Results 111 to 120 of about 63,041 (218)

cis‐Carboxylate Enhancement of Mn(III)‐OH Hydrogen Atom Abstraction through PCET Thermodynamics

open access: yesAdvanced Science, EarlyView.
ABSTRACT Manganese(III)‐hydroxo intermediates are proposed as key hydrogen atom abstraction (HAA) species in manganese‐dependent enzymes, yet how first‐sphere carboxylate ligands control their proton‐coupled electron transfer (PCET) thermodynamics remains poorly understood.
Yuri Lee   +4 more
wiley   +1 more source

EPR spectroscopy 80 years after its discovery. [PDF]

open access: yesSci Adv
Goldfarb D   +5 more
europepmc   +1 more source

Unlocking Zenith Electronic State of Ni Sites in Ligand‐Engineered COFs for Efficient •O2−‐Driven Uranium Photoreduction

open access: yesAdvanced Science, EarlyView.
We develop a ligand engineering strategy to construct Ni‐diketimine‐linked COFs with precisely tuned Ni electronic states. By varying the coordinated diketone units, we achieve an optimal electronic configuration that enhances O2 adsorption and lowers the energy barrier for •O2− generation.
Guihong Wu   +5 more
wiley   +1 more source

Large Electrostrain and High Optical Transmittance via Oxygen Octahedron Rotation Disordering in KNN Ceramics

open access: yesAdvanced Science, EarlyView.
Chemical disorder engineering reconfigures BO6 oxygen‐octahedron rotations in lead‐free K0.5Na0.5NbO3 ceramics from local ordering into a random distribution, dissolving the longstanding trade‐off between optical transparency and electromechanical strain.
Xia Luo   +5 more
wiley   +1 more source

Lsp2 links early-life diet to adult translation and lifespan in Drosophila. [PDF]

open access: yesNature
Kosakamoto H   +7 more
europepmc   +1 more source

Linkage Engineering Boosts Battery Performance of Two‐Electron Phenothiazine‐Based Polyamide Cathodes

open access: yesAdvanced Science, EarlyView.
Three phenothiazine‐based polyamides featuring gradually strengthened electron‐withdrawing linkers are developed as high‐voltage cathodes for lithium‐organic batteries. The linker motif serves not only as a structural bridge to suppress solubility, but also as a functional design element that governs optoelectronic properties and electron/ion transport
Shujuan Cao   +4 more
wiley   +1 more source

High-Spin-Locked Fe(II) Spin-Crossover Compounds: THz-EPR Investigations and Spin-Phonon Coupling. [PDF]

open access: yesInorg Chem
Al Said T   +10 more
europepmc   +1 more source

Engineered Peptide Self‐Assembled Nanofibers for Enhanced STING Activation: A Promising Nanodelivery Platform for Immunotherapy of Pediatric Solid Tumors

open access: yesAdvanced Science, EarlyView.
An engineered peptide self‐assembled nanofiber platform, designed to replicate STING–cGAMP binding motifs, facilitates pH‐responsive cytosolic delivery of cGAMP, enhances the endoplasmic reticulum with high efficiency, and robustly activates the STING pathway.
Yubin He   +6 more
wiley   +1 more source

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