Results 121 to 130 of about 30,818 (251)
Cesium Promotion in Styrene Epoxidation on Silver Catalysts
Cesium Promotion in Styrene Epoxidation on Silver ...
Ling Zhou (51948) +2 more
core +1 more source
Post‐Synthetic Zinc Modifications to Correct Speciation in Ti‐MWW Zeolites for Catalytic Oxidation
Post‐synthetic Zn modifications of Ti‐MWW zeolite catalysts exhibit improved catalytic properties in the selective oxidation reaction, namely the ammoximation reaction. The origin of the beneficial effect of Zn is related via an array of spectroscopic and microscopic techniques to the modification of extra‐framework TiO2 and TiOx clusters and the ...
Christoph J. Kaul +10 more
wiley +2 more sources
We report the first example of direct electrochemical regeneration of a flavin-dependent monooxygenase for asymmetric epoxidation catalysis. It is shown that electrochemical regeneration of the oxygenase subunit of the multicomponent styrene ...
Karin Hofstetter (2683693) +4 more
core +1 more source
Development of a catalyst for epoxidation of methyl esters
The diploma thesis is focused on the study of heterogeneous catalysts in the epoxidation of rapeseed oil methyl ester. Epoxides of these components have applications in cutting oils, where they could replace hitherto used oils from fossil sources ...
Pham, Tien Thanh
core
π‐Extended Salphen Scaffolds Enable CO2 Electroreduction and Singlet Oxygen Generation
New family of π‐extended salen ligands bearing phenylene bridge and tunable phenyl‐based substituents, and their corresponding boron difluoride complexes. Thanks to the extended π‐delocalization over the molecule, the ligands themselves show promising results in electrochemical CO2 reduction to CO, while the complexes act as efficient photosensitizers ...
Vincenzo Langellotti +10 more
wiley +1 more source
Beyond the Oxo‐Wall: Synthesis and Reactivity of a Six‐Coordinate Formally CoIV‐Oxo Complex
We present the first example of a six‐coordinate formally Co(IV)‐oxo complex, [Co(TQA)(O)(OH)]+ (1), which exists as an admixture of CoIV‐oxo and CoIII‐oxyl resonance structures. Complex 1 is capable of performing oxygen atom transfer reactions and abstracting moderately strong hydrogen atoms at rates faster than other characterized CoIV‐oxo compounds.
Jason Shearer +6 more
wiley +2 more sources
The In-Situ Epoxidation of Rubber Seed Oil (Hevea brasiliensis) by Peroxyacids
This paper adds to the sustainable materials field by in-situ epoxidation of rubber seed oil (RSO), a highly underutilized resource that has been sporadically used, using an optimized combination of 30% hydrogen peroxide and acetic/formic acid sulfuric ...
Eni Budiyati +2 more
doaj +1 more source
Amide‐Enabled Reversal of Regioselectivity in Carbonyl‐Substituted Allenes
A substrate‐embedded secondary amide reverses the inherent regioselectivity of carbonyl‐substituted allenes, enabling rhodium‐catalyzed α‐acyloxylation with carboxylic acids. This redox‐neutral method requires no external oxidants or auxiliary‐type directing groups and tolerates diverse carboxylic acids.
Naoki Hikida +3 more
wiley +1 more source
Synthesis and Polymerization of a Lactone Building Block Derived From Cashew Nut Shells
Cardanol as a renewable substituted phenol feedstock was selectively transformed into the corresponding cyclohexanone derivative by means of a partial metal‐catalyzed hydrogenation. Subsequent conversion via Baeyer–Villiger oxidation gave a lactone product consisting of a mixture of regioisomers, which has been readily converted into its homopolymer ...
Paulo R. Wohlfahrt +6 more
wiley +1 more source
Chiral Ketone-Catalyzed Asymmetric Epoxidation of 2,2-Disubstituted Vinylsilanes
Chiral Ketone-Catalyzed Asymmetric Epoxidation of 2,2-Disubstituted ...
J. David Warren (439659) +1 more
core +1 more source

