Results 101 to 110 of about 30,818 (251)

Iminium Salt Catalysts for Asymmetric Epoxidation:  The First High Enantioselectivities

open access: yes, 2016
A highly enantioselective iminium salt catalyst has been prepared and tested in the catalytic asymmetric epoxidation of unfunctionalized alkenes, giving up to 95% ee, the highest ee yet reported for iminium salt-catalyzed epoxidation.
Benjamin R. Buckley (1299393)   +2 more
core   +1 more source

Spatial and temporal scales in plant phenotyping for crop water stress assessment: A review

open access: yesThe Plant Phenome Journal, Volume 9, Issue 1, December 2026.
Abstract Water stress is a major limiting factor for crop productivity worldwide, and its impacts are intensifying due to climate variability and increasing water scarcity. This review focuses on the spatial and temporal scales in plant phenotyping as a critical approach to improving crop water‐stress assessment and supporting precision water ...
Daniel Kingsley Cudjoe   +3 more
wiley   +1 more source

De Novo Design and Structural Optimization of Mn(salen)‐Based Artificial Metalloenzymes for Asymmetric Sulfoxidation

open access: yesAngewandte Chemie, Volume 138, Issue 44, 26 October 2026.
We report the computational design of de novo proteins that bind Mn(salen)‐based complexes (L1) using Rosetta FastDesign and verified by AlphaFold2. After screening, the catalytic activity for the promising design (dnMSBP) toward enantioselective sulfoxidation of thioanisole was optimized based on its crystal structure. With 10 different substrates, we
Jing‐Xiang Wang   +6 more
wiley   +2 more sources

Multienzyme Cascade Reactions: Compatibility, Cooperativity, and Control

open access: yesAdvanced Synthesis &Catalysis, Volume 368, Issue 21, 3 November 2026.
Multienzyme cascade reactions are sequences of telescoped biotransformations that avoid the isolation of intermediates and offer significant efficiency advantages over traditional multistep routes. This review article highlights recent examples of multienzyme cascades and explores how their success depends on the consideration of compatibility ...
Isabella E. E. Kroschel   +2 more
wiley   +1 more source

Asymmetric epoxidation catalyzed by chiral ketones

open access: yes, 2011
Chiral ketones have been developed as efficient catalysts for asymmetric alkene epoxidation in the past decades. The development of different classes of chiral ketones for asymmetric epoxidation of unfunctionalized alkenes will be discussed. In addition,
Yang, D   +5 more
core   +1 more source

Substrate‐Dependent Crosslinking by the Cytochrome P450 From Aminopyruvatide Biosynthesis

open access: yesAngewandte Chemie, Volume 138, Issue 44, 26 October 2026.
Substitutions in the aminopyruvatide precursor peptide altered the C─C linkage formed from a YLY motif by the P450 ApyO to a N─C linkage in a WLY motif. Moreover, constitutional isomers crosslinked by C─C and C─O linkages were formed from YYY or YWY motifs. ABSTRACT Cytochrome P450s catalyze an array of reactions including crosslinking of aromatic side
Chandrashekhar Padhi   +6 more
wiley   +2 more sources

Dimethyldioxirane epoxidation of polycyclic fluoranthene hydrocarbons

open access: yes, 1999
Direct epoxidation of polycyclic fluoranthenes with dimethyldioxirane provides several new mono-and di-oxide ...
Cho, Bongsup P., Liu, Fushuang
core   +1 more source

Chiral imidazolium and triazolium salts as NHC and aNHC ligand precursors: A promising framework for asymmetric epoxidation catalysis

open access: yesResults in Chemistry
Two chiral imidazolium salts and one chiral triazolium salt were synthesized containing a chiral cyclohexane bridge based on the salen ligand framework of the Jacobsen-Katsuki epoxidation catalysts.
Tim P. Schlachta   +2 more
doaj   +1 more source

Highly diastereo- and enantio-selective epoxidation of secondary allylic alcohols catalyzed by styrene monooxygenase

open access: yes, 2011
Enantiomerically enriched glycidol derivatives with contiguous stereogenic centers were obtained in a highly diastereo- and enantio-selective epoxidation catalyzed with the styrene monooxygenase ...
Liu, Yan   +3 more
core  

Meroterpenoids Produced by Fungi: Occurrence, Structural Diversity, and Biological Activity (An Update: February 2020 to December 2025)

open access: yesChemistry &Biodiversity, Volume 23, Issue 11, November 2026.
This review firstly summarizes the update of meroterpenoids from February 2020 to December 2025 by applying a new classification method based on twelve key non‐terpene precursors. ABSTRACT Meroterpenoids are a class of hybrid natural products, biosynthesized from terpenoid fragments and non‐terpenoid precursors, exhibiting a wide range of biological ...
Yuqian Tang   +6 more
wiley   +1 more source

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