Results 51 to 60 of about 30,818 (251)

Epoxides and Soluble Epoxide Hydrolase in Cardiovascular Physiology [PDF]

open access: yesPhysiological Reviews, 2012
Epoxyeicosatrienoic acids (EETs) are arachidonic acid metabolites that importantly contribute to vascular and cardiac physiology. The contribution of EETs to vascular and cardiac function is further influenced by soluble epoxide hydrolase (sEH) that degrades EETs to diols. Vascular actions of EETs include dilation and angiogenesis.
openaire   +2 more sources

Molybdenum containing surface complex for olefin epoxidation

open access: yes, 2003
Silica-supported molybdenum surface complexes were prepared by the reaction between (N=) Mo(OtBu)(3) and silica via displacement of the tert-butoxy ligands for siloxyls from the silica surface.
Basset, JM, Coperet, C, Yang, QH, Li, C
core   +1 more source

Biosynthesis of sulfonated carbon catalyst from carbohydrate polymer derivatives for epoxidation of Croton macrostachyus seed oil

open access: yesCarbohydrate Polymer Technologies and Applications, 2022
In the present study, biosynthesis of sulfonated carbon acid catalyst from brewery spent grain through carbonation process followed by sulphonation method used for production of epoxy oil from Croton macrostachyus seed oil in presence of acetic acid as ...
Tafere Aga Bullo   +2 more
doaj   +1 more source

Epoxidação do óleo de mamona e derivados empregando o sistema catalítico VO(acac)2/TBHP Epoxidation of castor oil and its derivatives using VO(acac)2/TBHP as the catalytic system

open access: yesQuímica Nova, 2008
The alternative system VO(acac)2/TBHP was investigated for the epoxidation reaction of castor oil and its derivatives. Results of 88% of conversion, 73% of epoxidation and 82% of selectivity were obtained for the system containing 20% excess of TBHP and ...
Marta Regina dos Santos Nunes   +2 more
doaj   +1 more source

Attempted Synthesis of Vinca Alkaloids Condensed with Three-Membered Rings

open access: yesMolecules, 2018
Our successful work for the synthesis of cyclopropanated vinblastine and its derivatives by the Simmons–Smith reaction was followed to build up further three-membered rings into the 14,15-position of the vindoline part of the dimer alkaloid ...
András Keglevich   +8 more
doaj   +1 more source

Synthesis of a Stable Hydrophilic trans‐Cyclooctene Amino Acid Unlocks Fast Bioorthogonal Click Chemistry for the Generation of Antibody‐Drug Conjugates by Genetic Code Expansion

open access: yesAngewandte Chemie International Edition, EarlyView.
A novel trans‐cyclooctene (TCO) based noncanonical amino acid (ncAA) is reported, characterized by high hydrophilicity and remarkable stability to trans‐cis isomerization. Its incorporation via genetic code expansion into an antibody and subsequent conjugation resulted in a highly efficacious antibody‐drug conjugate (ADC).
Georgi R. Genov   +4 more
wiley   +1 more source

A Convergent Materials Design Paradigm Across Electro‐ and Photocatalysis for Sustainable Hydrogen Peroxide Production

open access: yesCarbon Energy, EarlyView.
This review outlines advanced modification strategies for electrocatalytic and photocatalytic H2O2 production, covering bandgap tuning, defect engineering, heterostructure construction, cocatalyst loading, and functional framework design. Structure‐performance correlations are revealed across catalysts such as metal oxides, sulfides, carbon nitrides ...
Na Li   +9 more
wiley   +1 more source

MurNAc‐Based Electrophilic Inhibitors of O‐Acetylpeptidoglycan Esterase (Ape): Design, Synthesis, and Kinetic Evaluation

open access: yesChemistry – A European Journal, EarlyView.
A series of N‐acetylmuramic acid (MurNAc)‐based electrophilic inhibitors targeting Ape esterase was synthesized. Their inhibitory potency ranged from micromolar to submillimolar. The study probed binding contributions of stem peptide extension, replacing the anomeric methyl group with a benzyl, and α‐fluorination of the carbonyl to enhance ...
Dmytro Voskoboinyk, Martin E. Tanner
wiley   +1 more source

What leads to direct epoxidation? An exhaustive DFT investigation of electrophilic oxygen mediated epoxidation of ethylene on Ag(100) [PDF]

open access: yes
Extensive research has contributed to a better understanding of the commercially important epoxidation reaction. Selectivity, a crucial aspect of this reaction, has re- ceived significant attention in both experimental and theoretical investigations. How-
Aathira, Nair, Kavita , Joshi
core   +2 more sources

A lumped modelling framework for the epoxidation of vegetable oils and fatty acid methyl esters

open access: yesThe Canadian Journal of Chemical Engineering, EarlyView.
Abstract Epoxidized vegetable oils and fatty acid methyl esters are promising bio‐based alternatives to phthalates for plasticizer applications. Their synthesis typically involves the reaction of unsaturated double bonds with peracetic acid in a biphasic liquid–liquid system, where the simultaneous occurrence of reaction and phase partitioning makes ...
Irene Presti   +3 more
wiley   +1 more source

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