Results 111 to 120 of about 83,419 (283)

A Biochar‐Based Composite Hydrogel Microenvironment for Enhanced Biocatalysis

Advanced Materials, EarlyView.
This work presents the synthesis of a polyacrylamide hydrogel wherein biomass‐derived biochar is co‐encapsulated with the enzyme horseradish peroxidase (HRP). The resulting composite hydrogel possesses balanced electron‐rich and electron‐deficient domains, creating an optimal microenvironment that concentrates both hydrogen peroxide and phenol ...
Shengzhe Wang, Jingling Zhu, Weiyang Xue, Yuting Wen, Zhongxing Zhang, Xia Song, Yuan Yu, Chenglin Sun, Huangzhao Wei, Jun Li   +9 more
wiley   +1 more source

2D MOF with Intrinsic Porosity for Colorimetric Volatile Organic Compounds (VOCs) Detection

Advanced Materials, EarlyView.
An uncommon 2D MOF with intrinsic in‐plane porosity that can be mechanically exfoliated undergoes a distinct and reversible colour change upon exposure to various volatile organic compounds. ABSTRACT In this work, we report an uncommon 2D metal–organic framework (MOF) with intrinsic in‐plane porosity that undergoes a distinct and reversible colour ...
Sergio R. Gamarra, Alberto Fernández‐Alarcón, Joaquín Calbo, Enrique Ortí, Guillermo Mínguez Espallargas   +4 more
wiley   +1 more source

Frequency multiplexing enables parallel multi-sample EPR

Scientific Reports
Electron paramagnetic resonance (EPR) spectroscopy stands out as a powerful analytical technique with extensive applications in the fields of biology, chemistry, physics, and material sciences.
Chun Him Lee, Jan G. Korvink, Mazin Jouda   +2 more
doaj   +1 more source

Spectroscopically Distinct Cobalt(II) Sites in Heterodimetallic Forms of the Aminopeptidase from \u3cem\u3eAeromonas proteolytica\u3c/em\u3e:  Characterization of Substrate Binding [PDF]

, 1997
The Co(II)Zn(II)- and Zn(II)Co(II)-substituted derivatives of the aminopeptidase from Aeromonas proteolytica (AAP) were probed by EPR spectroscopy. EPR spectra of the high-spin S = 3/2 Co(II) ions in [CoZn(AAP)] and [ZnCo(AAP)] indicated that each metal ...
Bennett, Brian, Holz, Richard C.
core   +1 more source

Single‐Atom Photocatalyst as Floatable Artificial Leaf for Upcycling Oceanic Plastic Waste

Advanced Materials, EarlyView.
To resolve the catastrophic disaster of oceanic plastic pollution, the novel Ru single atom loaded ZnIn2S4 photocatalysts, in the forms of powder or floatable artificial leaf, were prepared for direct conversion of raw polypropylene plastic into valuable chemicals. The optimized catalyst exhibits exceptional performance, with a total formic/acetic acid
Amin Talebian‐Kiakalaieh, Xin Xu, Wenzhong Ji, Yun Liu, Bingquan Xia, Jingrun Ran, Shi‐Zhang Qiao   +6 more
wiley   +1 more source

Bulk and Surface Dual‐Modification for Stabilizing RuO2 Anode in 2 A cm−2 PEMWE Operation

Advanced Materials, EarlyView.
The high‐current‐density stability of the RuO2‐based anode in PEMWE could be taken care of by a bulk and surface dual modification strategy developed in this work, where Cr doping modulates the Ru valence state in the bulk phase, suppressing Ru overoxidation, whereas Si modification stabilizes the reaction interface by inhibiting catalyst ...
Jiayi Tang, Zijun Fang, Yu‐Cheng Huang, Daqin Guan, Bin Chen, Zongping Shao   +5 more
wiley   +1 more source

Inter‐Atomic Synergy on Single‐Atom Alloy Promotes Cyclohexanone Oxime Electrosynthesis

Advanced Materials, EarlyView.
Electrosynthesis of cyclohexanone oxime using renewable electricity offers a greener alternative to traditional energy‐intensive methods. Here, we develop a Fe1Bi single‐atom alloy that delivers 70.9% Faradaic efficiency and 0.94 mmol cm−2 h−1 yield rate through the atomic‐scale synergistic mechanism.
Panlong Zhai, Chen Wang, Guan Sheng, Chao Ye, Jungang Hou, Qinfen Gu, Tao Ling, Ye Zhu, Pei Liang, Xin Wang, Jieqiong Shan   +10 more
wiley   +1 more source

Laser‐Synthesized Amorphous PdSe2‐x Nanoparticles: A Defect‐Rich Platform for High‐Efficiency SERS, Photocatalysis, and Photothermal Conversion

Advanced Materials Interfaces, EarlyView.
Using femtosecond ablation, we show that an ordered, stoichiometric crystalline PdSe2 target can be controllably converted into a stable, disordered, non‐stoichiometric, and highly functional amorphous nanomaterial, PdSe2−x${\rm PdSe}_{2-x}$. The obtained nanoparticles offer significant advantages over conventional planar plasmon‐free substrates due to
Andrei Ushkov, Nadezhda Belozerova, Dmitriy Dyubo, Ilya Martynov, Alexander Syuy, Daniil Tselikov, Georgy Ermolaev, Sergey V. Bazhenov, Roman I. Romanov, Ivan Kruglov, Anton A. Popov, Alexander Chernov, Alexey D. Bolshakov, Sergey Novikov, Andrey A. Vyshnevyy, Aleksey Arsenin, Andrei V. Kabashin, Gleb I. Tselikov, Valentyn Volkov   +18 more
wiley   +1 more source

Noise characteristics of a 750-MHz electronically tunable resonator for electron paramagnetic resonance spectroscopy

AIP Advances, 2019
This paper describes an experimental investigation of the noise characteristics of a 750-MHz electronically tunable resonator for electron paramagnetic resonance (EPR) spectroscopy.
Ririko Nakaoka, Hiroshi Hirata
doaj   +1 more source

Radiotherapy Enhancement by Gold Nanocluster‐functionalized Nanoliposomes Using Polychromatic Orthovoltage X‐ray Irradiation

Advanced Materials Interfaces, EarlyView.
Lipid drug carriers to which ultra‐small gold nanoparticles were added enabled more efficient radiotherapy of cultured pancreatic cancer tumors. These nanoparticles boosted radiation‐induced damage to tumors by generating more reactive molecules, though higher gold levels are needed for strong benefits.
Nazareth Milagros Carigga Gutierrez, Eaazhisai Kandiah, Sofia Leo, Erwan Dupont, Fabrizio Johnson‐Corrales, Marc‐André Hograindleur, Sarvenaz Keshmiri, Hélène Elleaume, Benoit Busser, Romain Haudecoeur, Véronique Jacob, Anthony Vella, Véronique Josserand, Maxime Henry, Jean‐Luc Coll, Amandine Hurbin, Xavier Le Guével, Mans Broekgaarden   +17 more
wiley   +1 more source