Results 191 to 200 of about 30,752 (265)

Towards Characterization of Skin Melanoma in the Clinic by Electron Paramagnetic Resonance (EPR) Spectroscopy and Imaging of Melanin. [PDF]

Mol Imaging Biol
Wehbi M, Harkemanne E, Mignion L, Joudiou N, Tromme I, Baurain JF, Gallez B.   +6 more
europepmc   +1 more source

Incorporation of Organic Counter‐Cations Into Poly(Heptazine Imide) Networks for Promoting Proton‐Coupled Electron Transfer During Photocatalytic H2O2 Evolution

Angewandte Chemie, EarlyView.
Incorporation of N‐based onium ions into the ionic framework of poly(heptazine imide) was obtained via protonation‐deprotonation of PHI frameworks arising from a parent Na‐containing analogue. Particularly, methylammonium moieties, through their small molecular size, hydrogen bonding capabilities and rotational mobility, appear to stabilize ...
Dingqiao Ji, Hikmat Binyaminov, Desiree Leistenschneider, Martin Oschatz, Paolo Giusto, Markus Antonietti, Horațiu Szalad   +6 more
wiley   +1 more source

Domain-Specific EPR Spectroscopy to Monitor Facilitated Dissociation of a DNA-Transcription Factor Complex

Epasto LM, Khalil M, Sicoli G, Kurzbach D.   +3 more
europepmc   +1 more source

Enriched and Sustained Oxygen Vacancies in Amorphous NiWOx Enhance and Stabilize Urea Electrooxidation

Angewandte Chemie, EarlyView.
We propose an “amorphous oxygen mechanism (AOM)” for urea electrooxidation on amorphous NiWOx with tunable Ov, which achieves robust UOR activity and stability simultaneously. The “amorphous oxygen” in NiWOx prefers to escape during the UOR, in situ generating and stabilizing Ov, which thermodynamically promotes the reaction.
Yinuo Wang, Ke Zhang, Mingxing Zhou, Shijin Zhang, Ling Zhao, Gongjin Chen, Luca Magagnin, Lu Wang, Yian Wang, Minhua Shao   +9 more
wiley   +1 more source

Modulating Local Coordination in Single‐Atom Catalysts: From Fundamental Concepts to Emerging Breakthroughs in Electrocatalysis

Angewandte Chemie, EarlyView.
This review summarizes atomic‐level design strategies for single‐atom catalysts, emphasizing modulation of the local coordination environment, active‐site geometry, and metal‐support interactions to optimize catalytic activity and stability in electrocatalytic energy conversion applications.
Ashwani Kumar, Harun Tüysüz
wiley   +1 more source

Deconvoluting Monomer- and Dimer-Specific Distance Distributions between Spin Labels in a Monomer/Dimer Mixture Using <i>T</i>₁-Edited DEER EPR Spectroscopy. [PDF]

J Am Chem Soc
Schmidt T, Kubatova N, Clore GM.
europepmc   +1 more source

Radical‐Mediated Dispersion Breaks Aggregation Limits in Carbon Thermoelectrics

Angewandte Chemie, EarlyView.
We report a rationally designed small molecule (OTN) that effectively disperses SWCNTs via π–π and radical‐radical interactions, yielding hybrid films with a record power factor of 30.1 µW cm−1 K−2 and excellent flexibility. A nine‐leg device achieves a record normalized power density of 0.653 µW cm−2 K−2, setting a new benchmark for carbon‐based ...
Shanshan Zhou, Xiao‐Lei Shi, Meng Li, Wenyi Chen, Tianyi Cao, Nan‐Hai Li, Min Zhang, Prashant Sonar, Qian Liu, Zhi‐Gang Chen   +9 more
wiley   +1 more source

Structural Dynamics of Protein Interactions Using Site-Directed Spin Labeling of Cysteines to Measure Distances and Rotational Dynamics with EPR Spectroscopy. [PDF]

Appl Magn Reson
Roopnarine O, Thomas DD.
europepmc   +1 more source

Electrochemical Switch‐On of Nonlinear Optical Response in a Nitro‐Functionalized Arylimido‐Polyoxometalate

Angewandte Chemie, EarlyView.
Reducing a nitro‐derivatized arylimido‐polyoxometalate (POM) reversibly switches on its second‐order NLO response, contrasting with prior donor‐functionalized systems that switch off upon reduction. Attenuation of charge‐transfer (CT) to the POM upon reduction gives a more strongly dipolar imido/π‐bridge to ─NO2 CT, signal enhancement of up to 15× (β ...
Claire F. Jones, Bethany R. Hood, Yovan de Coene, Hayleigh Kearns, Karen Faulds, Benoît Champagne, Koen Clays, John Fielden   +7 more
wiley   +1 more source

Coupled Fe3O4‐Cluster Precipitates and Single Fe‐Atom Catalysts Can Boost Oxygen Reduction via Concomitantly Accelerated Water Dissociation

Angewandte Chemie, EarlyView.
Fe3O4 clusters can be precipitated onto Fe–N–C SACs through a residual‐oxygen‐assisted precipitation approach. Compelling evidence, including operando spectroscopy and ab initio calculations, suggests that Fe3O4‐cluster precipitates not only induce asymmetric electronic structures of Fe‐N4 active center to optimize the OH* adsorption, but also ...
Cheng‐Kai Du, Xiongyi Liang, Fei‐Xiang Ma, Yutong Li, Zheng‐Qi Liu, Long Ma, Zeng Li, Liang Zhen, Yan Huang, Xiao Cheng Zeng, Cheng‐Yan Xu   +10 more
wiley   +1 more source