Results 91 to 100 of about 233,639 (295)

Single‐Atom Pt Anchoring on Self‐Doped ZrO2@G‐C3N4 Nanostructure Enables Efficient Photocatalytic Seawater Hydrogen Evolution

open access: yesAdvanced Science, EarlyView.
Grain‐like Zr3+‐ZrO2 and Pt single atoms are integrated into an S‐scheme Zr3+‐ZrO2@g‐C3N4 heterostructure to enable efficient visible‐light‐driven seawater hydrogen production. The combined effect of Pt single‐atom sites and the S‐scheme charge‐transfer pathway accelerates carrier separation, preserves strong redox ability, and markedly enhances ...
Hezheng Sun   +8 more
wiley   +1 more source

Oral Bioinspired Peroxisome‐Engineered Probiotics for Modulating Gut Microbiota Homeostasis and Alleviating Cardiac Chemotherapy Toxicity

open access: yesAdvanced Science, EarlyView.
This study developed an oral bioinspired peroxisome‐engineered probiotic (BPEP) by anchoring lipid‐encapsulated ruthenium nanozymes onto Escherichia coli Nissle 1917, utilizing probiotics to deliver nanozymes to the intestinal barrier for reactive oxygen species/reactive nitrogen species elimination, tight junction restoration, and gut microbiota ...
Shuyu Wang   +10 more
wiley   +1 more source

Axial F–Bi–Ov Electron Pump Drives Continuous Reconfiguration of Bi Sites for Efficient Photocatalytic N2 Reduction

open access: yesAdvanced Science, EarlyView.
Axial Fluorine and Light‐Induced Oxygen Vacancies Synergize as an Electron Pump to Lower N2 Activation Energy and Enable Sustained NH3 Synthesis on FBWO. ABSTRACT The electronic structure precision of single‐atom catalysts (SACs) represents a decisive factor limiting advancements in photocatalytic nitrogen reduction (NRR) efficiency.
Xiao Ge   +6 more
wiley   +1 more source

Fe2+‐ Induced Activation of Single and Dual Metal Site—Lattice Oxygen Mechanism in Fe Rich NiFe‐LDHs for Oxygen Evolution Reaction

open access: yesAdvanced Science, EarlyView.
Fe‐rich NiFe‐LDH catalysts derived from MOFs, showing superior OER activity via lattice oxygen mechanism activation. ABSTRACT Developing a durable and efficient oxygen evolution reaction (OER) catalyst without noble metals is essential for the economical and sustainable production of hydrogen by alkaline water electrolysis.
Nithinraj Panangattu Dharmarajan   +12 more
wiley   +1 more source

Unexpected one-pot formation of the 1H-6a,8a-epiminotricyclopenta[a,c,e][8]annulene system from cyclopentanone, ammonia and dimethyl fumarate. Synthesis of highly strained polycyclic nitroxide and EPR study

open access: yesBeilstein Journal of Organic Chemistry, 2019
The unexpected formation of a highly strained polycyclic amine was observed in a one-pot synthesis from cyclopentanone, dimethyl fumarate and ammonium acetate.
Sergey A. Dobrynin   +7 more
doaj   +1 more source

Commentary on "Rebalancing the three pillars of Basel II." [PDF]

open access: yes
This paper was part of the conference "Beyond Pillar 3 in International Banking Regulation: Disclosure and Market Discipline of Financial Firms," cosponsored by the Federal Reserve Bank of New York and the Jerome A.
Jeremy C. Stein
core  

Liquid Bismuth Catalyst Enables High‐CO‐Selectivity in CO2 Hydrogenation

open access: yesAdvanced Science, EarlyView.
This work introduces a dynamic liquid bismuth catalyst for efficient CO2‐to‐syngas conversion. Stabilized molten Bi nanodroplets on a defective VOx support enable a reversible Bi3+/Bi0 redox cycle at moderate temperatures. Mechanistic insights reveal that Ni‐Bi dual sites synergistically activate H2 and cleave CO2, leading to high CO selectivity ...
Xinxin Lu   +6 more
wiley   +1 more source

When the back office moved to the front burner: settlement fails in the treasury market after 9/11 [PDF]

open access: yes
Settlement fails, which occur when securities are not delivered and paid for on the date scheduled by the buyer and seller, can expose market participants to the risk of loss due to counterparty insolvency.
Kenneth D. Garbade, Michael J. Fleming
core   +1 more source

Atomic Tuning of Metal‐Support Interactions for Pathway‐Selective CO2 Photoreduction on TiO2

open access: yesAdvanced Science, EarlyView.
Single‐atom Fe and Cu catalysts anchored on TiO2 steer photocatalytic CO2 reduction toward distinct pathways. Fe sites favor rapid *CO desorption and selective CO formation, whereas Cu sites stabilize *CHO intermediates, enabling deep reduction and C─C coupling. Combined spectroscopy and DFT calculations reveal how metal–support interactions and oxygen
Dongyun Kim   +13 more
wiley   +1 more source

Design of an Automated Instrument for Washing EPR Sample Tubes

open access: yesChinese Journal of Magnetic Resonance
Many quartz tubes are used in electron paramagnetic resonance (EPR) experiments. These tubes are long and thin, and difficult to clean. To address the problem, an automated washing instrument for EPR sample tubes is designed.
LI Jingxin   +4 more
doaj   +1 more source

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