Results 11 to 20 of about 84,237 (324)

Br−/BrO−-mediated highly efficient photoelectrochemical epoxidation of alkenes on α-Fe2O3

open access: yesNature Communications, 2023
Alkene epoxidation, whose products are important intermediates for the manufacture of pharmaceuticals and epoxy resins, has attracted extensive attention.
Yukun Zhao   +9 more
doaj   +2 more sources

Biomimetic Mn(III) porphyrin-catalyzed aromaticity-breaking epoxidation of electron-deficient naphthalene [PDF]

open access: yesNature Communications
Selective catalytic aromaticity-breaking epoxidation of arenes remains an ongoing research challenge, attributed to the stability of aromatic systems, the occurrence of over-oxidation, and the instability of epoxides.
Hongli Wu   +7 more
doaj   +2 more sources

The diastereoselective Meth-Cohn epoxidation of camphor-derived vinyl sulfones [PDF]

open access: bronze, 2012
Some camphor-derived vinyl sulfones bearing oxygen functionality at the allylic position have been synthesized and their nucleophilic epoxidation reactions under Meth-Cohn conditions have been explored.
Adam   +91 more
core   +3 more sources

Research Progress in Epoxidation of Light Small-Molecule Olefins [PDF]

open access: yesMolecules
Light olefins, as important bulk raw materials in the petrochemical industry, play an irreplaceable role in the development of the manufacturing industry and the economy.
Guanghui Zhao   +8 more
doaj   +2 more sources

In situ formation of catalytically active graphene in ethylene photo-epoxidation. [PDF]

open access: yesNature Communications, 2018
Ethylene epoxidation is used to produce 2 × 107 ton per year of ethylene oxide, a major feedstock for commodity chemicals and plastics. While high pressures and temperatures are required for the reaction, plasmonic photoexcitation of the Ag catalyst ...
Heo, Jaeyoung   +3 more
core   +3 more sources

Niobia as an efficient catalyst for the epoxidation of dicyclopentadiene

open access: yesCatalysis Communications, 2023
We studied the epoxidation of dicyclopentadiene (DCPD) with hydrogen peroxide over different heterogeneous catalysts. Among them, niobium pentoxide (Nb2O5) catalysts showed promising catalytic activity, giving mono- and di-epoxy DCPD with low amounts of ...
Sang-Ho Chung   +3 more
doaj   +1 more source

Synthesis and Kinetic Model of Oleic Acid-based Epoxides by In Situ Peracid Mechanism [PDF]

open access: yesKemija u Industriji, 2022
The global consumption of raw materials has shifted from the use of non-renewable materials to renewable materials. Studies on greener epoxidation by using vegetable oils to produce eco-friendly epoxides have also increased.
Intan Suhada Azmi   +5 more
doaj   +1 more source

Regulating the electronic structure through charge redistribution in dense single-atom catalysts for enhanced alkene epoxidation

open access: yesNature Communications, 2023
Inter-site interaction in densely populated single-atom catalysts has been demonstrated to have a crucial role in regulating the electronic structure of metal atoms, and consequently their catalytic performances.
Hong-Sung Jin   +7 more
semanticscholar   +1 more source

An Electrocatalytic/Heterogeneous Catalytic Cascade for Selective Production of Propylene Oxide via Anodic H2O2 Generation. [PDF]

open access: yesAngew Chem Int Ed Engl
This work demonstrates a cascade strategy for the selective synthesis of propylene oxide (PO) by coupling anodic H2O2 generation with TS‐1 catalyzed propylene epoxidation. By immobilizing TS‐1 on a gas diffusion layer, the system achieves high PO productivity with efficient H2O2 utilization, providing a safer and greener alternative to conventional PO ...
Chandra S   +5 more
europepmc   +2 more sources

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