Results 141 to 150 of about 26,006 (279)

Catalytic and mechanistic studies into the epoxidation of styrenes using manganese complexes of structurally similar polyamine ligands [PDF]

, 2014
Watkinson, M, Ilyashenko, G, Follier, T, De Faveri, G, Al-Safadi, R, Motevalli, M   +5 more
core   +1 more source

Convergent Total Synthesis of 16β‐Hydroxylpseudobufarenogin

Angewandte Chemie, Volume 138, Issue 23, 1 June 2026.
We present a novel convergent strategy that integrates Pd/Ag‐promoted Suzuki–Miyaura coupling with Ir‐catalyzed radical‐relay cyclization, enabling the first total synthesis of 16β‐hydroxylpseudobufarenogin. This approach is broadly applicable to the total synthesis of various oxygenated bufadienolides by simply modifying the fragment structures ...
Wataru Shigematsu, Yo Matsumoto, Koichi Hagiwara, Masayuki Inoue   +3 more
wiley   +2 more sources

A General Strategy for the Synthesis of Jerangolids Enabled by π‐allyl Stille Coupling

Chemistry – A European Journal, Volume 32, Issue 23, 16 June 2026.
A general strategy for the synthesis of jerangolids is established, featuring a late‐stage π‐allyl Stille coupling of two advanced, highly customizable building blocks to form the skipped diene core. The approach provides access to all naturally occurring jerangolids, including jerangolid H, whose configuration is confirmed by NMR analysis.
Janick Schug, Bernd Morgenstern, Johann Jauch   +2 more
wiley   +1 more source

Sulfur‐Directed Construction of Vinyl Cyclopropanes from 1,3‐Dienes

Angewandte Chemie International Edition, Volume 65, Issue 25, 15 June 2026.
Sulfur takes control. A pending thioether acts as a molecular compass, directing carbene addition to the 1,3‐diene scaffold with exceptional regio‑ and diastereocontrol to forge sulfur‐substituted vinyl cyclopropanes (S‐VCPs) — molecular architectures inaccessible via conventional cyclopropanation strategies.
Anna Keimer, Jonas Rettig, Tim‐Niclas Streit, Bob Barthel, Mélissa Calmels, Moritz Malischewski, Franz‐Lucas Haut   +6 more
wiley   +1 more source

Expanding the Toolbox for Biocatalytic Halogenation by Identification and Characterization of Three Vanadium Chloroperoxidases

ChemBioChem, Volume 27, Issue 11, 15 June 2026.
Schematic illustration of the workflow from DNA sequence‐based research to expression in shaking flasks and subsequent purification via IMAC. The obtained enzymes broaden the toolbox of enzymes used for halogenation reactions with differing catalytic properties and tolerances to reaction‐related conditions.
Sonja Schönrock, Nils Senge, Dirk Holtmann   +2 more
wiley   +1 more source

Correlation Between the Molecular Structure of Metal‐Supporting Ligands and Catalysis in the Oxygenase‐Mimicking Immobilized Metal Complex Catalysts

European Journal of Inorganic Chemistry, Volume 29, Issue 16, 4 June 2026.
The correlation between the structures of metal complexes immobilized in the mesopores of hydrophobically modified silicate supports was examined in relation to the catalytic activities toward C‐H oxidation. On the alkene oxidation with H2O2, the iron catalyst bearing bis(imidazolyl)methane ligand promotes allylic oxidation, whereas the mononuclear ...
Yuta Akizawa, Hiroe Fukuzaki, Nana Aizawa, Sho Ikeda, Airi Kawabe, Saori Nishiyama, Iori Nagasawa, Masaya Okamura, Shiro Hikichi   +8 more
wiley   +1 more source

Chemo-Enzymatic Epoxidation of Unsaturated Fatty Acids

, 2006
Epoxy fatty acids are useful molecules and find a number of applications e.g. as PVC plasticisers and stabilisers, additives in polyurethane production, reactive diluents in paints, corrosion protection agents, etc.
Orellana Coca Åkerman, Cecilia
core   +1 more source

Unveiling the Roles of Ti Species and Solvent in Propylene Epoxidation With H2O2 Over Titanosilicate‐1 Catalyst Through Density Functional Theory Insights

Carbon and Hydrogen, Volume 28, Issue 2, Page 269-283, June 2026.
This work employs density functional theory (DFT) calculations to identify the reaction mechanism and unveil the roles of Ti species and solvent in propylene epoxidation with H2O2 over TS‐1 catalyst. ABSTRACT The mechanism of propylene epoxidation catalyzed by distinct titanium (Ti) species within the TS‐1 framework was systematically explored through ...
Junxi Chen, Xue Wei, Xinyue Wang, Xiaowa Nie, Xinwen Guo   +4 more
wiley   +1 more source

Structural‐to‐Functional Complexity Transformations Enabled by Bridged Polyheterocycles: Access to Cis‐1,3‐Diamines and Amino‐Alcohols

ChemistryEurope, Volume 4, Issue 6, June 2026.
Polycyclic intermediates enable stereocontrolled synthesis of densely functionalized cis‐1,3‐diamine and amino alcohol carbocycles and heterocycles via structural‐to‐functional complexity transformations from low‐complexity starting material. Cis‐1,3‐functionalized carbocycles and saturated heterocycles are ubiquitous motifs in natural products ...
Jiayi Zhu, Erica Benedetti, Laurent Micouin   +2 more
wiley   +1 more source

Fe(porphyrin)-Catalyzed Alkene Epoxidation with NaOCl: A Practical Small- and Large-Scale Alternative to <i>m</i>CPBA. [PDF]

J Am Chem Soc
Maiti S, Baek D, Stahl SS.
europepmc   +1 more source