Cysteine Thioaldehydes: Photolytic Generation, Reactivity, and Biological Implications
Photolysis of cysteine phenacylsulfides bearing non‐conjugating electron‐withdrawing substituents leads to high conversions into cysteine thioaldehydes through a Norrish type‐II pathway. This methodology enabled the study of the aqueous reactivity of these important biosynthetic intermediates, which, depending on peptide sequence, pH and buffer ...
Ardra Karthika +9 more
wiley +1 more source
Assessing the impact of government healthcare expenditure and life expectancy on economic growth in Saudi Arabia: an econometric time-series study (2000-2023). [PDF]
Alghannam R, Alharbi A.
europepmc +1 more source
Orchestrating Anion–π+ Interactions to Accelerate Metal‐Free Room‐Temperature Phosphorescence
Tuning anion–π+ interactions in pyridinium iodide contact ion pairs enables ultrafast metal‐free room‐temperature phosphorescence (540–605 nm) with radiative rates up to 5.2×105 s−1. Strong iodide→π+ charge‐transfer coupling, enhanced spin–orbit interactions, and dynamic ion‐pair organization accelerate intersystem crossing and emission, establishing ...
Eetu Hakkarainen +12 more
wiley +1 more source
Psychological Health Risk Factors Among Healthcare Workers: A Structural Equation Modeling Approach. [PDF]
Zhang Z, Li Y, Song B, Wang K, Hu F.
europepmc +1 more source
An iron‐photocatalyzed unsymmetrical 1,2‐hetero(atom)difunctionalization of alkenes enables to install orthogonal C–Cl and C–O (alkoxyamine) handles which provides access to diverse nucleophiles via complementary reactivity (SN and photoredox) at two distinct sites. Detailed mechanistic studies elucidate interesting features of the iron catalytic cycle.
Amrita Chaudhuri +5 more
wiley +1 more source
A Symmetric Cogeneration Fuel Cell for Coupled Production of Hydrogen, Ammonia and Formate. [PDF]
Song Y +8 more
europepmc +1 more source
The first hydrogel system employing anion–π interactions as a central design motif is developed. The cooperative aromatic–phosphate interaction motif provides dynamic cohesion and is proposed to regulate the separation and transport of water‐derived ionic species, achieving high piezoionic response in injectable, self‐healing, ultrasoft, low‐salinity ...
Jinyang Jiang +11 more
wiley +1 more source
Valorizing Carbide Slag as Cement-Compatible CaCO<sub>3</sub> Suspension via Pretreatment-Controlled Carbonation. [PDF]
Zhu J +5 more
europepmc +1 more source
Endogenous green technology innovation and diffusion with strategic international spillovers. [PDF]
Feng Z.
europepmc +1 more source
The interrelationship among physical activity, smartphone addiction, loneliness, and sport motivation in Chinese college students: a cross-sectional network analysis. [PDF]
Hou W, Song H, Deng W, Zhou L.
europepmc +1 more source

