Results 231 to 240 of about 3,440,905 (299)

Engineering a Fluorinated AlPO4 Interface: Toward High Initial Coulombic Efficiency and Stable Oxygen Redox in Li‐Rich Layered Oxide Cathodes

open access: yesAdvanced Functional Materials, EarlyView.
We report a chemically incorporated fluorinated AlPO4 (AlPO4‐F) architecture that functions as a multifunctional “interfacial fortress” for Li‐rich layered oxides (LLOs). By modulating the surface potential to –32.16 mV, this architecture enriches Li+ concentration and repels detrimental electrolyte anions.
Hojun Moon   +13 more
wiley   +1 more source

Mechanistic Origins of Chemo‐Mechanical Instability and Failure in Solid‐State Lithium‐Sulfur Electrodes

open access: yesAdvanced Functional Materials, EarlyView.
Conversion‐induced sulfur expansion generates strong mechanical constraints and localized stresses within solid‐state Li‐S cathodes. Heterogeneous solid‐electrolyte confinement creates tensile strain‐energy hotspots that govern particle cracking. Larger sulfur particles accelerate fracture, while higher porosity relaxes constraint and delays damage ...
Arpan K. Sharma   +3 more
wiley   +1 more source

3D‐Printed Gradient Shape‐Memory Strain Sensors With Rewritable Gauge Factors

open access: yesAdvanced Functional Materials, EarlyView.
A 3D‐printed shape‐memory strain sensor combines thermomechanical programming with gradient architectural design. Preset strain rewrites the gauge factor (GF), while the gradient geometry amplifies the response through strain redistribution. Reprogrammable sensitivity enables the same sensor to detect weak pulse signals and monitor large‐amplitude ...
Xuan Zhang   +10 more
wiley   +1 more source

Intracrystalline Void‐Mediated Toughening of Brittle Crystals in Quail Eggshells

open access: yesAdvanced Functional Materials, EarlyView.
In quail eggshells, the high density and disordered arrangement of intracrystalline voids inhibit lattice cleavage, suppress long‐range crack propagation, and promote deformation twinning and quasi‐plasticity, serving as an essential toughening motif. We show that these voids remain within a narrow subcritical size range and therefore predominantly do ...
Jingxiao Zhong   +16 more
wiley   +1 more source

Nanoamphizymes: Self‐Assembled Amphiphilic Enzymatic Nanomaterials for High‐Performance Biocatalysis and Biosensing

open access: yesAdvanced Functional Materials, EarlyView.
An amphiphilic GOx nanoamphizyme was constructed by covalently introducing hydrophobic PPNI linkers onto GOx, enabling spontaneous self‐assembly into tunable nanoparticles. Mild crosslinking further stabilized the assemblies and enhanced catalytic performance and stability.
Yuan‐Hao Hsiao   +4 more
wiley   +1 more source

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