Results 81 to 90 of about 26,006 (279)

Mesoporous SiO2–TiO2 Epoxidation Catalysts: Tuning Surface Polarity to Improve Performance in the Presence of Water

, 2018
In order to circumvent the deactivation of the amorphous and mesoporous TiO2–SiO2 catalyst, we investigated the effect of surface hydrophobization on the catalyst activity in the presence of water for the epoxidation of ...
Lilia Ben, Mustapha, Lilia Ben Mustapha (4977218), Schnee, Josefine, Ben Mustapha, Lilia, Valentin, Smeets, Eric M., Gaigneaux, Lilia Ben Mustapha, Damien Debecker (4977188), Gaigneaux, Eric M., Damien P. Debecker, Valentin Smeets (4977215), Eric M. Gaigneaux (1975606), Josefine Schnee, Damien Debecker, Damien, Debecker, Smeets, Valentin, Eric M. Gaigneaux, Valentin Smeets, Josefine, Schnee, Josefine Schnee (3614978), Debecker, Damien P.   +20 more
core   +1 more source

Safranal epoxide – A potential source for diverse therapeutic applications

Saudi Pharmaceutical Journal, 2018
Safranal is an organic compound isolated from saffron oil. Photo epoxidation and thermal reactions of safranal can be a significant tool for the design of drugs to act as anticancer agents and potent chemoprevention.
Suzan Khayyat, Eman Elgendy
doaj   +1 more source

A Self‐Enhanced Tandem Catalytic System for Olefin‐to‐Diol Conversion Powered by Single‐Atom Fe Catalysts With In Situ Generated Acid

EcoEnergy, EarlyView.
A single‐atom iron catalyst with well‐defined Fe–N4 sites enables a tandem epoxidation‐hydrolysis process for converting terminal olefins to 1,2‐diols. The in situ‐generated isobutyric acid drives the hydrolysis step, affording broad substrate scope and excellent recyclability.
Tao‐Tao Liu, Shuai‐Long Yang, Xiao‐Hui Huang, Jun Liang, Peng‐Chao Shi, Rui Xu, Yuan‐Biao Huang, Rong Cao   +7 more
wiley   +1 more source

Electrochemical epoxidation enhanced by C2H4 activation and hydroxyl generation at the Ag/SnO2 interface

Nature Communications
Direct electrochemical ethylene (C2H4) epoxidation with water (H2O) represents a promising approach for the production of value-added ethylene oxide (EO) in a sustainable way.
Hao Dong, Ran Luo, Gong Zhang, Lulu Li, Chaoxi Wang, Guodong Sun, Hongyi Wang, Jiachang Liu, Tuo Wang, Zhi-Jian Zhao, Peng Zhang, Jinlong Gong   +11 more
doaj   +1 more source

Enantiospecific Acid‐Catalysed Hydroperoxidation of Scalemic Tertiary Benzylic Alcohols Facilitating a Concise Asymmetric Synthesis of Yingzhaosu C

European Journal of Organic Chemistry, EarlyView.
Asymmetric synthesis of antimalarial yingzhaosu C was achieved in 4–5 steps by asymmetric Grignard synthesis of (R)‐gossonorol followed by novel enantiospecific hydroperoxidation. We report a concise asymmetric synthesis of antimalarial yingzhaosu C in 59% ee.
Saranna E. Kavanagh, Claudio Monasterolo, Declan G. Gilheany   +2 more
wiley   +1 more source

Total Synthesis of Sacrolide A and Cytotoxic Evaluation

European Journal of Organic Chemistry, EarlyView.
Isolated from the edible cyanobacterium Aphanothece sacrum, sacrolide A is a highly potent antimicrobial and cytotoxic metabolite. Its total synthesis via a convergent strategy enabled accurate assessment of its effects on liver and colon cells, offering new insights into its bioactivity and potential health risks.
Priyanka Kataria, Kamel Hadj‐Kaddour, Alexis Giraudon, Jawad Belkheir, Alexandre Guy, Thierry Durand, Magali Gary‐Bobo, Camille Oger   +7 more
wiley   +1 more source

Epoxidation of Cashmeran and Unprecedented Rearrangement to an α‐Carbonyl δ‐Spirolactone

European Journal of Organic Chemistry, EarlyView.
A new strategy enables diastereoselective conversion of Cashmeran into a previously unknown α‐carbonyl δ‐spirolactone via epoxidation, Baeyer–Villiger oxidation, and acid‐catalyzed rearrangement. Structure and mechanism were confirmed by NMR, single crystal X‐ray diffraction, and computational studies. We report the epoxidation of Cashmeran followed by
Lukas Kell, Niklas Bartsch, Johannes Panten, Marcus Eh, Jan Paradies, Hans Egold, Anke Spannenberg, Thomas Werner   +7 more
wiley   +1 more source

New catalyst for the epoxidation of olefins [PDF]

, 2008
This thesis describes the development of inexpensive and practical iron catalysts for the environmentally benign epoxidation of olefins with hydrogen peroxide as terminal oxidant.
Bitterlich, Bianca (gnd: 137022905)
core   +1 more source

Chemistry Underlying the Behavior of Food and Agricultural Components During Industrial Manufacturing Processes and Its Implications in Quality Assurance, Food Quality, and Food Safety Management: A Systematic Review

Food Safety and Health, EarlyView.
Industrial manufacturing processes have transformative effects on the components of food matrix. These transformations in food matrix and components have direct implications for quality assurance (QA), food quality (e.g., nutritional profile and texture), and food safety management (e.g., pathogen control and toxin mitigation). ABSTRACT This systematic
Chinaza Godswill Awuchi
wiley   +1 more source

A Green Amphoteric Surfactant Derived From Rapeseed Oil for Enhanced Oil Recovery From Carbonate Acidic Oil Reservoirs

Journal of Surfactants and Detergents, EarlyView.
The Green Amphoteric Surfactant Derived From Rapeseed Oil for Enhanced Oil Recovery From Carbonate Acidic Oil Reservoirs. ABSTRACT Surfactants with both positive and negative functional groups (amphoteric or zwitterionic) are particularly advantageous in acidic oil reservoirs because they remain stable under harsh chemical conditions, tolerate acidic ...
Iman Nowrouzi, Amir H. Mohammadi, Abbas Khaksar Manshad   +2 more
wiley   +1 more source