Results 71 to 80 of about 48,446 (261)
One-pot multi-reaction processes: synthesis of natural products and drug-like scaffolds [PDF]
One-pot multi-reaction processes involving Overman rearrangements, metathesis cyclizations, and Diels–Alder reactions have been developed for the rapid and efficient synthesis of amino-substituted carbocyclic and heterocyclic compounds.
Calder, Ewen D.D. +2 more
core +1 more source
Learning Strategies from Nature's Blueprint to Cyclic Carbonate Synthesis
The development of sustainable synthetic methods for cyclic carbonates draws inspiration from nature, focusing on eco‐friendly processes and renewable resources like CO2 and biomass. This review explore various CO2 activation mechanisms, green chemistry principles, and green catalysts.
Erika Saccullo +4 more
wiley +1 more source
ROLE OF Mn(TPP)Cl IN THE EPOXIDATION WITH SINGLET OXYGEN [PDF]
Mn(TPP)Cl catalyzes cooxidation of olefin in the singlet oxygenation of sulfid. Mn(TPP)Cl is able to transfer an oxygen atom from a peroxidic intermediate generated in singlet oxygenation of sulfide to a metal ion affording metal 0x0 species which is ...
doaj
Chemoenzymatic Epoxidation of Alkenes and Reusability Study of the Phenylacetic Acid
Here, we focused on a simple enzymatic epoxidation of alkenes using lipase and phenylacetic acid. The immobilised Candida antarctica lipase B, Novozym 435 was used to catalyse the formation of peroxy acid instantly from hydrogen peroxide (H2O2) and ...
Emilia Abdulmalek +5 more
doaj +1 more source
The correlation between the structures of metal complexes immobilized in the mesopores of hydrophobically modified silicate supports was examined in relation to the catalytic activities toward C‐H oxidation. On the alkene oxidation with H2O2, the iron catalyst bearing bis(imidazolyl)methane ligand promotes allylic oxidation, whereas the mononuclear ...
Yuta Akizawa +8 more
wiley +1 more source
Knock-Out of the Genes Coding for the Rieske Protein and the ATP-Synthase δ-Subunit of Arabidopsis [PDF]
In Arabidopsis, the nuclear genes PetC and AtpD code for the Rieske protein of the cytochrome b6/f (cyt b6/f) complex and the δ-subunit of the chloroplast ATP synthase (cpATPase), respectively.
Dietzmann, Angela +8 more
core +1 more source
A Practical and Flexible De Novo Synthesis of Deoxygenated Carbasugars and Their Cyclitol Epoxides
A de novo synthesis route comprising enantioselective Brown crotylation and ring‐closing metathesis as the key steps enables the synthesis of a‐ and b‐carba‐paratose, a‐ and b‐carba‐colitose as well as four configurational deoxycyclophellitol isosteres.
Yevhenii Radchenko +4 more
wiley +1 more source
Lipase-mediated epoxidation of alkenes in supercritical carbon dioxide
In this work, supercritical carbon dioxide was used as reaction media in the lipase-mediated epoxidation of alkenes for the first time. Under the optimal conditions (alkene (1 mmol), novozym 435 (15 mg), H2O2 (50% aqueous solution, 1.4 mmol), n-caprylic ...
Jiaxin Zhang +7 more
doaj +1 more source
The investigation of optimum condition of natural rubber epoxidation reaction in latex phase
Natural rubber (NR) latex epoxidation is a chemical modifcation of natural rubber to produce natural rubber with higher polarity (oil resistant) which is commonly called epoxidized natural rubber (ENR). ENR is produced from the reaction of natural rubber
Norma Arisanti Kinasih +3 more
doaj +1 more source
Epoxidation of the C=C double bond in unsaturated norlignans derived from hydroxymatairesinol was studied. The intermediate epoxides were formed in up to quantitative conversions and were readily further transformed into tetrahydrofuran, aryltetralin ...
Patrik A. Runeberg +2 more
doaj +1 more source

