Results 71 to 80 of about 48,446 (261)

One-pot multi-reaction processes: synthesis of natural products and drug-like scaffolds [PDF]

open access: yes, 2014
One-pot multi-reaction processes involving Overman rearrangements, metathesis cyclizations, and Diels–Alder reactions have been developed for the rapid and efficient synthesis of amino-substituted carbocyclic and heterocyclic compounds.
Calder, Ewen D.D.   +2 more
core   +1 more source

Learning Strategies from Nature's Blueprint to Cyclic Carbonate Synthesis

open access: yesChemSusChem, Volume 18, Issue 6, March 15, 2025.
The development of sustainable synthetic methods for cyclic carbonates draws inspiration from nature, focusing on eco‐friendly processes and renewable resources like CO2 and biomass. This review explore various CO2 activation mechanisms, green chemistry principles, and green catalysts.
Erika Saccullo   +4 more
wiley   +1 more source

ROLE OF Mn(TPP)Cl IN THE EPOXIDATION WITH SINGLET OXYGEN [PDF]

open access: yesJournal of Sciences, Islamic Republic of Iran, 2000
Mn(TPP)Cl catalyzes cooxidation of olefin in the singlet oxygenation of sulfid. Mn(TPP)Cl is able to transfer an oxygen atom from a peroxidic intermediate generated in singlet oxygenation of sulfide to a metal ion affording metal 0x0 species which is ...
doaj  

Chemoenzymatic Epoxidation of Alkenes and Reusability Study of the Phenylacetic Acid

open access: yesThe Scientific World Journal, 2014
Here, we focused on a simple enzymatic epoxidation of alkenes using lipase and phenylacetic acid. The immobilised Candida antarctica lipase B, Novozym 435 was used to catalyse the formation of peroxy acid instantly from hydrogen peroxide (H2O2) and ...
Emilia Abdulmalek   +5 more
doaj   +1 more source

Correlation Between the Molecular Structure of Metal‐Supporting Ligands and Catalysis in the Oxygenase‐Mimicking Immobilized Metal Complex Catalysts

open access: yesEuropean Journal of Inorganic Chemistry, EarlyView.
The correlation between the structures of metal complexes immobilized in the mesopores of hydrophobically modified silicate supports was examined in relation to the catalytic activities toward C‐H oxidation. On the alkene oxidation with H2O2, the iron catalyst bearing bis(imidazolyl)methane ligand promotes allylic oxidation, whereas the mononuclear ...
Yuta Akizawa   +8 more
wiley   +1 more source

Knock-Out of the Genes Coding for the Rieske Protein and the ATP-Synthase δ-Subunit of Arabidopsis [PDF]

open access: yes, 2003
In Arabidopsis, the nuclear genes PetC and AtpD code for the Rieske protein of the cytochrome b6/f (cyt b6/f) complex and the δ-subunit of the chloroplast ATP synthase (cpATPase), respectively.
Dietzmann, Angela   +8 more
core   +1 more source

A Practical and Flexible De Novo Synthesis of Deoxygenated Carbasugars and Their Cyclitol Epoxides

open access: yesEuropean Journal of Organic Chemistry, EarlyView.
A de novo synthesis route comprising enantioselective Brown crotylation and ring‐closing metathesis as the key steps enables the synthesis of a‐ and b‐carba‐paratose, a‐ and b‐carba‐colitose as well as four configurational deoxycyclophellitol isosteres.
Yevhenii Radchenko   +4 more
wiley   +1 more source

Lipase-mediated epoxidation of alkenes in supercritical carbon dioxide

open access: yesGreen Chemistry Letters and Reviews, 2018
In this work, supercritical carbon dioxide was used as reaction media in the lipase-mediated epoxidation of alkenes for the first time. Under the optimal conditions (alkene (1 mmol), novozym 435 (15 mg), H2O2 (50% aqueous solution, 1.4 mmol), n-caprylic ...
Jiaxin Zhang   +7 more
doaj   +1 more source

The investigation of optimum condition of natural rubber epoxidation reaction in latex phase

open access: yesMajalah Kulit, Karet, dan Plastik, 2021
Natural rubber (NR) latex epoxidation is a chemical modifcation of natural rubber to produce natural rubber with higher polarity (oil resistant) which is commonly called epoxidized natural rubber (ENR). ENR is produced from the reaction of natural rubber
Norma Arisanti Kinasih   +3 more
doaj   +1 more source

Formation of Tetrahydrofurano-, Aryltetralin, and Butyrolactone Norlignans through the Epoxidation of 9-Norlignans

open access: yesMolecules, 2020
Epoxidation of the C=C double bond in unsaturated norlignans derived from hydroxymatairesinol was studied. The intermediate epoxides were formed in up to quantitative conversions and were readily further transformed into tetrahydrofuran, aryltetralin ...
Patrik A. Runeberg   +2 more
doaj   +1 more source

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