Results 121 to 130 of about 29,601 (261)
We address the long‐standing challenge of reactivity–selectivity trade‐off by precisely tuning the redox properties of Fe(IV), rather than simply accelerating its formation, to enable chemically efficient and low‐emission water treatment. ABSTRACT High‐valent iron oxo species (Fe(IV)) are attractive for wastewater treatment because of their high ...
Hongyu Zhou +9 more
wiley +2 more sources
Sodium Hypochlorite Pentahydrate in Organic Synthesis and Beyond
Sodium hypochlorite pentahydrate emerges as a versatile, stable, and practical oxidant for organic synthesis. This review highlights its unique reactivity, broad synthetic applications, and growing impact on sustainable oxidation chemistry, providing a comprehensive overview of recent advances and future opportunities. Sodium hypochlorite pentahydrate (
Masayuki Kirihara +2 more
wiley +1 more source
A continuous catalytic epoxidation process using molecular oxygen and heterogeneous catalysts was evaluated for the first time to produce epoxidized biodiesel.
Wonjin Jeon, Ji-Yeon Park, Deog-Keun Kim
doaj +1 more source
Co-SAPO-5 and Co-SAPO-34 were prepared by a simple ion-exchange route and firstly applied in the aerobic epoxidation of alkenes. Both catalysts exhibited high activities in the epoxidation of alkenes with air to achieve 92.0-91.9 mol% conversion with the
Zhang, J. -L. +8 more
core +1 more source
Two factors identified by co‐expression analysis of photosynthetic regulators are described, which are involved in thylakoid pigment content and composition and, through their function, shape the dynamics of NPQ. Abstract Rapid fluctuations in light intensity require swift regulatory adjustments of photosynthesis. Although the major plant regulators of
J.‐M. Keller +11 more
wiley +1 more source
Development of modified MCM-41 catalyst system towards epoxidation of 1-octene and Methyl Oleate / Suhaila Mohamed [PDF]
The discovery of mesoporous molecular sieves has created a tremendous interest in the synthesis of these materials, particularly MCM-41 and its analogue, because of their very high surface areas and possibility of precisely tuned pore sizes (20-100 Å ...
Mohamed, Suhaila
core
The In-Situ Epoxidation of Rubber Seed Oil (Hevea brasiliensis) by Peroxyacids
This paper adds to the sustainable materials field by in-situ epoxidation of rubber seed oil (RSO), a highly underutilized resource that has been sporadically used, using an optimized combination of 30% hydrogen peroxide and acetic/formic acid sulfuric ...
Eni Budiyati +2 more
doaj +1 more source
A new quaternary ammonium heteropolyoxotungstant (cat.C) is prepared and characterized. And the cat.C also is an reaction-controlled phase-transfer catalyst.
Li, M, Xi, ZW, Lu, Y, Gao, S, Zhang, RH
core
Catalytic Sulfur‐Atom Transfer Enabled by a Bis(disulfide) Titanium Complex
Multi‐electron transformations with titanium are underexplored due to limited access to low‐valent precursors. The four‐electron activation of elemental sulfur by a Ti(IV) complex yields a rare titanium bis(disulfide) complex, enabling the efficient catalytic synthesis of isothiocyanates from isonitriles under mild conditions.
Sebastian Samir Cremer +3 more
wiley +1 more source
Stereochemistry of Epoxidation of Some Caryophyllenols
Epoxidation of the caryophyllene allylic alcohols 3−5 by tert-butyl hydroperoxide/vanadyl acetylacetonate afforded the epoxides 6a, 7, and 8, respectively. The tetracyanoethylene-catalyzed solvolysis shed some light on the stereochemistry of epoxidation.
Peter B. Hitchcock (2009605) +3 more
core +1 more source

