europepmc   +1 more source

Intermolecular Electrophilic Germylation Using GeCl4 and Al2Cl6

Angewandte Chemie, EarlyView.
While electrophilic aromatic substitution is well‐established for carbon and silicon‐based electrophiles, it is extremely underdeveloped for germanium. Herein we report the first effective intermolecular Germa–Friedel–Crafts reaction. The process can be modified to enable selective synthesis of the mono‐ or the di‐aryl germane derivatives, ArGeCl3 and ...
Justyna Łosiewicz, Milan Kumar Bisai, Zachary A. Bub, Stuart A. Macgregor, Michael J. Ingleson   +4 more
wiley   +2 more sources

Quantification of redox thermodynamics shifts within coacervates. [PDF]

Proc Natl Acad Sci U S A
Rodriguez G, Watkins NB, Faraji X, Lee E, Sepunaru L.   +4 more
europepmc   +1 more source

Site‐Selective B─H Activation via HAT Toward Xanthyl‐closo‐Carboranes as Bench‐Stable Precursors of Organosulfur Boron Clusters

Angewandte Chemie, EarlyView.
A light mediated direct regioselective B─H functionalization, via hydrogen atom transfer (HAT), is described. Unexplored xanthyl‐closo‐carboranes as novel bench‐stable and versatile platforms to access sulfur‐containing boron clusters are reported for the first time.
Marco Rusconi, Eugenia Magi, Polyssena Renzi, Emanuele Azzi, Valeria Lagostina, Enrico Salvadori, Mario Chiesa, Birgit Hischa, Giovanni Ghigo, Annamaria Deagostino   +9 more
wiley   +2 more sources

Determination and Validation of Standard Enthalpies of Formation and Sublimation of Potassium Salts Using Solution Calorimetry and Quantum-Chemical Calculations. [PDF]

ChemistryOpen
Amanollahi Z, Zaitsau DH, Müller K, Bokareva OS, Siewert R.   +4 more
europepmc   +1 more source

Sequence‐Encoded Frustration Directs the Formation of Abridged G‐Quadruplex Architectures

Angewandte Chemie, EarlyView.
Programmable frustration reshapes the free‐energy surface (FES) of guanine‐quadruplex (G4) folding, stabilizing an abridged G4 and a G‐triplex intermediate. ABSTRACT Frustration—competing interactions that cannot be simultaneously optimized—shapes energy landscapes in proteins and soft matter, but has rarely been exploited as a programmable design ...
Yuncheng Qian, Mohamed Y. Ali, Andreas I. Karsisiotis, Paul Dillon, Scarlett A. Dvorkin, Peter A. C. McPherson, Mateus Webba da Silva   +6 more
wiley   +2 more sources