Results 101 to 110 of about 30,818 (251)
Iminium Salt Catalysts for Asymmetric Epoxidation: The First High Enantioselectivities
A highly enantioselective iminium salt catalyst has been prepared and tested in the catalytic asymmetric epoxidation of unfunctionalized alkenes, giving up to 95% ee, the highest ee yet reported for iminium salt-catalyzed epoxidation.
Benjamin R. Buckley (1299393) +2 more
core +1 more source
Spatial and temporal scales in plant phenotyping for crop water stress assessment: A review
Abstract Water stress is a major limiting factor for crop productivity worldwide, and its impacts are intensifying due to climate variability and increasing water scarcity. This review focuses on the spatial and temporal scales in plant phenotyping as a critical approach to improving crop water‐stress assessment and supporting precision water ...
Daniel Kingsley Cudjoe +3 more
wiley +1 more source
We report the computational design of de novo proteins that bind Mn(salen)‐based complexes (L1) using Rosetta FastDesign and verified by AlphaFold2. After screening, the catalytic activity for the promising design (dnMSBP) toward enantioselective sulfoxidation of thioanisole was optimized based on its crystal structure. With 10 different substrates, we
Jing‐Xiang Wang +6 more
wiley +2 more sources
Multienzyme Cascade Reactions: Compatibility, Cooperativity, and Control
Multienzyme cascade reactions are sequences of telescoped biotransformations that avoid the isolation of intermediates and offer significant efficiency advantages over traditional multistep routes. This review article highlights recent examples of multienzyme cascades and explores how their success depends on the consideration of compatibility ...
Isabella E. E. Kroschel +2 more
wiley +1 more source
Asymmetric epoxidation catalyzed by chiral ketones
Chiral ketones have been developed as efficient catalysts for asymmetric alkene epoxidation in the past decades. The development of different classes of chiral ketones for asymmetric epoxidation of unfunctionalized alkenes will be discussed. In addition,
Yang, D +5 more
core +1 more source
Substrate‐Dependent Crosslinking by the Cytochrome P450 From Aminopyruvatide Biosynthesis
Substitutions in the aminopyruvatide precursor peptide altered the C─C linkage formed from a YLY motif by the P450 ApyO to a N─C linkage in a WLY motif. Moreover, constitutional isomers crosslinked by C─C and C─O linkages were formed from YYY or YWY motifs. ABSTRACT Cytochrome P450s catalyze an array of reactions including crosslinking of aromatic side
Chandrashekhar Padhi +6 more
wiley +2 more sources
Dimethyldioxirane epoxidation of polycyclic fluoranthene hydrocarbons
Direct epoxidation of polycyclic fluoranthenes with dimethyldioxirane provides several new mono-and di-oxide ...
Cho, Bongsup P., Liu, Fushuang
core +1 more source
Two chiral imidazolium salts and one chiral triazolium salt were synthesized containing a chiral cyclohexane bridge based on the salen ligand framework of the Jacobsen-Katsuki epoxidation catalysts.
Tim P. Schlachta +2 more
doaj +1 more source
Enantiomerically enriched glycidol derivatives with contiguous stereogenic centers were obtained in a highly diastereo- and enantio-selective epoxidation catalyzed with the styrene monooxygenase ...
Liu, Yan +3 more
core
This review firstly summarizes the update of meroterpenoids from February 2020 to December 2025 by applying a new classification method based on twelve key non‐terpene precursors. ABSTRACT Meroterpenoids are a class of hybrid natural products, biosynthesized from terpenoid fragments and non‐terpenoid precursors, exhibiting a wide range of biological ...
Yuqian Tang +6 more
wiley +1 more source

